Formation of regular zigzag branch of CsCl crystallites on glass substrate: A new lateral growth mechanism leading to long-range ordering

We report in this article a mechanism to form regularly zigzag branch of CsCl crystallites on a flat glass substrate, in which the crystallographic orientation rotates continuously, and a pattern with long-range order on tens of micrometer scale is generated. Atomic force microscopy (AFM) indicates...

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Veröffentlicht in:Journal of crystal growth 2007-09, Vol.307 (1), p.171-176
Hauptverfasser: Pan, Wei, Mao, Y.W., Shu, D.J., Ma, G.B., Wang, Mu, Peng, R.W., Hao, X.P., Ming, N.-B.
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container_end_page 176
container_issue 1
container_start_page 171
container_title Journal of crystal growth
container_volume 307
creator Pan, Wei
Mao, Y.W.
Shu, D.J.
Ma, G.B.
Wang, Mu
Peng, R.W.
Hao, X.P.
Ming, N.-B.
description We report in this article a mechanism to form regularly zigzag branch of CsCl crystallites on a flat glass substrate, in which the crystallographic orientation rotates continuously, and a pattern with long-range order on tens of micrometer scale is generated. Atomic force microscopy (AFM) indicates that this unusual crystallization behavior is associated with successive nucleation at the concave edge of crystallite facet and glass substrate, where interfacial tension underneath the nucleus is asymmetric. We suggest that these observations reveal a new lateral growth mode, and may help to understand a class of long-range ordering effect in crystallization.
doi_str_mv 10.1016/j.jcrysgro.2007.05.051
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subjects A1. Atomic force microscopy
A1. Nucleation
A1. Physics of crystal growth
A1. Surface tension
A3. Film growth and epitaxy
Condensed matter: structure, mechanical and thermal properties
Cross-disciplinary physics: materials science
rheology
Equations of state, phase equilibria, and phase transitions
Exact sciences and technology
General studies of phase transitions
Inorganic compounds
Materials science
Methods of crystal growth
physics of crystal growth
Order-disorder and statistical mechanics of model systems
Physics
Solid-solid transitions
Specific phase transitions
Structure of solids and liquids
crystallography
Structure of specific crystalline solids
Theory and models of crystal growth
physics of crystal growth, crystal morphology and orientation
title Formation of regular zigzag branch of CsCl crystallites on glass substrate: A new lateral growth mechanism leading to long-range ordering
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