Asymmetric Hydrosilylation of Prochiral Ketones Catalyzed by Nanocrystalline Copper(II) Oxide
Asymmetric hydrosilylation of aryl alkyl ketones to afford chiral secondary alcohols with good yields and excellent enantioselectivity is realized by using nanocrystalline copper(II) oxide and BINAP in the presence of organosilanes as the stoichiometric reducing agents.
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| Veröffentlicht in: | Advanced synthesis & catalysis 2007-07, Vol.349 (10), p.1797-1802 |
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| container_end_page | 1802 |
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| container_issue | 10 |
| container_start_page | 1797 |
| container_title | Advanced synthesis & catalysis |
| container_volume | 349 |
| creator | Kantam, M. Lakshmi Laha, Soumi Yadav, Jagjit Likhar, Pravin R. Sreedhar, B. Choudary, B. M. |
| description | Asymmetric hydrosilylation of aryl alkyl ketones to afford chiral secondary alcohols with good yields and excellent enantioselectivity is realized by using nanocrystalline copper(II) oxide and BINAP in the presence of organosilanes as the stoichiometric reducing agents. |
| doi_str_mv | 10.1002/adsc.200600481 |
| format | Article |
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| language | eng |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | asymmetric hydrosilylation heterogeneous catalysis nanocrystalline copper(II) oxide reduction secondary alcohols |
| title | Asymmetric Hydrosilylation of Prochiral Ketones Catalyzed by Nanocrystalline Copper(II) Oxide |
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