Dispersion of silica nano-particles in sol-gel hybrid resins for fabrication of multi-scale hybrid nanocomposite
Multi-scale hybrid nanocomposites containing both ∼15 nm silica colloids and ∼2 nm oligosiloxanes in a methacryl polymer matrix were newly designed and fabricated. Colloidal silica sols were dispersed in methacryl oligosiloxanes nano-hybrid resins synthesized by sol-gel reaction of methacryloxypropy...
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Veröffentlicht in: | Journal of sol-gel science and technology 2007-03, Vol.41 (3), p.249-255 |
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container_title | Journal of sol-gel science and technology |
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creator | JEONG HWAN KIM JI HOON KO BAE, Byeong-Soo |
description | Multi-scale hybrid nanocomposites containing both ∼15 nm silica colloids and ∼2 nm oligosiloxanes in a methacryl polymer matrix were newly designed and fabricated. Colloidal silica sols were dispersed in methacryl oligosiloxanes nano-hybrid resins synthesized by sol-gel reaction of methacryloxypropylmethoxysilane and diphenylsilanediol. On the basis of TEM and SANS analyses, it was confirmed that the silica colloids were compatibly dispersed and different sizes of colloidal silica and oligosiloxanes co-exist in the solutions. Multi-scale hybrid nanocomposites fabricated by UV and thermal curing with incorporation of silica colloids in the nano-hybrid materials show enhanced mechanical and thermal characteristics. |
doi_str_mv | 10.1007/s10971-006-9001-7 |
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Colloidal silica sols were dispersed in methacryl oligosiloxanes nano-hybrid resins synthesized by sol-gel reaction of methacryloxypropylmethoxysilane and diphenylsilanediol. On the basis of TEM and SANS analyses, it was confirmed that the silica colloids were compatibly dispersed and different sizes of colloidal silica and oligosiloxanes co-exist in the solutions. Multi-scale hybrid nanocomposites fabricated by UV and thermal curing with incorporation of silica colloids in the nano-hybrid materials show enhanced mechanical and thermal characteristics.</description><identifier>ISSN: 0928-0707</identifier><identifier>EISSN: 1573-4846</identifier><identifier>DOI: 10.1007/s10971-006-9001-7</identifier><language>eng</language><publisher>Heidelberg: Springer</publisher><subject>Chemical synthesis ; Chemistry ; Colloidal gels. 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Colloidal silica sols were dispersed in methacryl oligosiloxanes nano-hybrid resins synthesized by sol-gel reaction of methacryloxypropylmethoxysilane and diphenylsilanediol. On the basis of TEM and SANS analyses, it was confirmed that the silica colloids were compatibly dispersed and different sizes of colloidal silica and oligosiloxanes co-exist in the solutions. Multi-scale hybrid nanocomposites fabricated by UV and thermal curing with incorporation of silica colloids in the nano-hybrid materials show enhanced mechanical and thermal characteristics.</description><subject>Chemical synthesis</subject><subject>Chemistry</subject><subject>Colloidal gels. Colloidal sols</subject><subject>Colloidal state and disperse state</subject><subject>Colloids</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Nanocomposites</subject><subject>Physical and chemical studies. Granulometry. Electrokinetic phenomena</subject><subject>Polymers</subject><subject>Resins</subject><subject>Silica gel</subject><subject>Silicon dioxide</subject><subject>Sol-gel processes</subject><subject>Sols</subject><issn>0928-0707</issn><issn>1573-4846</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2007</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNpdkU1r3DAQhkVoIdu0PyA3QUhvakdflnUMaZIWFnppz0KWpURBazka7yH_Pl52SyGngeF5H4Z5Cbnk8I0DmO_IwRrOADpmATgzZ2TDtZFM9ar7QDZgRc_AgDknnxCfAUArbjZk_pFxjg1znWhNFHPJwdPJT5XNvi05lIg0TxRrYY-x0KfXoeWRtoh5Qppqo8mvm-CXk2G3L0tmGHyJ_-CDLdTdXDEv8TP5mHzB-OU0L8jf-7s_tz_Z9vfDr9ubLQtSqoUFkDZ2g7VceD6MPvVKBOi4F36UMgUTbQqxl4b3Zhyj6VOnNNdDZ4xXgxTygnw9eudWX_YRF7fLGGIpfop1j07YXlmhYQWv3oHPdd-m9TYnhLa6U1J3K8WPVGgVscXk5pZ3vr06Du7QgDs24NYG3KEBZ9bM9cnsD_9IzU8h4_9gr5UFyeUb7ySHWA</recordid><startdate>20070301</startdate><enddate>20070301</enddate><creator>JEONG HWAN KIM</creator><creator>JI HOON KO</creator><creator>BAE, Byeong-Soo</creator><general>Springer</general><general>Springer Nature B.V</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>L6V</scope><scope>M7S</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>20070301</creationdate><title>Dispersion of silica nano-particles in sol-gel hybrid resins for fabrication of multi-scale hybrid nanocomposite</title><author>JEONG HWAN KIM ; JI HOON KO ; BAE, Byeong-Soo</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c334t-c039e6b9912a1bdaf842c061a2ad33fc7e9fce837187dde78f64515b677a4b323</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2007</creationdate><topic>Chemical synthesis</topic><topic>Chemistry</topic><topic>Colloidal gels. 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subjects | Chemical synthesis Chemistry Colloidal gels. Colloidal sols Colloidal state and disperse state Colloids Exact sciences and technology General and physical chemistry Nanocomposites Physical and chemical studies. Granulometry. Electrokinetic phenomena Polymers Resins Silica gel Silicon dioxide Sol-gel processes Sols |
title | Dispersion of silica nano-particles in sol-gel hybrid resins for fabrication of multi-scale hybrid nanocomposite |
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