Chemically attaching polyhydroxyethylmethacrylate brush on substrate surface, derivation, and the role in differential etching
This article reports the preparation and derivation of chemically tethered polyhydroxyethylmethacrylate (PHEMA) brush and its application in microfabrication. PHEMA brush was prepared by the surface‐initiated atomic transfer radical polymerization and derived by either organic reaction or sequence p...
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| Veröffentlicht in: | Journal of applied polymer science 2007-10, Vol.106 (2), p.723-729 |
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| container_title | Journal of applied polymer science |
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| creator | Zhou, Feng Mu, Zonggang Wang, Tingmei Liu, Zhilu Yu, Bo Hao, Jingcheng Liu, Weimin |
| description | This article reports the preparation and derivation of chemically tethered polyhydroxyethylmethacrylate (PHEMA) brush and its application in microfabrication. PHEMA brush was prepared by the surface‐initiated atomic transfer radical polymerization and derived by either organic reaction or sequence polymerization. The differential etching process was studied by atomic force microscope (AFM) and optical micrograph. PHEMA brush cannot prevent the underlying gold from dissolving in aqueous etchant KI/I2 solution. Differential etching of UV‐patterned PHEMA template resulted in metal (gold) rings. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007 |
| doi_str_mv | 10.1002/app.25046 |
| format | Article |
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PHEMA brush was prepared by the surface‐initiated atomic transfer radical polymerization and derived by either organic reaction or sequence polymerization. The differential etching process was studied by atomic force microscope (AFM) and optical micrograph. PHEMA brush cannot prevent the underlying gold from dissolving in aqueous etchant KI/I2 solution. Differential etching of UV‐patterned PHEMA template resulted in metal (gold) rings. © 2007 Wiley Periodicals, Inc. 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Appl. Polym. Sci</addtitle><description>This article reports the preparation and derivation of chemically tethered polyhydroxyethylmethacrylate (PHEMA) brush and its application in microfabrication. PHEMA brush was prepared by the surface‐initiated atomic transfer radical polymerization and derived by either organic reaction or sequence polymerization. The differential etching process was studied by atomic force microscope (AFM) and optical micrograph. PHEMA brush cannot prevent the underlying gold from dissolving in aqueous etchant KI/I2 solution. Differential etching of UV‐patterned PHEMA template resulted in metal (gold) rings. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007</description><subject>Applied sciences</subject><subject>atomic force microscope (AFM)</subject><subject>atomic transfer radical polymerization (ATRP)</subject><subject>Exact sciences and technology</subject><subject>hydrophilic polymer</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Polymerization</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><subject>self-assembly</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2007</creationdate><recordtype>article</recordtype><recordid>eNp1kM1u1DAURi1EJYaWBW_gDUhITWsnju0sy0AL0rR0wc_ScuwbYvAkqe1As-HZ6-mUsmJzr3R9vs_SQeglJSeUkPJUT9NJWRPGn6AVJY0oGC_lU7TKb7SQTVM_Q89j_EEIpTXhK_Rn3cPWGe39gnVK2vRu-I6n0S_9YsN4u0DqF7_NU5uweJ0At2GOPR4HHOc2prA7xTl02sAxthDcL53cOBxjPVicesBh9IDdgK3rOggwJKc9hnT_0xE66LSP8OJhH6Iv5-8_rz8Um08XH9dnm8JUXPJCNNBaa0RtBZSG67phljLGZGtsXgyooBZKIbluLG0tJZlitgPeyIpXsjpEr_e9UxhvZohJbV004L0eYJyjqrIQIeod-GYPmjDGGKBTU3BbHRZFidoZVtmwujec2VcPpTpmg13Qg3HxX0A2kgvCMne65347D8v_C9XZ9fXf5mKfcDHB7WNCh5-Ki0rU6tvVhZJXb79uRPNOXVZ3ML-cfQ</recordid><startdate>20071015</startdate><enddate>20071015</enddate><creator>Zhou, Feng</creator><creator>Mu, Zonggang</creator><creator>Wang, Tingmei</creator><creator>Liu, Zhilu</creator><creator>Yu, Bo</creator><creator>Hao, Jingcheng</creator><creator>Liu, Weimin</creator><general>Wiley Subscription Services, Inc., A Wiley Company</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20071015</creationdate><title>Chemically attaching polyhydroxyethylmethacrylate brush on substrate surface, derivation, and the role in differential etching</title><author>Zhou, Feng ; Mu, Zonggang ; Wang, Tingmei ; Liu, Zhilu ; Yu, Bo ; Hao, Jingcheng ; Liu, Weimin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3686-79ebddc75d7e2c6a594d14448bcd4444e171de2786a9d1bd102c64dfe69836383</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2007</creationdate><topic>Applied sciences</topic><topic>atomic force microscope (AFM)</topic><topic>atomic transfer radical polymerization (ATRP)</topic><topic>Exact sciences and technology</topic><topic>hydrophilic polymer</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Polymerization</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><topic>self-assembly</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhou, Feng</creatorcontrib><creatorcontrib>Mu, Zonggang</creatorcontrib><creatorcontrib>Wang, Tingmei</creatorcontrib><creatorcontrib>Liu, Zhilu</creatorcontrib><creatorcontrib>Yu, Bo</creatorcontrib><creatorcontrib>Hao, Jingcheng</creatorcontrib><creatorcontrib>Liu, Weimin</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhou, Feng</au><au>Mu, Zonggang</au><au>Wang, Tingmei</au><au>Liu, Zhilu</au><au>Yu, Bo</au><au>Hao, Jingcheng</au><au>Liu, Weimin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Chemically attaching polyhydroxyethylmethacrylate brush on substrate surface, derivation, and the role in differential etching</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. Appl. Polym. Sci</addtitle><date>2007-10-15</date><risdate>2007</risdate><volume>106</volume><issue>2</issue><spage>723</spage><epage>729</epage><pages>723-729</pages><issn>0021-8995</issn><eissn>1097-4628</eissn><coden>JAPNAB</coden><abstract>This article reports the preparation and derivation of chemically tethered polyhydroxyethylmethacrylate (PHEMA) brush and its application in microfabrication. PHEMA brush was prepared by the surface‐initiated atomic transfer radical polymerization and derived by either organic reaction or sequence polymerization. The differential etching process was studied by atomic force microscope (AFM) and optical micrograph. PHEMA brush cannot prevent the underlying gold from dissolving in aqueous etchant KI/I2 solution. Differential etching of UV‐patterned PHEMA template resulted in metal (gold) rings. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007</abstract><cop>Hoboken</cop><pub>Wiley Subscription Services, Inc., A Wiley Company</pub><doi>10.1002/app.25046</doi><tpages>7</tpages></addata></record> |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Applied sciences atomic force microscope (AFM) atomic transfer radical polymerization (ATRP) Exact sciences and technology hydrophilic polymer Organic polymers Physicochemistry of polymers Polymerization Preparation, kinetics, thermodynamics, mechanism and catalysts self-assembly |
| title | Chemically attaching polyhydroxyethylmethacrylate brush on substrate surface, derivation, and the role in differential etching |
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