Demonstration of π–π Stacking at Interfaces: Synthesis of an Indole-Modified Monodisperse Silica Microsphere SiO2@IN
In the present study, a novel silane coupling agent, designated INSi, was synthesized via a facile synthetic route, incorporating indole-functional moieties. This agent was further employed for the surface modification of homemade silica nanomicrospheres (SMPs). The ensuing nanomicrosphere composite...
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| Veröffentlicht in: | Langmuir 2024-04, Vol.40 (16), p.8685-8693 |
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| creator | Tang, Qiaolin Zhu, Feng Li, Yanqi Yin, Sijie Xu, Yunbo Yan, Huicheng Kang, Ming Chang, Guanjun |
| description | In the present study, a novel silane coupling agent, designated INSi, was synthesized via a facile synthetic route, incorporating indole-functional moieties. This agent was further employed for the surface modification of homemade silica nanomicrospheres (SMPs). The ensuing nanomicrosphere composite, denoted as SiO2@IN, exemplified pronounced interfacial π–π interactions. Optimization of the reaction conditions was conducted using the response surface optimization technique. Subsequent validation of interfacial π–π interactions was accomplished through a synergistic approach, integrating theoretical calculations and comprehensive analyses of spectral and morphological attributes exhibited by the SiO2@IN. |
| doi_str_mv | 10.1021/acs.langmuir.4c00504 |
| format | Article |
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| title | Demonstration of π–π Stacking at Interfaces: Synthesis of an Indole-Modified Monodisperse Silica Microsphere SiO2@IN |
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