Property modification of poly(methyl methacrylate) through copolymerization with fluorinated aryl methacrylate monomers

Property modification of poly(methyl methacrylate) through copolymerization with fluorinated aryl methacrylate monomers

Copolymers of methyl methacrylate (MMA) with 2,3,5,6‐tetrafluorophenyl methacrylate (TFPMA), pentafluorophenyl methacrylate (PFPMA), and 4‐trifluoromethyl‐2,3,5,6‐tetrafluorophenyl methacrylate (TFMPMA) were investigated. All the three systems showed a random copolymerization character. The composit...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Polymers for advanced technologies 2007-06, Vol.18 (6), p.453-457
Hauptverfasser: Teng, Hongxiang, Yang, Liang, Mikes, Frantisek, Koike, Yasuhiro, Okamoto, Yoshiyuki
Format: Artikel
Sprache:eng
Schlagworte:
copolymerization
fluoropolymers
modification
poly(methyl methacrylate)
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 457
container_issue 6
container_start_page 453
container_title Polymers for advanced technologies
container_volume 18
creator Teng, Hongxiang
Yang, Liang
Mikes, Frantisek
Koike, Yasuhiro
Okamoto, Yoshiyuki
description Copolymers of methyl methacrylate (MMA) with 2,3,5,6‐tetrafluorophenyl methacrylate (TFPMA), pentafluorophenyl methacrylate (PFPMA), and 4‐trifluoromethyl‐2,3,5,6‐tetrafluorophenyl methacrylate (TFMPMA) were investigated. All the three systems showed a random copolymerization character. The composition, glass transition temperature (Tg), and refractive index of the copolymers obtained were studied. Tgs of TFPMA/MMA and PFPMA/MMA copolymers were found to deviate positively from the Gordon–Taylor equation. However, Tgs of TFMPMA/MMA copolymers were well fit with the Gordon–Taylor equation. These results indicated the existence of interaction between MMA and either TFPMA or PFPMA units in copolymers. This interaction resulted in the enhancement of the Tg of MMA polymers through the copolymerization with TFPMA and PFPMA. The refractive index and the light transmittance of copolymers were close to those of PMMA. Copyright © 2007 John Wiley & Sons, Ltd.
doi_str_mv 10.1002/pat.884
format Article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_29984653</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>29984653</sourcerecordid><originalsourceid>FETCH-LOGICAL-c3304-6fc65692026ce2fd35bba69a6a8b9902741c22d86764ee7c326cc832a3a735bc3</originalsourceid><addsrcrecordid>eNp10E1LwzAYB_AiCs4pfoWefEE689ImzXEM3ZQxd5h4DFma2mi71CRj1k9vRsWD4OkJ5PdPeP5RdA7BCAKAblvhR3meHkQDCBhLYJbDw_05RQmFKT2OTpx7AyDcMTqIdktrWmV9Fzem0KWWwmuziU0Zt6burhrlq66O90NI29XCq-vYV9ZsX6tYmr1plNVffWqnfRWX9dZYvQmyiIX9Ew6_bExIuNPoqBS1U2c_cxg939-tJrNk_jR9mIznicQYpAkpJckIQwARqVBZ4Gy9FoQJIvI1YwDRFEqEipxQkipFJQ5O5hgJLGiwEg-ji_7d1pqPrXKeN9pJVddio8zWccRYnpIMB3jZQ2mNc1aVvLW6CQtwCPi-WB6K5aHYIG96udO16v5jfDle9TrptXZeff5qYd85oZhm_GUx5Vn2-AjhbMEh_ga4A4v2</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>29984653</pqid></control><display><type>article</type><title>Property modification of poly(methyl methacrylate) through copolymerization with fluorinated aryl methacrylate monomers</title><source>Wiley Online Library Journals Frontfile Complete</source><creator>Teng, Hongxiang ; Yang, Liang ; Mikes, Frantisek ; Koike, Yasuhiro ; Okamoto, Yoshiyuki</creator><creatorcontrib>Teng, Hongxiang ; Yang, Liang ; Mikes, Frantisek ; Koike, Yasuhiro ; Okamoto, Yoshiyuki</creatorcontrib><description>Copolymers of methyl methacrylate (MMA) with 2,3,5,6‐tetrafluorophenyl methacrylate (TFPMA), pentafluorophenyl methacrylate (PFPMA), and 4‐trifluoromethyl‐2,3,5,6‐tetrafluorophenyl methacrylate (TFMPMA) were investigated. All the three systems showed a random copolymerization character. The composition, glass transition temperature (Tg), and refractive index of the copolymers obtained were studied. Tgs of TFPMA/MMA and PFPMA/MMA copolymers were found to deviate positively from the Gordon–Taylor equation. However, Tgs of TFMPMA/MMA copolymers were well fit with the Gordon–Taylor equation. These results indicated the existence of interaction between MMA and either TFPMA or PFPMA units in copolymers. This interaction resulted in the enhancement of the Tg of MMA polymers through the copolymerization with TFPMA and PFPMA. The refractive index and the light transmittance of copolymers were close to those of PMMA. Copyright © 2007 John Wiley &amp; Sons, Ltd.</description><identifier>ISSN: 1042-7147</identifier><identifier>EISSN: 1099-1581</identifier><identifier>DOI: 10.1002/pat.884</identifier><language>eng</language><publisher>Chichester, UK: John Wiley &amp; Sons, Ltd</publisher><subject>copolymerization ; fluoropolymers ; modification ; poly(methyl methacrylate)</subject><ispartof>Polymers for advanced technologies, 2007-06, Vol.18 (6), p.453-457</ispartof><rights>Copyright © 2007 John Wiley &amp; Sons, Ltd.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3304-6fc65692026ce2fd35bba69a6a8b9902741c22d86764ee7c326cc832a3a735bc3</citedby><cites>FETCH-LOGICAL-c3304-6fc65692026ce2fd35bba69a6a8b9902741c22d86764ee7c326cc832a3a735bc3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fpat.884$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fpat.884$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27923,27924,45573,45574</link.rule.ids></links><search><creatorcontrib>Teng, Hongxiang</creatorcontrib><creatorcontrib>Yang, Liang</creatorcontrib><creatorcontrib>Mikes, Frantisek</creatorcontrib><creatorcontrib>Koike, Yasuhiro</creatorcontrib><creatorcontrib>Okamoto, Yoshiyuki</creatorcontrib><title>Property modification of poly(methyl methacrylate) through copolymerization with fluorinated aryl methacrylate monomers</title><title>Polymers for advanced technologies</title><addtitle>Polym. Adv. Technol</addtitle><description>Copolymers of methyl methacrylate (MMA) with 2,3,5,6‐tetrafluorophenyl methacrylate (TFPMA), pentafluorophenyl methacrylate (PFPMA), and 4‐trifluoromethyl‐2,3,5,6‐tetrafluorophenyl methacrylate (TFMPMA) were investigated. All the three systems showed a random copolymerization character. The composition, glass transition temperature (Tg), and refractive index of the copolymers obtained were studied. Tgs of TFPMA/MMA and PFPMA/MMA copolymers were found to deviate positively from the Gordon–Taylor equation. However, Tgs of TFMPMA/MMA copolymers were well fit with the Gordon–Taylor equation. These results indicated the existence of interaction between MMA and either TFPMA or PFPMA units in copolymers. This interaction resulted in the enhancement of the Tg of MMA polymers through the copolymerization with TFPMA and PFPMA. The refractive index and the light transmittance of copolymers were close to those of PMMA. Copyright © 2007 John Wiley &amp; Sons, Ltd.</description><subject>copolymerization</subject><subject>fluoropolymers</subject><subject>modification</subject><subject>poly(methyl methacrylate)</subject><issn>1042-7147</issn><issn>1099-1581</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2007</creationdate><recordtype>article</recordtype><recordid>eNp10E1LwzAYB_AiCs4pfoWefEE689ImzXEM3ZQxd5h4DFma2mi71CRj1k9vRsWD4OkJ5PdPeP5RdA7BCAKAblvhR3meHkQDCBhLYJbDw_05RQmFKT2OTpx7AyDcMTqIdktrWmV9Fzem0KWWwmuziU0Zt6burhrlq66O90NI29XCq-vYV9ZsX6tYmr1plNVffWqnfRWX9dZYvQmyiIX9Ew6_bExIuNPoqBS1U2c_cxg939-tJrNk_jR9mIznicQYpAkpJckIQwARqVBZ4Gy9FoQJIvI1YwDRFEqEipxQkipFJQ5O5hgJLGiwEg-ji_7d1pqPrXKeN9pJVddio8zWccRYnpIMB3jZQ2mNc1aVvLW6CQtwCPi-WB6K5aHYIG96udO16v5jfDle9TrptXZeff5qYd85oZhm_GUx5Vn2-AjhbMEh_ga4A4v2</recordid><startdate>200706</startdate><enddate>200706</enddate><creator>Teng, Hongxiang</creator><creator>Yang, Liang</creator><creator>Mikes, Frantisek</creator><creator>Koike, Yasuhiro</creator><creator>Okamoto, Yoshiyuki</creator><general>John Wiley &amp; Sons, Ltd</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>200706</creationdate><title>Property modification of poly(methyl methacrylate) through copolymerization with fluorinated aryl methacrylate monomers</title><author>Teng, Hongxiang ; Yang, Liang ; Mikes, Frantisek ; Koike, Yasuhiro ; Okamoto, Yoshiyuki</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3304-6fc65692026ce2fd35bba69a6a8b9902741c22d86764ee7c326cc832a3a735bc3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2007</creationdate><topic>copolymerization</topic><topic>fluoropolymers</topic><topic>modification</topic><topic>poly(methyl methacrylate)</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Teng, Hongxiang</creatorcontrib><creatorcontrib>Yang, Liang</creatorcontrib><creatorcontrib>Mikes, Frantisek</creatorcontrib><creatorcontrib>Koike, Yasuhiro</creatorcontrib><creatorcontrib>Okamoto, Yoshiyuki</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Polymers for advanced technologies</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Teng, Hongxiang</au><au>Yang, Liang</au><au>Mikes, Frantisek</au><au>Koike, Yasuhiro</au><au>Okamoto, Yoshiyuki</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Property modification of poly(methyl methacrylate) through copolymerization with fluorinated aryl methacrylate monomers</atitle><jtitle>Polymers for advanced technologies</jtitle><addtitle>Polym. Adv. Technol</addtitle><date>2007-06</date><risdate>2007</risdate><volume>18</volume><issue>6</issue><spage>453</spage><epage>457</epage><pages>453-457</pages><issn>1042-7147</issn><eissn>1099-1581</eissn><abstract>Copolymers of methyl methacrylate (MMA) with 2,3,5,6‐tetrafluorophenyl methacrylate (TFPMA), pentafluorophenyl methacrylate (PFPMA), and 4‐trifluoromethyl‐2,3,5,6‐tetrafluorophenyl methacrylate (TFMPMA) were investigated. All the three systems showed a random copolymerization character. The composition, glass transition temperature (Tg), and refractive index of the copolymers obtained were studied. Tgs of TFPMA/MMA and PFPMA/MMA copolymers were found to deviate positively from the Gordon–Taylor equation. However, Tgs of TFMPMA/MMA copolymers were well fit with the Gordon–Taylor equation. These results indicated the existence of interaction between MMA and either TFPMA or PFPMA units in copolymers. This interaction resulted in the enhancement of the Tg of MMA polymers through the copolymerization with TFPMA and PFPMA. The refractive index and the light transmittance of copolymers were close to those of PMMA. Copyright © 2007 John Wiley &amp; Sons, Ltd.</abstract><cop>Chichester, UK</cop><pub>John Wiley &amp; Sons, Ltd</pub><doi>10.1002/pat.884</doi><tpages>5</tpages></addata></record>
fulltext fulltext
identifier ISSN: 1042-7147
ispartof Polymers for advanced technologies, 2007-06, Vol.18 (6), p.453-457
issn 1042-7147
1099-1581
language eng
recordid cdi_proquest_miscellaneous_29984653
source Wiley Online Library Journals Frontfile Complete
subjects copolymerization
fluoropolymers
modification
poly(methyl methacrylate)
title Property modification of poly(methyl methacrylate) through copolymerization with fluorinated aryl methacrylate monomers
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-09T06%3A07%3A13IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Property%20modification%20of%20poly(methyl%20methacrylate)%20through%20copolymerization%20with%20fluorinated%20aryl%20methacrylate%20monomers&rft.jtitle=Polymers%20for%20advanced%20technologies&rft.au=Teng,%20Hongxiang&rft.date=2007-06&rft.volume=18&rft.issue=6&rft.spage=453&rft.epage=457&rft.pages=453-457&rft.issn=1042-7147&rft.eissn=1099-1581&rft_id=info:doi/10.1002/pat.884&rft_dat=%3Cproquest_cross%3E29984653%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=29984653&rft_id=info:pmid/&rfr_iscdi=true