Influence of In on the surface morphology of HVPE grown GaN

In this paper, a study is presented on the effect of In on the surface morphology of GaN grown by HVPE. Experiments are performed with N 2 and H 2 as the carrier gasses, both with and without In present in the reactor. The adding of In increases the morphological quality of the grown layers; this ef...

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Veröffentlicht in:Journal of crystal growth 2007-09, Vol.307 (1), p.19-25
Hauptverfasser: Dam, C.E.C., Hageman, P.R., van Enckevort, W.J.P., Bohnen, T., Larsen, P.K.
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container_end_page 25
container_issue 1
container_start_page 19
container_title Journal of crystal growth
container_volume 307
creator Dam, C.E.C.
Hageman, P.R.
van Enckevort, W.J.P.
Bohnen, T.
Larsen, P.K.
description In this paper, a study is presented on the effect of In on the surface morphology of GaN grown by HVPE. Experiments are performed with N 2 and H 2 as the carrier gasses, both with and without In present in the reactor. The adding of In increases the morphological quality of the grown layers; this effect is most strongly observed for N 2 as the carrier gas. It is found that adding In reduces the growth rate and also increases the steepness of the growth hillocks on the surface. The step velocity, which is calculated from hillock slopes and the growth rate, decreases upon adding In. Without In, trails are visible across the surface where steps are distorted by passing a dislocation outcrop. With In present this pinning is still present, however, the trails do not form. Two possible explanations for this phenomenon are an increased surface diffusion due to a mono- or bi-layer of In on the surface and the slower step motion when In is present.
doi_str_mv 10.1016/j.jcrysgro.2007.06.005
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Experiments are performed with N 2 and H 2 as the carrier gasses, both with and without In present in the reactor. The adding of In increases the morphological quality of the grown layers; this effect is most strongly observed for N 2 as the carrier gas. It is found that adding In reduces the growth rate and also increases the steepness of the growth hillocks on the surface. The step velocity, which is calculated from hillock slopes and the growth rate, decreases upon adding In. Without In, trails are visible across the surface where steps are distorted by passing a dislocation outcrop. With In present this pinning is still present, however, the trails do not form. 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subjects A3. Hydride vapour phase epitaxy
B1. Nitrides
Condensed matter: structure, mechanical and thermal properties
Cross-disciplinary physics: materials science
rheology
Defects and impurities in crystals
microstructure
Exact sciences and technology
Linear defects: dislocations, disclinations
Materials science
Methods of deposition of films and coatings
film growth and epitaxy
Physics
Structure and morphology
thickness
Structure of solids and liquids
crystallography
Surfaces and interfaces
thin films and whiskers (structure and nonelectronic properties)
Theory and models of film growth
Thin film structure and morphology
Vapor phase epitaxy
growth from vapor phase
title Influence of In on the surface morphology of HVPE grown GaN
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