Laboratory measurement of the pH profile near a vapor-water interface
We have begun a novel set of experiments to observe the pH profile near the vapor-water and vapor-ice interface as a function of growth and sublimation rate and, in the case of ice, also as a function of surface morphology. The temperature and humidity controlled sample is held in a optical cryostat...
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Veröffentlicht in: | Bulletin of the American Physical Society 2004-03, Vol.49 (1) |
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creator | Swanson, Brian D Wilson, C Brant |
description | We have begun a novel set of experiments to observe the pH profile near the vapor-water and vapor-ice interface as a function of growth and sublimation rate and, in the case of ice, also as a function of surface morphology. The temperature and humidity controlled sample is held in a optical cryostat while the ion concentration is measured as a function of depth into the sample using a confocal microscope. Ion concentrations are determined from a combination of Raman spectroscopy and UV fluorescence spectroscopy using a specialized molecular probe whose fluorescence spectrum depends on pH. Initial results for the pH profile near a vapor-water interface will be shown. |
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title | Laboratory measurement of the pH profile near a vapor-water interface |
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