Dispersion of silica nano-particles in sol-gel hybrid resins for fabrication of multi-scale hybrid nanocomposite

Multi-scale hybrid nanocomposites containing both ∼15 nm silica colloids and ∼2 nm oligosiloxanes in a methacryl polymer matrix were newly designed and fabricated. Colloidal silica sols were dispersed in methacryl oligosiloxanes nano-hybrid resins synthesized by sol-gel reaction of methacryloxypropy...

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Veröffentlicht in:Journal of sol-gel science and technology 2007-03, Vol.41 (3), p.249-255
Hauptverfasser: JEONG HWAN KIM, JI HOON KO, BAE, Byeong-Soo
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container_title Journal of sol-gel science and technology
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creator JEONG HWAN KIM
JI HOON KO
BAE, Byeong-Soo
description Multi-scale hybrid nanocomposites containing both ∼15 nm silica colloids and ∼2 nm oligosiloxanes in a methacryl polymer matrix were newly designed and fabricated. Colloidal silica sols were dispersed in methacryl oligosiloxanes nano-hybrid resins synthesized by sol-gel reaction of methacryloxypropylmethoxysilane and diphenylsilanediol. On the basis of TEM and SANS analyses, it was confirmed that the silica colloids were compatibly dispersed and different sizes of colloidal silica and oligosiloxanes co-exist in the solutions. Multi-scale hybrid nanocomposites fabricated by UV and thermal curing with incorporation of silica colloids in the nano-hybrid materials show enhanced mechanical and thermal characteristics.
doi_str_mv 10.1007/s10971-006-9001-7
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subjects Chemical synthesis
Chemistry
Colloidal gels. Colloidal sols
Colloidal state and disperse state
Colloids
Exact sciences and technology
General and physical chemistry
Nanocomposites
Physical and chemical studies. Granulometry. Electrokinetic phenomena
Polymers
Resins
Silica gel
Silicon dioxide
Sol-gel processes
Sols
title Dispersion of silica nano-particles in sol-gel hybrid resins for fabrication of multi-scale hybrid nanocomposite
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