SiCN/C-ceramic composite as anode material for lithium ion batteries
The choice of electrode and electrolyte materials to design lithium batteries is limited due to the chemical reactivity of the used materials during the intercalation/deintercalation process. Amorphous silicon carbonitride (SiCN) ceramics are known to be chemically stable in corrosive environments a...
Gespeichert in:
| Veröffentlicht in: | Journal of the European Ceramic Society 2006, Vol.26 (16), p.3903-3908 |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 3908 |
|---|---|
| container_issue | 16 |
| container_start_page | 3903 |
| container_title | Journal of the European Ceramic Society |
| container_volume | 26 |
| creator | Kolb, Robert Fasel, Claudia Liebau-Kunzmann, Verena Riedel, Ralf |
| description | The choice of electrode and electrolyte materials to design lithium batteries is limited due to the chemical reactivity of the used materials during the intercalation/deintercalation process. Amorphous silicon carbonitride (SiCN) ceramics are known to be chemically stable in corrosive environments and exhibit disordered carbonaceous regions making it potentially suitable to protect graphite from exfoliation. The material studied in this work was synthesized by mixing commercial graphite powder with the crosslinked polysilazane VL20
®. Pyrolysis of the polymer/graphite compound at appropriate temperatures in inert argon atmosphere resulted in the formation of an amorphous SiCN/graphite composite material. First electrochemical investigations of pure SiCN and of the SiCN/C composite are presented here. A reversible capacity of 474
mA
hg
−1 was achieved with a sample containing 25
wt% VL20
® and 75
wt% graphite. The measured capacity exceeds that of the used graphite powder by a factor of 1.3 without any fading over 50
cycles. |
| doi_str_mv | 10.1016/j.jeurceramsoc.2006.01.009 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_29865464</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0955221906000483</els_id><sourcerecordid>29865464</sourcerecordid><originalsourceid>FETCH-LOGICAL-c385t-c77156cf4c50c64715593e8406b4cb010a4036f2746de49ab1446bad04c3d19c3</originalsourceid><addsrcrecordid>eNqNkE1Lw0AQhhdRsFb_QxD0lnQ22Wyy3qT1C4oeVPC2bCYT3JJk624q-O9NbUGPnoZhnnmHeRg755Bw4HK2Sla08UjedMFhkgLIBHgCoA7YhJdFFkuu3g7ZBFSex2nK1TE7CWEFwAtQasIWz3b-OJvHPxEWI3Td2gU7UGRCZHpXU9SZgbw1bdQ4H7V2eLebLrKujyozbCcUTtlRY9pAZ_s6Za-3Ny_z-3j5dPcwv17GmJX5EGNR8FxiIzAHlGJscpVRKUBWAivgYARkskkLIWsSylRcCFmZGgRmNVeYTdnlLnft3ceGwqA7G5Da1vTkNkGnqpS5kGIEr3YgeheCp0avve2M_9Ic9FacXum_4vRWnAauR3Hj8sX-iglo2sabHm34TShTnslyyy12HI0vf1ryOqClHqm2nnDQtbP_OfcN0PGKOg</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>29865464</pqid></control><display><type>article</type><title>SiCN/C-ceramic composite as anode material for lithium ion batteries</title><source>ScienceDirect Journals (5 years ago - present)</source><creator>Kolb, Robert ; Fasel, Claudia ; Liebau-Kunzmann, Verena ; Riedel, Ralf</creator><creatorcontrib>Kolb, Robert ; Fasel, Claudia ; Liebau-Kunzmann, Verena ; Riedel, Ralf</creatorcontrib><description>The choice of electrode and electrolyte materials to design lithium batteries is limited due to the chemical reactivity of the used materials during the intercalation/deintercalation process. Amorphous silicon carbonitride (SiCN) ceramics are known to be chemically stable in corrosive environments and exhibit disordered carbonaceous regions making it potentially suitable to protect graphite from exfoliation. The material studied in this work was synthesized by mixing commercial graphite powder with the crosslinked polysilazane VL20
®. Pyrolysis of the polymer/graphite compound at appropriate temperatures in inert argon atmosphere resulted in the formation of an amorphous SiCN/graphite composite material. First electrochemical investigations of pure SiCN and of the SiCN/C composite are presented here. A reversible capacity of 474
mA
hg
−1 was achieved with a sample containing 25
wt% VL20
® and 75
wt% graphite. The measured capacity exceeds that of the used graphite powder by a factor of 1.3 without any fading over 50
cycles.</description><identifier>ISSN: 0955-2219</identifier><identifier>EISSN: 1873-619X</identifier><identifier>DOI: 10.1016/j.jeurceramsoc.2006.01.009</identifier><language>eng</language><publisher>Oxford: Elsevier Ltd</publisher><subject>Applied sciences ; Batteries ; Building materials. Ceramics. Glasses ; Ceramic industries ; Cermets, ceramic and refractory composites ; Chemical industry and chemicals ; Cross-disciplinary physics: materials science; rheology ; Direct energy conversion and energy accumulation ; Electrical engineering. Electrical power engineering ; Electrical power engineering ; Electrochemical conversion: primary and secondary batteries, fuel cells ; Electrotechnical and electronic ceramics ; Exact sciences and technology ; Glass ; Materials science ; Mechanical properties ; Other materials ; Physics ; Poisson's ratio ; Precursors-organic ; SiCN/C ; Specific materials ; Technical ceramics</subject><ispartof>Journal of the European Ceramic Society, 2006, Vol.26 (16), p.3903-3908</ispartof><rights>2006 Elsevier Ltd</rights><rights>2007 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c385t-c77156cf4c50c64715593e8406b4cb010a4036f2746de49ab1446bad04c3d19c3</citedby><cites>FETCH-LOGICAL-c385t-c77156cf4c50c64715593e8406b4cb010a4036f2746de49ab1446bad04c3d19c3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.jeurceramsoc.2006.01.009$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,4024,27923,27924,27925,45995</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=18213689$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Kolb, Robert</creatorcontrib><creatorcontrib>Fasel, Claudia</creatorcontrib><creatorcontrib>Liebau-Kunzmann, Verena</creatorcontrib><creatorcontrib>Riedel, Ralf</creatorcontrib><title>SiCN/C-ceramic composite as anode material for lithium ion batteries</title><title>Journal of the European Ceramic Society</title><description>The choice of electrode and electrolyte materials to design lithium batteries is limited due to the chemical reactivity of the used materials during the intercalation/deintercalation process. Amorphous silicon carbonitride (SiCN) ceramics are known to be chemically stable in corrosive environments and exhibit disordered carbonaceous regions making it potentially suitable to protect graphite from exfoliation. The material studied in this work was synthesized by mixing commercial graphite powder with the crosslinked polysilazane VL20
®. Pyrolysis of the polymer/graphite compound at appropriate temperatures in inert argon atmosphere resulted in the formation of an amorphous SiCN/graphite composite material. First electrochemical investigations of pure SiCN and of the SiCN/C composite are presented here. A reversible capacity of 474
mA
hg
−1 was achieved with a sample containing 25
wt% VL20
® and 75
wt% graphite. The measured capacity exceeds that of the used graphite powder by a factor of 1.3 without any fading over 50
cycles.</description><subject>Applied sciences</subject><subject>Batteries</subject><subject>Building materials. Ceramics. Glasses</subject><subject>Ceramic industries</subject><subject>Cermets, ceramic and refractory composites</subject><subject>Chemical industry and chemicals</subject><subject>Cross-disciplinary physics: materials science; rheology</subject><subject>Direct energy conversion and energy accumulation</subject><subject>Electrical engineering. Electrical power engineering</subject><subject>Electrical power engineering</subject><subject>Electrochemical conversion: primary and secondary batteries, fuel cells</subject><subject>Electrotechnical and electronic ceramics</subject><subject>Exact sciences and technology</subject><subject>Glass</subject><subject>Materials science</subject><subject>Mechanical properties</subject><subject>Other materials</subject><subject>Physics</subject><subject>Poisson's ratio</subject><subject>Precursors-organic</subject><subject>SiCN/C</subject><subject>Specific materials</subject><subject>Technical ceramics</subject><issn>0955-2219</issn><issn>1873-619X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2006</creationdate><recordtype>article</recordtype><recordid>eNqNkE1Lw0AQhhdRsFb_QxD0lnQ22Wyy3qT1C4oeVPC2bCYT3JJk624q-O9NbUGPnoZhnnmHeRg755Bw4HK2Sla08UjedMFhkgLIBHgCoA7YhJdFFkuu3g7ZBFSex2nK1TE7CWEFwAtQasIWz3b-OJvHPxEWI3Td2gU7UGRCZHpXU9SZgbw1bdQ4H7V2eLebLrKujyozbCcUTtlRY9pAZ_s6Za-3Ny_z-3j5dPcwv17GmJX5EGNR8FxiIzAHlGJscpVRKUBWAivgYARkskkLIWsSylRcCFmZGgRmNVeYTdnlLnft3ceGwqA7G5Da1vTkNkGnqpS5kGIEr3YgeheCp0avve2M_9Ic9FacXum_4vRWnAauR3Hj8sX-iglo2sabHm34TShTnslyyy12HI0vf1ryOqClHqm2nnDQtbP_OfcN0PGKOg</recordid><startdate>2006</startdate><enddate>2006</enddate><creator>Kolb, Robert</creator><creator>Fasel, Claudia</creator><creator>Liebau-Kunzmann, Verena</creator><creator>Riedel, Ralf</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QQ</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>2006</creationdate><title>SiCN/C-ceramic composite as anode material for lithium ion batteries</title><author>Kolb, Robert ; Fasel, Claudia ; Liebau-Kunzmann, Verena ; Riedel, Ralf</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c385t-c77156cf4c50c64715593e8406b4cb010a4036f2746de49ab1446bad04c3d19c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2006</creationdate><topic>Applied sciences</topic><topic>Batteries</topic><topic>Building materials. Ceramics. Glasses</topic><topic>Ceramic industries</topic><topic>Cermets, ceramic and refractory composites</topic><topic>Chemical industry and chemicals</topic><topic>Cross-disciplinary physics: materials science; rheology</topic><topic>Direct energy conversion and energy accumulation</topic><topic>Electrical engineering. Electrical power engineering</topic><topic>Electrical power engineering</topic><topic>Electrochemical conversion: primary and secondary batteries, fuel cells</topic><topic>Electrotechnical and electronic ceramics</topic><topic>Exact sciences and technology</topic><topic>Glass</topic><topic>Materials science</topic><topic>Mechanical properties</topic><topic>Other materials</topic><topic>Physics</topic><topic>Poisson's ratio</topic><topic>Precursors-organic</topic><topic>SiCN/C</topic><topic>Specific materials</topic><topic>Technical ceramics</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kolb, Robert</creatorcontrib><creatorcontrib>Fasel, Claudia</creatorcontrib><creatorcontrib>Liebau-Kunzmann, Verena</creatorcontrib><creatorcontrib>Riedel, Ralf</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Ceramic Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of the European Ceramic Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kolb, Robert</au><au>Fasel, Claudia</au><au>Liebau-Kunzmann, Verena</au><au>Riedel, Ralf</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>SiCN/C-ceramic composite as anode material for lithium ion batteries</atitle><jtitle>Journal of the European Ceramic Society</jtitle><date>2006</date><risdate>2006</risdate><volume>26</volume><issue>16</issue><spage>3903</spage><epage>3908</epage><pages>3903-3908</pages><issn>0955-2219</issn><eissn>1873-619X</eissn><abstract>The choice of electrode and electrolyte materials to design lithium batteries is limited due to the chemical reactivity of the used materials during the intercalation/deintercalation process. Amorphous silicon carbonitride (SiCN) ceramics are known to be chemically stable in corrosive environments and exhibit disordered carbonaceous regions making it potentially suitable to protect graphite from exfoliation. The material studied in this work was synthesized by mixing commercial graphite powder with the crosslinked polysilazane VL20
®. Pyrolysis of the polymer/graphite compound at appropriate temperatures in inert argon atmosphere resulted in the formation of an amorphous SiCN/graphite composite material. First electrochemical investigations of pure SiCN and of the SiCN/C composite are presented here. A reversible capacity of 474
mA
hg
−1 was achieved with a sample containing 25
wt% VL20
® and 75
wt% graphite. The measured capacity exceeds that of the used graphite powder by a factor of 1.3 without any fading over 50
cycles.</abstract><cop>Oxford</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.jeurceramsoc.2006.01.009</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0955-2219 |
| ispartof | Journal of the European Ceramic Society, 2006, Vol.26 (16), p.3903-3908 |
| issn | 0955-2219 1873-619X |
| language | eng |
| recordid | cdi_proquest_miscellaneous_29865464 |
| source | ScienceDirect Journals (5 years ago - present) |
| subjects | Applied sciences Batteries Building materials. Ceramics. Glasses Ceramic industries Cermets, ceramic and refractory composites Chemical industry and chemicals Cross-disciplinary physics: materials science rheology Direct energy conversion and energy accumulation Electrical engineering. Electrical power engineering Electrical power engineering Electrochemical conversion: primary and secondary batteries, fuel cells Electrotechnical and electronic ceramics Exact sciences and technology Glass Materials science Mechanical properties Other materials Physics Poisson's ratio Precursors-organic SiCN/C Specific materials Technical ceramics |
| title | SiCN/C-ceramic composite as anode material for lithium ion batteries |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-06T22%3A47%3A20IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=SiCN/C-ceramic%20composite%20as%20anode%20material%20for%20lithium%20ion%20batteries&rft.jtitle=Journal%20of%20the%20European%20Ceramic%20Society&rft.au=Kolb,%20Robert&rft.date=2006&rft.volume=26&rft.issue=16&rft.spage=3903&rft.epage=3908&rft.pages=3903-3908&rft.issn=0955-2219&rft.eissn=1873-619X&rft_id=info:doi/10.1016/j.jeurceramsoc.2006.01.009&rft_dat=%3Cproquest_cross%3E29865464%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=29865464&rft_id=info:pmid/&rft_els_id=S0955221906000483&rfr_iscdi=true |