Effects of clay dispersion and content on the rheological, mechanical properties, and flame retardance of HDPE/clay nanocomposites

Full exfoliation of clay/high density polyethylene (HDPE) nanocomposites was successfully achieved with the aid of maleated HDPE (PE‐g‐MAn), by melt blending in a twin‐screw extruder employing a long residence time configuration. The morphology of the composites was determined using wide‐angle X‐ray...

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Veröffentlicht in:Journal of applied polymer science 2007-08, Vol.105 (4), p.1993-1999
Hauptverfasser: Lee, Y. H., Park, Chul B., Sain, M., Kontopoulou, M., Zheng, Wenge
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container_end_page 1999
container_issue 4
container_start_page 1993
container_title Journal of applied polymer science
container_volume 105
creator Lee, Y. H.
Park, Chul B.
Sain, M.
Kontopoulou, M.
Zheng, Wenge
description Full exfoliation of clay/high density polyethylene (HDPE) nanocomposites was successfully achieved with the aid of maleated HDPE (PE‐g‐MAn), by melt blending in a twin‐screw extruder employing a long residence time configuration. The morphology of the composites was determined using wide‐angle X‐ray diffraction and transmission electron microscopy. The effects of clay content and state of clay dispersion on the rheological, tensile properties, and flame retardancy of nanocomposites containing very small amounts of clay, in the range of 0.05–1.0 wt %, were investigated in this study. It was demonstrated that achieving a higher degree of exfoliation for nanosized clay particles is key to enhancing the rheological, mechanical, and flame retarding properties even when small amounts of clay (less than 1%) are used. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2007
doi_str_mv 10.1002/app.26403
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source Wiley Online Library Journals Frontfile Complete
subjects Applied sciences
Composites
Exact sciences and technology
flame retardance
Forms of application and semi-finished materials
mechanical properties
nanocomposites
organoclay
polyethylene (PE)
Polymer industry, paints, wood
Technology of polymers
title Effects of clay dispersion and content on the rheological, mechanical properties, and flame retardance of HDPE/clay nanocomposites
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