Epitaxial growth of cobalt oxide by atomic layer deposition

Highly oriented thin films of cobalt oxide were made by the atomic layer deposition (ALD) technique, using Co(thd) 2 (Hthd=2,2,6,6-tetramethylheptan-3,5-dione) and ozone as precursors. Films were deposited on single-crystalline substrates of MgO(1 0 0), α-Al 2O 3(0 0 1), and SrTiO 3(1 0 0). Epitaxia...

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Veröffentlicht in:Journal of crystal growth 2007-09, Vol.307 (2), p.457-465
Hauptverfasser: Klepper, K.B., Nilsen, O., Fjellvåg, H.
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Nilsen, O.
Fjellvåg, H.
description Highly oriented thin films of cobalt oxide were made by the atomic layer deposition (ALD) technique, using Co(thd) 2 (Hthd=2,2,6,6-tetramethylheptan-3,5-dione) and ozone as precursors. Films were deposited on single-crystalline substrates of MgO(1 0 0), α-Al 2O 3(0 0 1), and SrTiO 3(1 0 0). Epitaxial growth has been established with the following orientations: (0 0 1)[1 0 0]Co 3O 4∥(0 0 1)[1 0 0]MgO, (1 1 1)[1 1 1]Co 3O 4∥(0 0 1)[0 0 1]α-Al 2O 3, and (0 0 1)[1 0 0]Co 3O 4∥(0 0 1)[1 0 0]SrTiO 3. The resulting texture was studied as function of deposition temperature in the range 138–283 °C for MgO(1 0 0) and 186–283 °C for the remaining substrates. The topography and morphology of the films were investigated by atomic force microscopy (AFM), and in selected cases scanning electron microscopy. The specific electronic resistivities of as-deposited films grown on the various substrates were measured to be from 0.8 to 85 Ωcm.
doi_str_mv 10.1016/j.jcrysgro.2007.06.028
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Films were deposited on single-crystalline substrates of MgO(1 0 0), α-Al 2O 3(0 0 1), and SrTiO 3(1 0 0). Epitaxial growth has been established with the following orientations: (0 0 1)[1 0 0]Co 3O 4∥(0 0 1)[1 0 0]MgO, (1 1 1)[1 1 1]Co 3O 4∥(0 0 1)[0 0 1]α-Al 2O 3, and (0 0 1)[1 0 0]Co 3O 4∥(0 0 1)[1 0 0]SrTiO 3. The resulting texture was studied as function of deposition temperature in the range 138–283 °C for MgO(1 0 0) and 186–283 °C for the remaining substrates. The topography and morphology of the films were investigated by atomic force microscopy (AFM), and in selected cases scanning electron microscopy. The specific electronic resistivities of as-deposited films grown on the various substrates were measured to be from 0.8 to 85 Ωcm.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.jcrysgro.2007.06.028</doi><tpages>9</tpages></addata></record>
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subjects A1. Epitaxial growth
A2. Atomic layer deposition (ALD)
A3. Atomic layer chemical vapour deposition (ALCVD)
A3. Atomic layer epitaxy (ALE)
B1. Cobalt oxide
Chemical vapor deposition (including plasma-enhanced cvd, mocvd, etc.)
Condensed matter: structure, mechanical and thermal properties
Cross-disciplinary physics: materials science
rheology
Exact sciences and technology
Materials science
Methods of deposition of films and coatings
film growth and epitaxy
Physics
Structure and morphology
thickness
Surfaces and interfaces
thin films and whiskers (structure and nonelectronic properties)
Theory and models of film growth
Thin film structure and morphology
Vapor phase epitaxy
growth from vapor phase
title Epitaxial growth of cobalt oxide by atomic layer deposition
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