Study of isothermal decomposition of lanthanide mixed complexes with 2,2,6,6-tetramethyl-3,5-heptanodione and 1,10-phenanthroline
Isothermal decomposition kinetic of three lanthanide mixed complexes with the general formula of Ln(thd)3phen (where Ln=Nd, Sm or Er, thd=2,2,6,6-tetramethyl-3,5-heptanodione and phen=1,10-phenanthroline) has been studied in this work. The powders were characterized by their melting point, elemental...
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container_title | Journal of thermal analysis and calorimetry |
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creator | LOPES, W. S MORAIS, Crisiene R. S SOUZA, A. G LEITE, V. D FIRMO, B. D. De A |
description | Isothermal decomposition kinetic of three lanthanide mixed complexes with the general formula of Ln(thd)3phen (where Ln=Nd, Sm or Er, thd=2,2,6,6-tetramethyl-3,5-heptanodione and phen=1,10-phenanthroline) has been studied in this work. The powders were characterized by their melting point, elemental analysis, FTIR spectroscopy and thermogravimetry. The isothermal TG curves have been recorded under the same conditions at 265-285, 265-285 and 250-270 deg C for Nd(thd)3phen, Sm(thd)3phen and Er(thd)3phen, respectively. |
doi_str_mv | 10.1007/s10973-006-7785-x |
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The isothermal TG curves have been recorded under the same conditions at 265-285, 265-285 and 250-270 deg C for Nd(thd)3phen, Sm(thd)3phen and Er(thd)3phen, respectively.</description><identifier>ISSN: 1388-6150</identifier><identifier>EISSN: 1588-2926</identifier><identifier>EISSN: 1572-8943</identifier><identifier>DOI: 10.1007/s10973-006-7785-x</identifier><language>eng</language><publisher>Dordrecht: Springer</publisher><subject>Chemistry ; Coordination compounds ; Exact sciences and technology ; Inorganic chemistry and origins of life ; Preparations and properties</subject><ispartof>Journal of thermal analysis and calorimetry, 2007-03, Vol.87 (3), p.841-845</ispartof><rights>2007 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c306t-33b7d640861b721b83fb6ae9c8bb1fb3cf1a5c5371a8559d115d76399e44184d3</citedby><cites>FETCH-LOGICAL-c306t-33b7d640861b721b83fb6ae9c8bb1fb3cf1a5c5371a8559d115d76399e44184d3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>309,310,314,776,780,785,786,23909,23910,25118,27901,27902</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=18642189$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>LOPES, W. 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The isothermal TG curves have been recorded under the same conditions at 265-285, 265-285 and 250-270 deg C for Nd(thd)3phen, Sm(thd)3phen and Er(thd)3phen, respectively.</description><subject>Chemistry</subject><subject>Coordination compounds</subject><subject>Exact sciences and technology</subject><subject>Inorganic chemistry and origins of life</subject><subject>Preparations and properties</subject><issn>1388-6150</issn><issn>1588-2926</issn><issn>1572-8943</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2007</creationdate><recordtype>article</recordtype><recordid>eNpFkEFr3TAQhE1JoUnaH9CbLs3JSrWWJUvHEJI0EOih7VnI0hqr2JYr6ZH3jv3ntXmBnnZgZj7YqarPwG6Bse5rBqY7ThmTtOuUoMd31SUIpWijG3mxab5pCYJ9qK5y_s0Y05rBZfX3Rzn4E4kDCTmWEdNsJ-LRxXmNOZQQl92b7FJGuwSPZA5H9GT3JzxiJq-hjKSpm1rWkhYsyc5YxtNEeS3oiGuxS_QbBoldPIEaGF1HXHZgilNY8GP1frBTxk9v97r69fjw8_4bffn-9Hx_90IdZ7JQzvvOy5YpCX3XQK_40EuL2qm-h6HnbgArnOAdWCWE9gDCd5JrjW0LqvX8uro5c9cU_xwwFzOH7HDafsN4yKbRutFMyy0I56BLMeeEg1lTmG06GWBmH9ucxzbb2GYf2xy3zpc3uM3OTkOyiwv5f1HJtgGl-T-rA4BC</recordid><startdate>20070301</startdate><enddate>20070301</enddate><creator>LOPES, W. 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De A</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Study of isothermal decomposition of lanthanide mixed complexes with 2,2,6,6-tetramethyl-3,5-heptanodione and 1,10-phenanthroline</atitle><jtitle>Journal of thermal analysis and calorimetry</jtitle><date>2007-03-01</date><risdate>2007</risdate><volume>87</volume><issue>3</issue><spage>841</spage><epage>845</epage><pages>841-845</pages><issn>1388-6150</issn><eissn>1588-2926</eissn><eissn>1572-8943</eissn><abstract>Isothermal decomposition kinetic of three lanthanide mixed complexes with the general formula of Ln(thd)3phen (where Ln=Nd, Sm or Er, thd=2,2,6,6-tetramethyl-3,5-heptanodione and phen=1,10-phenanthroline) has been studied in this work. The powders were characterized by their melting point, elemental analysis, FTIR spectroscopy and thermogravimetry. The isothermal TG curves have been recorded under the same conditions at 265-285, 265-285 and 250-270 deg C for Nd(thd)3phen, Sm(thd)3phen and Er(thd)3phen, respectively.</abstract><cop>Dordrecht</cop><pub>Springer</pub><doi>10.1007/s10973-006-7785-x</doi><tpages>5</tpages></addata></record> |
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subjects | Chemistry Coordination compounds Exact sciences and technology Inorganic chemistry and origins of life Preparations and properties |
title | Study of isothermal decomposition of lanthanide mixed complexes with 2,2,6,6-tetramethyl-3,5-heptanodione and 1,10-phenanthroline |
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