Ammonium removal from landfill leachate by anodic oxidation

The feasibility of removing ammonium from landfill leachates by electrochemical oxidation was studied. Raw leachates and biologically/physico-chemically pretreated leachates from a municipal landfill site were treated. Boron doped diamond was used as anode and stainless steel as cathode, both electr...

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Veröffentlicht in:Journal of hazardous materials 2007-06, Vol.144 (3), p.715-719
Hauptverfasser: Cabeza, Adelaida, Urtiaga, Ane, Rivero, María-José, Ortiz, Inmaculada
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container_end_page 719
container_issue 3
container_start_page 715
container_title Journal of hazardous materials
container_volume 144
creator Cabeza, Adelaida
Urtiaga, Ane
Rivero, María-José
Ortiz, Inmaculada
description The feasibility of removing ammonium from landfill leachates by electrochemical oxidation was studied. Raw leachates and biologically/physico-chemically pretreated leachates from a municipal landfill site were treated. Boron doped diamond was used as anode and stainless steel as cathode, both electrodes with an area of 70 cm 2. The effects of the applied current density (15–90 mA cm −2), the initial ammonium concentration (480–2000 mg L −1), and the initial chloride concentration were experimentally studied. Total ammonium removal was obtained after 360 min of processing and almost half of the initial ammonium nitrogen was oxidized to nitrate. On the other hand, the concentration of chloride enhanced the rate of ammonium oxidation. In addition, the amount of N–NH 4 + transformed into N–NO 3 − decreased when additional chloride was provided.
doi_str_mv 10.1016/j.jhazmat.2007.01.106
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subjects Ammonium removal
Applied sciences
Boron
Chemical engineering
Diamond
Electrochemistry
Electrodes
Electrooxidation
Exact sciences and technology
General treatment and storage processes
Leachate treatment
Oxidation-Reduction
Pollution
Quaternary Ammonium Compounds - chemistry
Quaternary Ammonium Compounds - isolation & purification
Reactors
Refuse Disposal
Wastes
Water Pollutants, Chemical - chemistry
Water Pollutants, Chemical - isolation & purification
Water Purification - methods
title Ammonium removal from landfill leachate by anodic oxidation
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