Radiolysis of ferrocyanide solutions studied by infrared spectroscopy
The behavior of the neutral and basic aqueous ferrocyanide system under irradiation is investigated using the coupling of a LINAC with infrared spectroscopy. The comparison between the neutral and basic system evidences the formation of the hydroxopentacyanoferrate (III) ions and gives information o...
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| Veröffentlicht in: | Radiation physics and chemistry (Oxford, England : 1993) England : 1993), 2007-08, Vol.76 (8), p.1280-1284 |
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| container_end_page | 1284 |
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| container_issue | 8 |
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| container_title | Radiation physics and chemistry (Oxford, England : 1993) |
| container_volume | 76 |
| creator | Le Caër, S. Vigneron, G. Renault, J.P. Pommeret, S. |
| description | The behavior of the neutral and basic aqueous ferrocyanide system under irradiation is investigated using the coupling of a LINAC with infrared spectroscopy. The comparison between the neutral and basic system evidences the formation of the hydroxopentacyanoferrate (III) ions and gives information on the reaction mechanisms. The pseudo-protective effect of the dissolved dioxygen on the ferrocyanide is explained via a mechanism implying the superoxide radical anion. |
| doi_str_mv | 10.1016/j.radphyschem.2007.02.019 |
| format | Article |
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The comparison between the neutral and basic system evidences the formation of the hydroxopentacyanoferrate (III) ions and gives information on the reaction mechanisms. The pseudo-protective effect of the dissolved dioxygen on the ferrocyanide is explained via a mechanism implying the superoxide radical anion.</description><identifier>ISSN: 0969-806X</identifier><identifier>EISSN: 1879-0895</identifier><identifier>DOI: 10.1016/j.radphyschem.2007.02.019</identifier><language>eng</language><publisher>Elsevier Ltd</publisher><subject>Ferricyanide ; Ferrocyanide ; FT-IR spectroscopy ; Radiolysis ; Superoxide</subject><ispartof>Radiation physics and chemistry (Oxford, England : 1993), 2007-08, Vol.76 (8), p.1280-1284</ispartof><rights>2007 Elsevier Ltd</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c383t-d85580edde3825c8216c70182e2a45de95b18152625785b70bba52bbb3f9cb353</citedby><cites>FETCH-LOGICAL-c383t-d85580edde3825c8216c70182e2a45de95b18152625785b70bba52bbb3f9cb353</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.radphyschem.2007.02.019$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>315,782,786,3554,27933,27934,46004</link.rule.ids></links><search><creatorcontrib>Le Caër, S.</creatorcontrib><creatorcontrib>Vigneron, G.</creatorcontrib><creatorcontrib>Renault, J.P.</creatorcontrib><creatorcontrib>Pommeret, S.</creatorcontrib><title>Radiolysis of ferrocyanide solutions studied by infrared spectroscopy</title><title>Radiation physics and chemistry (Oxford, England : 1993)</title><description>The behavior of the neutral and basic aqueous ferrocyanide system under irradiation is investigated using the coupling of a LINAC with infrared spectroscopy. The comparison between the neutral and basic system evidences the formation of the hydroxopentacyanoferrate (III) ions and gives information on the reaction mechanisms. The pseudo-protective effect of the dissolved dioxygen on the ferrocyanide is explained via a mechanism implying the superoxide radical anion.</description><subject>Ferricyanide</subject><subject>Ferrocyanide</subject><subject>FT-IR spectroscopy</subject><subject>Radiolysis</subject><subject>Superoxide</subject><issn>0969-806X</issn><issn>1879-0895</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2007</creationdate><recordtype>article</recordtype><recordid>eNqNkE1LxDAQhoMouK7-h3rx1jpJTZscZfELFgRR8BbyMcUs3aYmrdB_b2Q9ePQ0c3jel5mHkEsKFQXaXO-qqN34sST7gfuKAbQVsAqoPCIrKlpZgpD8mKxANrIU0LyfkrOUdpBBwesVuXvRzod-ST4VoSs6jDHYRQ_eYZFCP08-DKlI0-w8usIshR-6qGPe04h2iiHZMC7n5KTTfcKL37kmb_d3r5vHcvv88LS53Za2FvVUOsG5AHQOa8G4FYw2tgUqGDJ9wx1KbqignDWM5-tMC8ZozowxdSetqXm9JleH3jGGzxnTpPY-Wex7PWCYk6oht_H2fyDcSJpBeQBtfiVF7NQY_V7HRVFQP4bVTv0xrH4MK2AqG87ZzSGL-eUvj1El63Gw6HzMbpQL_h8t38nBi8M</recordid><startdate>20070801</startdate><enddate>20070801</enddate><creator>Le Caër, S.</creator><creator>Vigneron, G.</creator><creator>Renault, J.P.</creator><creator>Pommeret, S.</creator><general>Elsevier Ltd</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>7U5</scope><scope>L7M</scope></search><sort><creationdate>20070801</creationdate><title>Radiolysis of ferrocyanide solutions studied by infrared spectroscopy</title><author>Le Caër, S. ; Vigneron, G. ; Renault, J.P. ; Pommeret, S.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c383t-d85580edde3825c8216c70182e2a45de95b18152625785b70bba52bbb3f9cb353</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2007</creationdate><topic>Ferricyanide</topic><topic>Ferrocyanide</topic><topic>FT-IR spectroscopy</topic><topic>Radiolysis</topic><topic>Superoxide</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Le Caër, S.</creatorcontrib><creatorcontrib>Vigneron, G.</creatorcontrib><creatorcontrib>Renault, J.P.</creatorcontrib><creatorcontrib>Pommeret, S.</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Radiation physics and chemistry (Oxford, England : 1993)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Le Caër, S.</au><au>Vigneron, G.</au><au>Renault, J.P.</au><au>Pommeret, S.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Radiolysis of ferrocyanide solutions studied by infrared spectroscopy</atitle><jtitle>Radiation physics and chemistry (Oxford, England : 1993)</jtitle><date>2007-08-01</date><risdate>2007</risdate><volume>76</volume><issue>8</issue><spage>1280</spage><epage>1284</epage><pages>1280-1284</pages><issn>0969-806X</issn><eissn>1879-0895</eissn><abstract>The behavior of the neutral and basic aqueous ferrocyanide system under irradiation is investigated using the coupling of a LINAC with infrared spectroscopy. The comparison between the neutral and basic system evidences the formation of the hydroxopentacyanoferrate (III) ions and gives information on the reaction mechanisms. The pseudo-protective effect of the dissolved dioxygen on the ferrocyanide is explained via a mechanism implying the superoxide radical anion.</abstract><pub>Elsevier Ltd</pub><doi>10.1016/j.radphyschem.2007.02.019</doi><tpages>5</tpages></addata></record> |
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| subjects | Ferricyanide Ferrocyanide FT-IR spectroscopy Radiolysis Superoxide |
| title | Radiolysis of ferrocyanide solutions studied by infrared spectroscopy |
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