Structure of unsolvated magnesium borohydride Mg(BH4)2

We have determined the structures of two phases of unsolvated Mg(BH4)2, a material of interest for hydrogen storage. One or both phases can be obtained depending on the synthesis conditions. The first, a hexagonal phase with space group P61, is stable below 453 K. Upon heating above that temperature...

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Veröffentlicht in:	Acta Crystallographica Section B: Structural Science 2007-08, Vol.63 (4), p.561-568
Hauptverfasser:	Her, Jae-Hyuk, Stephens, Peter W., Gao, Yan, Soloveichik, Grigorii L., Rijssenbeek, Job, Andrus, Matthew, Zhao, Ji-Cheng
Format:	Artikel
Sprache:	eng
Schlagworte:	08 HYDROGEN antisite disorder ATOMS BOROHYDRIDES Crystal structure Crystallography HEATING HYDROGEN HYDROGEN STORAGE MAGNESIUM Magnesium composites national synchrotron light source Phase transitions SPACE GROUPS synchrotron powder diffraction SYNTHESIS Temperature effects TEMPERATURE RANGE 0400-1000 K
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