Controllable synthesis of ZnS holely microspheres in solution containing ethylenediamine and CS2
ZnS holey microspheres (HMSs) were prepared by reacting ZnSO₄ with sulfide source from CS₂ and ethylenediamine at 50 °C, then aging at room temperature. The synthesized HMSs were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and...
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| Veröffentlicht in: | Journal of materials science 2007-09, Vol.42 (17), p.7245-7250 |
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| container_title | Journal of materials science |
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| creator | Lingang, Li Yu, Tang |
| description | ZnS holey microspheres (HMSs) were prepared by reacting ZnSO₄ with sulfide source from CS₂ and ethylenediamine at 50 °C, then aging at room temperature. The synthesized HMSs were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and UV–visible absorption measurement. The results showed that the holes were formed by gas of H₂S, and the small ZnS HMSs were formed by particles reaggregating with the aid of ethylenediamine. In addition, the size- and shape-controlled synthesis of ZnS HMSs was achieved by varying the process parameters, such as the aging time of the final solution, the molar ratio of CS₂ and ethylenediamine, and so on. A gas obtruding mechanism was proposed. |
| doi_str_mv | 10.1007/s10853-007-1553-6 |
| format | Article |
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The synthesized HMSs were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and UV–visible absorption measurement. The results showed that the holes were formed by gas of H₂S, and the small ZnS HMSs were formed by particles reaggregating with the aid of ethylenediamine. In addition, the size- and shape-controlled synthesis of ZnS HMSs was achieved by varying the process parameters, such as the aging time of the final solution, the molar ratio of CS₂ and ethylenediamine, and so on. A gas obtruding mechanism was proposed.</description><identifier>ISSN: 0022-2461</identifier><identifier>EISSN: 1573-4803</identifier><identifier>DOI: 10.1007/s10853-007-1553-6</identifier><identifier>CODEN: JMTSAS</identifier><language>eng</language><publisher>Heidelberg: Kluwer Academic Publishers-Plenum Publishers</publisher><subject>absorption ; ambient temperature ; carbon disulfide ; Chemistry ; Colloidal state and disperse state ; Electron microscopes ; Ethylenediamine ; Exact sciences and technology ; General and physical chemistry ; Hydrogen sulfide ; Materials science ; Microscopy ; Microspheres ; Physical and chemical studies. Granulometry. Electrokinetic phenomena ; Porous materials ; Process parameters ; Scanning electron microscopy ; Stability ; Synthesis ; Transmission electron microscopy ; X-ray diffraction</subject><ispartof>Journal of materials science, 2007-09, Vol.42 (17), p.7245-7250</ispartof><rights>2008 INIST-CNRS</rights><rights>Springer Science+Business Media, LLC 2007.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c424t-892417c9be92533915fb02e1c58e9d75498359d182e38bc746616cd2a74494453</citedby><cites>FETCH-LOGICAL-c424t-892417c9be92533915fb02e1c58e9d75498359d182e38bc746616cd2a74494453</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=18930322$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Lingang, Li</creatorcontrib><creatorcontrib>Yu, Tang</creatorcontrib><title>Controllable synthesis of ZnS holely microspheres in solution containing ethylenediamine and CS2</title><title>Journal of materials science</title><description>ZnS holey microspheres (HMSs) were prepared by reacting ZnSO₄ with sulfide source from CS₂ and ethylenediamine at 50 °C, then aging at room temperature. The synthesized HMSs were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and UV–visible absorption measurement. The results showed that the holes were formed by gas of H₂S, and the small ZnS HMSs were formed by particles reaggregating with the aid of ethylenediamine. In addition, the size- and shape-controlled synthesis of ZnS HMSs was achieved by varying the process parameters, such as the aging time of the final solution, the molar ratio of CS₂ and ethylenediamine, and so on. A gas obtruding mechanism was proposed.</description><subject>absorption</subject><subject>ambient temperature</subject><subject>carbon disulfide</subject><subject>Chemistry</subject><subject>Colloidal state and disperse state</subject><subject>Electron microscopes</subject><subject>Ethylenediamine</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Hydrogen sulfide</subject><subject>Materials science</subject><subject>Microscopy</subject><subject>Microspheres</subject><subject>Physical and chemical studies. Granulometry. Electrokinetic phenomena</subject><subject>Porous materials</subject><subject>Process parameters</subject><subject>Scanning electron microscopy</subject><subject>Stability</subject><subject>Synthesis</subject><subject>Transmission electron microscopy</subject><subject>X-ray diffraction</subject><issn>0022-2461</issn><issn>1573-4803</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2007</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNpdkU-LFDEQxYMoOK5-AE8GRG-tSSXpJEcZ_AcLHsa9eImZdPVOlkwyJj2H-fammQXBU73D7z2qXhHymrMPnDH9sXFmlBi6HLjqYnxCNlxpMUjDxFOyYQxgADny5-RFaw-MMaWBb8jvbclLLSn5fULaLnk5YIuNlpn-yjt6KAnThR5jqKWdDlix0ZhpK-m8xJJp6G4fc8z3FJfDJWHGKfpjzEh9nuh2By_Js9mnhq8e5w25-_L55_bbcPvj6_ftp9shSJDLYCxIroPdowUlhOVq3jNAHpRBO2klrRHKTtwACrMPWo4jH8MEXktppVTihry_5p5q-XPGtrhjbAH7YRnLuTmwttdhV_Dtf-BDOdfcd3MAymrQQo6d4ldqPbxVnN2pxqOvF8eZWxt318bdKtfG3ep595jsW_Bprj6H2P4ZjRVMAHTuzZWbfXH-vnbmbgeMj-tXpOFK_AXAe4jS</recordid><startdate>20070901</startdate><enddate>20070901</enddate><creator>Lingang, Li</creator><creator>Yu, Tang</creator><general>Kluwer Academic Publishers-Plenum Publishers</general><general>Springer</general><general>Springer Nature B.V</general><scope>FBQ</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>L6V</scope><scope>M7S</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20070901</creationdate><title>Controllable synthesis of ZnS holely microspheres in solution containing ethylenediamine and CS2</title><author>Lingang, Li ; Yu, Tang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c424t-892417c9be92533915fb02e1c58e9d75498359d182e38bc746616cd2a74494453</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2007</creationdate><topic>absorption</topic><topic>ambient temperature</topic><topic>carbon disulfide</topic><topic>Chemistry</topic><topic>Colloidal state and disperse state</topic><topic>Electron microscopes</topic><topic>Ethylenediamine</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>Hydrogen sulfide</topic><topic>Materials science</topic><topic>Microscopy</topic><topic>Microspheres</topic><topic>Physical and chemical studies. Granulometry. Electrokinetic phenomena</topic><topic>Porous materials</topic><topic>Process parameters</topic><topic>Scanning electron microscopy</topic><topic>Stability</topic><topic>Synthesis</topic><topic>Transmission electron microscopy</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lingang, Li</creatorcontrib><creatorcontrib>Yu, Tang</creatorcontrib><collection>AGRIS</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>ProQuest Engineering Collection</collection><collection>Engineering Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Engineering Collection</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of materials science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lingang, Li</au><au>Yu, Tang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Controllable synthesis of ZnS holely microspheres in solution containing ethylenediamine and CS2</atitle><jtitle>Journal of materials science</jtitle><date>2007-09-01</date><risdate>2007</risdate><volume>42</volume><issue>17</issue><spage>7245</spage><epage>7250</epage><pages>7245-7250</pages><issn>0022-2461</issn><eissn>1573-4803</eissn><coden>JMTSAS</coden><abstract>ZnS holey microspheres (HMSs) were prepared by reacting ZnSO₄ with sulfide source from CS₂ and ethylenediamine at 50 °C, then aging at room temperature. The synthesized HMSs were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and UV–visible absorption measurement. The results showed that the holes were formed by gas of H₂S, and the small ZnS HMSs were formed by particles reaggregating with the aid of ethylenediamine. In addition, the size- and shape-controlled synthesis of ZnS HMSs was achieved by varying the process parameters, such as the aging time of the final solution, the molar ratio of CS₂ and ethylenediamine, and so on. A gas obtruding mechanism was proposed.</abstract><cop>Heidelberg</cop><pub>Kluwer Academic Publishers-Plenum Publishers</pub><doi>10.1007/s10853-007-1553-6</doi><tpages>6</tpages></addata></record> |
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| subjects | absorption ambient temperature carbon disulfide Chemistry Colloidal state and disperse state Electron microscopes Ethylenediamine Exact sciences and technology General and physical chemistry Hydrogen sulfide Materials science Microscopy Microspheres Physical and chemical studies. Granulometry. Electrokinetic phenomena Porous materials Process parameters Scanning electron microscopy Stability Synthesis Transmission electron microscopy X-ray diffraction |
| title | Controllable synthesis of ZnS holely microspheres in solution containing ethylenediamine and CS2 |
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