Study of isothermal decomposition of lanthanide mixed complexes with 2,2,6,6-tetramethyl-3,5-heptanodione and 1,10-phenanthroline

Isothermal decomposition kinetic of three lanthanide mixed complexes with the general formula of Ln(thd)3phen (where Ln=Nd, Sm or Er, thd=2,2,6,6-tetramethyl-3,5-heptanodione and phen=1,10-phenanthroline) has been studied in this work. The powders were characterized by their melting point, elemental...

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Veröffentlicht in:Journal of thermal analysis and calorimetry 2007-03, Vol.87 (3), p.841-845
Hauptverfasser: LOPES, W. S, MORAIS, Crisiene R. S, SOUZA, A. G, LEITE, V. D, FIRMO, B. D. De A
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container_issue 3
container_start_page 841
container_title Journal of thermal analysis and calorimetry
container_volume 87
creator LOPES, W. S
MORAIS, Crisiene R. S
SOUZA, A. G
LEITE, V. D
FIRMO, B. D. De A
description Isothermal decomposition kinetic of three lanthanide mixed complexes with the general formula of Ln(thd)3phen (where Ln=Nd, Sm or Er, thd=2,2,6,6-tetramethyl-3,5-heptanodione and phen=1,10-phenanthroline) has been studied in this work. The powders were characterized by their melting point, elemental analysis, FTIR spectroscopy and thermogravimetry. The isothermal TG curves have been recorded under the same conditions at 265-285, 265-285 and 250-270 deg C for Nd(thd)3phen, Sm(thd)3phen and Er(thd)3phen, respectively.
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subjects Chemistry
Coordination compounds
Exact sciences and technology
Inorganic chemistry and origins of life
Preparations and properties
title Study of isothermal decomposition of lanthanide mixed complexes with 2,2,6,6-tetramethyl-3,5-heptanodione and 1,10-phenanthroline
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