Photochemical and Chemical Two-Channel Control of Functional Nanogated Hybrid Architectures

A two‐channel switchable nanoscopic hybrid system, able to modulate mass transport by photoresponsive appended organic groups and the presence of G1.5 PAMAM dendrimers as molecular caps, is reported. This new functional gatelike ensemble is chemically (by pH changes) and photochemically (using visib...

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Veröffentlicht in:Advanced materials (Weinheim) 2007-09, Vol.19 (17), p.2228-2231
Hauptverfasser: Aznar, E., Casasús, R., García-Acosta, B., Marcos, M. D., Martínez-Máñez, R., Sancenón, F., Soto, J., Amorós, P.
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container_end_page 2231
container_issue 17
container_start_page 2228
container_title Advanced materials (Weinheim)
container_volume 19
creator Aznar, E.
Casasús, R.
García-Acosta, B.
Marcos, M. D.
Martínez-Máñez, R.
Sancenón, F.
Soto, J.
Amorós, P.
description A two‐channel switchable nanoscopic hybrid system, able to modulate mass transport by photoresponsive appended organic groups and the presence of G1.5 PAMAM dendrimers as molecular caps, is reported. This new functional gatelike ensemble is chemically (by pH changes) and photochemically (using visible light) controlled in pure aqueous solution, as demonstrated by an experiment involving the controlled release of a dye (see figure).
doi_str_mv 10.1002/adma.200601958
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subjects Hybrid materials
Mesoporous materials
Optical switches
Supramolecular chemistry
Switches
title Photochemical and Chemical Two-Channel Control of Functional Nanogated Hybrid Architectures
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