Thermal electron capture by some halopropanes
Thermal electron attachment rate constants for CF 3CHClCH 3, CF 2ClCFClCF 3 and CBrF 2CH 2CH 2Br have been measured with electron swarm method. Corresponding rate constants are equal to 7.6×10 −11, 5.5×10 −9 and 1.5×10 −8 cm 3 molecule −1 s −1, respectively. The dissociative electron attachment (DEA...
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| Veröffentlicht in: | Radiation physics and chemistry (Oxford, England : 1993) England : 1993), 2007-06, Vol.76 (6), p.1017-1025 |
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| container_title | Radiation physics and chemistry (Oxford, England : 1993) |
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| creator | Barszczewska, W. Kopyra, J. Wnorowska, J. Foryś, M. Szamrej, I. Asfandiarov, N.L. Pshenichnyuk, S.A. Fal’ko, V.S. |
| description | Thermal electron attachment rate constants for CF
3CHClCH
3, CF
2ClCFClCF
3 and CBrF
2CH
2CH
2Br have been measured with electron swarm method. Corresponding rate constants are equal to 7.6×10
−11, 5.5×10
−9 and 1.5×10
−8
cm
3
molecule
−1
s
−1, respectively. The dissociative electron attachment (DEA) spectra for nine haloalkanes have been determined using negative ion mass spectrometry. The correlation between rate constants, position of the DEA peaks and vertical attachment energy (VAE) available in literature has been demonstrated. |
| doi_str_mv | 10.1016/j.radphyschem.2006.10.003 |
| format | Article |
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3CHClCH
3, CF
2ClCFClCF
3 and CBrF
2CH
2CH
2Br have been measured with electron swarm method. Corresponding rate constants are equal to 7.6×10
−11, 5.5×10
−9 and 1.5×10
−8
cm
3
molecule
−1
s
−1, respectively. The dissociative electron attachment (DEA) spectra for nine haloalkanes have been determined using negative ion mass spectrometry. The correlation between rate constants, position of the DEA peaks and vertical attachment energy (VAE) available in literature has been demonstrated.</description><identifier>ISSN: 0969-806X</identifier><identifier>EISSN: 1879-0895</identifier><identifier>DOI: 10.1016/j.radphyschem.2006.10.003</identifier><language>eng</language><publisher>Elsevier Ltd</publisher><subject>Dissociative electron attachment ; Electron swarm ; Halopropanes ; Negative ion mass spectra ; Rate constants</subject><ispartof>Radiation physics and chemistry (Oxford, England : 1993), 2007-06, Vol.76 (6), p.1017-1025</ispartof><rights>2006 Elsevier Ltd</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c352t-63cdc4831fade47ad92fbe18343bf71ec9da01b6d6bad06e1e85668dc36fbd33</citedby><cites>FETCH-LOGICAL-c352t-63cdc4831fade47ad92fbe18343bf71ec9da01b6d6bad06e1e85668dc36fbd33</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.radphyschem.2006.10.003$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3548,27923,27924,45994</link.rule.ids></links><search><creatorcontrib>Barszczewska, W.</creatorcontrib><creatorcontrib>Kopyra, J.</creatorcontrib><creatorcontrib>Wnorowska, J.</creatorcontrib><creatorcontrib>Foryś, M.</creatorcontrib><creatorcontrib>Szamrej, I.</creatorcontrib><creatorcontrib>Asfandiarov, N.L.</creatorcontrib><creatorcontrib>Pshenichnyuk, S.A.</creatorcontrib><creatorcontrib>Fal’ko, V.S.</creatorcontrib><title>Thermal electron capture by some halopropanes</title><title>Radiation physics and chemistry (Oxford, England : 1993)</title><description>Thermal electron attachment rate constants for CF
3CHClCH
3, CF
2ClCFClCF
3 and CBrF
2CH
2CH
2Br have been measured with electron swarm method. Corresponding rate constants are equal to 7.6×10
−11, 5.5×10
−9 and 1.5×10
−8
cm
3
molecule
−1
s
−1, respectively. The dissociative electron attachment (DEA) spectra for nine haloalkanes have been determined using negative ion mass spectrometry. The correlation between rate constants, position of the DEA peaks and vertical attachment energy (VAE) available in literature has been demonstrated.</description><subject>Dissociative electron attachment</subject><subject>Electron swarm</subject><subject>Halopropanes</subject><subject>Negative ion mass spectra</subject><subject>Rate constants</subject><issn>0969-806X</issn><issn>1879-0895</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2007</creationdate><recordtype>article</recordtype><recordid>eNqNkE1LxDAQhoMouK7-h3rx1jpptmlylMUvWPCyB28hTaa0S9vUpCv035tSDx49DAMz7zsfDyH3FDIKlD-eMq_t2MzBNNhnOQCP9QyAXZANFaVMQcjikmxAcpkK4J_X5CaEEwCUomAbkh4b9L3uEuzQTN4NidHjdPaYVHMSXI9Jozs3ejfqAcMtuap1F_DuN2_J8eX5uH9LDx-v7_unQ2pYkU8pZ8aanWC01hZ3pbYyryukgu1YVZcUjbQaaMUtr7QFjhRFwbmwhvG6soxtycM6Nu79OmOYVN8Gg10Xb3DnoHIpizJGFMpVaLwLwWOtRt_22s-Kglr4qJP6w0ctfJZW5BO9-9WL8ZHvFr0KpsXBoG19RKGsa_8x5Qc3rXYA</recordid><startdate>20070601</startdate><enddate>20070601</enddate><creator>Barszczewska, W.</creator><creator>Kopyra, J.</creator><creator>Wnorowska, J.</creator><creator>Foryś, M.</creator><creator>Szamrej, I.</creator><creator>Asfandiarov, N.L.</creator><creator>Pshenichnyuk, S.A.</creator><creator>Fal’ko, V.S.</creator><general>Elsevier Ltd</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20070601</creationdate><title>Thermal electron capture by some halopropanes</title><author>Barszczewska, W. ; Kopyra, J. ; Wnorowska, J. ; Foryś, M. ; Szamrej, I. ; Asfandiarov, N.L. ; Pshenichnyuk, S.A. ; Fal’ko, V.S.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c352t-63cdc4831fade47ad92fbe18343bf71ec9da01b6d6bad06e1e85668dc36fbd33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2007</creationdate><topic>Dissociative electron attachment</topic><topic>Electron swarm</topic><topic>Halopropanes</topic><topic>Negative ion mass spectra</topic><topic>Rate constants</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Barszczewska, W.</creatorcontrib><creatorcontrib>Kopyra, J.</creatorcontrib><creatorcontrib>Wnorowska, J.</creatorcontrib><creatorcontrib>Foryś, M.</creatorcontrib><creatorcontrib>Szamrej, I.</creatorcontrib><creatorcontrib>Asfandiarov, N.L.</creatorcontrib><creatorcontrib>Pshenichnyuk, S.A.</creatorcontrib><creatorcontrib>Fal’ko, V.S.</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Radiation physics and chemistry (Oxford, England : 1993)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Barszczewska, W.</au><au>Kopyra, J.</au><au>Wnorowska, J.</au><au>Foryś, M.</au><au>Szamrej, I.</au><au>Asfandiarov, N.L.</au><au>Pshenichnyuk, S.A.</au><au>Fal’ko, V.S.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Thermal electron capture by some halopropanes</atitle><jtitle>Radiation physics and chemistry (Oxford, England : 1993)</jtitle><date>2007-06-01</date><risdate>2007</risdate><volume>76</volume><issue>6</issue><spage>1017</spage><epage>1025</epage><pages>1017-1025</pages><issn>0969-806X</issn><eissn>1879-0895</eissn><abstract>Thermal electron attachment rate constants for CF
3CHClCH
3, CF
2ClCFClCF
3 and CBrF
2CH
2CH
2Br have been measured with electron swarm method. Corresponding rate constants are equal to 7.6×10
−11, 5.5×10
−9 and 1.5×10
−8
cm
3
molecule
−1
s
−1, respectively. The dissociative electron attachment (DEA) spectra for nine haloalkanes have been determined using negative ion mass spectrometry. The correlation between rate constants, position of the DEA peaks and vertical attachment energy (VAE) available in literature has been demonstrated.</abstract><pub>Elsevier Ltd</pub><doi>10.1016/j.radphyschem.2006.10.003</doi><tpages>9</tpages></addata></record> |
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| ispartof | Radiation physics and chemistry (Oxford, England : 1993), 2007-06, Vol.76 (6), p.1017-1025 |
| issn | 0969-806X 1879-0895 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_29957995 |
| source | ScienceDirect Journals (5 years ago - present) |
| subjects | Dissociative electron attachment Electron swarm Halopropanes Negative ion mass spectra Rate constants |
| title | Thermal electron capture by some halopropanes |
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