Studies on electrodeposition and corrosion behaviour of a Ni-W-Co amorphous alloy

A ternary alloy Ni–W–Co was electrodeposited and operational parameters in relation to its corrosion resistance and deposition efficiency were optimized. A 22 full factorial design was successfully employed for experimental design analysis of the results. By means of response surface analysis, the s...

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Veröffentlicht in:Journal of materials science 2007-11, Vol.42 (22), p.9137-9144
Hauptverfasser: SANTANA, Renato Alexandre C, CAMPOS, Ana Regina N, MEDEIROS, Emanuelle A, OLIVEIRA, Aldrighi Luiz M, SILVA, Liana Maria F, PRASAD, Shiva
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container_end_page 9144
container_issue 22
container_start_page 9137
container_title Journal of materials science
container_volume 42
creator SANTANA, Renato Alexandre C
CAMPOS, Ana Regina N
MEDEIROS, Emanuelle A
OLIVEIRA, Aldrighi Luiz M
SILVA, Liana Maria F
PRASAD, Shiva
description A ternary alloy Ni–W–Co was electrodeposited and operational parameters in relation to its corrosion resistance and deposition efficiency were optimized. A 22 full factorial design was successfully employed for experimental design analysis of the results. By means of response surface analysis, the statistical model identified the following operating conditions for obtaining corrosion resistant alloy: 60 mA/cm2 current density, 70 °C temperature, 20 rpm cathode rotation and 8.0 pH. The alloy was deposited at 36% current efficiency, with an average composition of 70% Ni, 8% Co, 22% W and traces of boron and with Ecorr −0.508 V and Rp 4.56 × 104 Ohm. The deposit obtained under these conditions had an amorphous character and showed good adherence, high corrosion resistance and presence of nodules on its surface. Electrochemical corrosion tests verified that the Ni–W–Co alloy had better corrosion resistance than similarly electrodeposited Co–W amorphous alloy.
doi_str_mv 10.1007/s10853-007-1931-0
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subjects Amorphous alloys
Applied sciences
Boron
Cobalt base alloys
Corrosion
Corrosion prevention
Corrosion resistance
Corrosion resistant alloys
Corrosion tests
Current density
Current efficiency
Deposition
Design analysis
Design of experiments
Design optimization
Electrochemical corrosion
Exact sciences and technology
Factorial design
Materials science
Mathematical models
Metallic coatings
Metallic glasses
Metals. Metallurgy
Nickel base alloys
Nodules
Production techniques
Response surface methodology
Statistical models
Surface analysis (chemical)
Surface treatment
Ternary alloys
title Studies on electrodeposition and corrosion behaviour of a Ni-W-Co amorphous alloy
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