Using Chiral Auxiliaries to Mimic the Effect of Chiral Media on the Structure of Lanthanide(III) Complexes Common in Bioimaging and Diagnostic MRI

[Ln·DOTA]− complexes and systems derived therefrom are commonly used in MRI and optical bioimaging. These lanthanide­(III) complexes are chiral, and, in solution, they are present in four forms, with two sets of enantiomers, with the ligand donors arranged in either a square antiprismatic, SAP, or t...

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Veröffentlicht in:	Inorganic chemistry 2024-04, Vol.63 (17), p.7560-7570
Hauptverfasser:	Nielsen, Lea Gundorff, Andersen, Helene O. B., Kenwright, Alan M., Platas-Iglesias, Carlos, So̷rensen, Thomas Just
Format:	Artikel
Sprache:	eng
Schlagworte:	Amides - chemistry Contrast Media - chemistry Contrast Media - pharmacology Coordination Complexes - chemical synthesis Coordination Complexes - chemistry Coordination Complexes - pharmacology Heterocyclic Compounds, 1-Ring - chemistry Lanthanoid Series Elements - chemistry Magnetic Resonance Imaging Molecular Structure Stereoisomerism
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