Structural and thermodynamic insights into the coordination preference of norbornadiene with the initiator complex [RuCl 2 (PPh 3 ) 2 (piperidine)] in polymerization via olefin metathesis

The metathesis reaction has been an important tool in both organic and inorganic synthetic chemistry. More specifically in polymer chemistry, ring opening metathesis polymerization (ROMP), the formation of an active metal-carbene species (MCHR), has been widely used. The elucidation of the mechanis...

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Veröffentlicht in:	Physical chemistry chemical physics : PCCP 2024-05, Vol.26 (17), p.13164-13171
Hauptverfasser:	Sousa, José Antonio de, Sá, José Luiz da Silva, Carneiro, José Walkimar de Mesquita, Matos, José Milton Elias de
Format:	Artikel
Sprache:	eng
Schlagworte:	Carbenes Catalysts Coordination Decomposition reactions Density functional theory Metathesis Piperidine Polymer chemistry Polymerization Ring opening
Online-Zugang:	Volltext
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