The occurrence of selected pharmaceuticals in wastewater effluent and surface waters of the lower Tyne catchment
This paper presents the results of a survey of the wastewater effluent and surface waters of the lower river Tyne, UK. Samples were analysed by reversed-phase high-performance liquid chromatography–electrospray tandem mass spectrometry following solid phase extraction, for the presence of 13 pharmac...
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Veröffentlicht in: | The Science of the total environment 2006-03, Vol.356 (1), p.143-153 |
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description | This paper presents the results of a survey of the wastewater effluent and surface waters of the lower river Tyne, UK. Samples were analysed by reversed-phase high-performance liquid chromatography–electrospray tandem mass spectrometry following solid phase extraction, for the presence of 13 pharmaceuticals selected from the priority lists of the UK Environment Agency and the Oslo and Paris Commission (OSPAR). The pharmaceutical compounds measured were acetyl-sulfamethoxazole, clofibric acid, clotrimazole, dextropropoxyphene, diclofenac, erythromycin, ibuprofen, mefenamic acid, paracetamol, propranolol, sulfamethoxazole, tamoxifen and trimethoprim.
Of the wastewater treatment works (WTW) samples (
n
=
9) analysed, all compounds except sulfamethoxazole and acetyl-sulfamethoxazole were detected at concentrations ranging from 11 to 69,570 ng l
−
1
(in raw effluent). In the surface water samples (
n
=
18), clotrimazole, dextropropoxyphene, erythromycin, ibuprofen, propranolol, tamoxifen and trimethoprim were detected at concentrations ranging from 4 to 2370 ng l
−
1
. Results of this study show that various pharmaceutical compounds are effectively reduced during their passage through a tertiary wastewater treatment works, whilst others are sufficiently persistent to occur in estuarine systems. |
doi_str_mv | 10.1016/j.scitotenv.2005.04.031 |
format | Article |
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Of the wastewater treatment works (WTW) samples (
n
=
9) analysed, all compounds except sulfamethoxazole and acetyl-sulfamethoxazole were detected at concentrations ranging from 11 to 69,570 ng l
−
1
(in raw effluent). In the surface water samples (
n
=
18), clotrimazole, dextropropoxyphene, erythromycin, ibuprofen, propranolol, tamoxifen and trimethoprim were detected at concentrations ranging from 4 to 2370 ng l
−
1
. Results of this study show that various pharmaceutical compounds are effectively reduced during their passage through a tertiary wastewater treatment works, whilst others are sufficiently persistent to occur in estuarine systems.</description><identifier>ISSN: 0048-9697</identifier><identifier>EISSN: 1879-1026</identifier><identifier>DOI: 10.1016/j.scitotenv.2005.04.031</identifier><identifier>PMID: 15936058</identifier><identifier>CODEN: STENDL</identifier><language>eng</language><publisher>Shannon: Elsevier B.V</publisher><subject>Applied sciences ; Earth sciences ; Earth, ocean, space ; Engineering and environment geology. Geothermics ; Exact sciences and technology ; Natural water pollution ; OSPAR ; Other wastewaters ; Pharmaceutical Preparations - analysis ; Pharmaceuticals ; Pollution ; Pollution, environment geology ; Raw effluent ; Rivers - chemistry ; Seawaters, estuaries ; United Kingdom ; Wastewater treatment works ; Wastewaters ; Water Pollutants, Chemical - analysis ; Water Purification - methods ; Water Supply - standards ; Water treatment and pollution</subject><ispartof>The Science of the total environment, 2006-03, Vol.356 (1), p.143-153</ispartof><rights>2005 Elsevier B.V.</rights><rights>2006 INIST-CNRS</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c607t-807bb5729495dd1d1f2e825ce358c8aab46f117fe1c3caad6c17c6b1e61d1fe23</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.scitotenv.2005.04.031$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>315,781,785,3551,27929,27930,46000</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=17541261$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/15936058$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Roberts, Paul H.</creatorcontrib><creatorcontrib>Thomas, Kevin V.</creatorcontrib><title>The occurrence of selected pharmaceuticals in wastewater effluent and surface waters of the lower Tyne catchment</title><title>The Science of the total environment</title><addtitle>Sci Total Environ</addtitle><description>This paper presents the results of a survey of the wastewater effluent and surface waters of the lower river Tyne, UK. Samples were analysed by reversed-phase high-performance liquid chromatography–electrospray tandem mass spectrometry following solid phase extraction, for the presence of 13 pharmaceuticals selected from the priority lists of the UK Environment Agency and the Oslo and Paris Commission (OSPAR). The pharmaceutical compounds measured were acetyl-sulfamethoxazole, clofibric acid, clotrimazole, dextropropoxyphene, diclofenac, erythromycin, ibuprofen, mefenamic acid, paracetamol, propranolol, sulfamethoxazole, tamoxifen and trimethoprim.
Of the wastewater treatment works (WTW) samples (
n
=
9) analysed, all compounds except sulfamethoxazole and acetyl-sulfamethoxazole were detected at concentrations ranging from 11 to 69,570 ng l
−
1
(in raw effluent). In the surface water samples (
n
=
18), clotrimazole, dextropropoxyphene, erythromycin, ibuprofen, propranolol, tamoxifen and trimethoprim were detected at concentrations ranging from 4 to 2370 ng l
−
1
. Results of this study show that various pharmaceutical compounds are effectively reduced during their passage through a tertiary wastewater treatment works, whilst others are sufficiently persistent to occur in estuarine systems.</description><subject>Applied sciences</subject><subject>Earth sciences</subject><subject>Earth, ocean, space</subject><subject>Engineering and environment geology. Geothermics</subject><subject>Exact sciences and technology</subject><subject>Natural water pollution</subject><subject>OSPAR</subject><subject>Other wastewaters</subject><subject>Pharmaceutical Preparations - analysis</subject><subject>Pharmaceuticals</subject><subject>Pollution</subject><subject>Pollution, environment geology</subject><subject>Raw effluent</subject><subject>Rivers - chemistry</subject><subject>Seawaters, estuaries</subject><subject>United Kingdom</subject><subject>Wastewater treatment works</subject><subject>Wastewaters</subject><subject>Water Pollutants, Chemical - analysis</subject><subject>Water Purification - methods</subject><subject>Water Supply - standards</subject><subject>Water treatment and pollution</subject><issn>0048-9697</issn><issn>1879-1026</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2006</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkUtvGyEURlHVqHGT_oWWTbubKcwDmGUUpQ8pUjfOGjGXi4w1DxeYWPn3ZWKrWZoNSJz7fYhDyBfOSs64-L4vI_g0J5yey4qxtmRNyWr-jmy4kl3BWSXekw1jjSo60clr8jHGPctLKv6BXPO2qwVr1YYctjukM8ASAk6Qj45GHBASWnrYmTAawCV5MEOkfqJHExMeTcJA0blhwSlRM1kal-AySV-v4pqScu4wHzO4fZmQgkmwGzN-S65cDsNP5_2GPP142N7_Kh7__Px9f_dYgGAyFYrJvm9l1TVday233FWoqhawbhUoY_pGOM6lQw41GGMFcAmi5yhWFqv6hnw75R7C_HfBmPToI-AwmAnnJeqqk0zUjF0GZaeaXH0R5Dmx7mqVQXkCIcwxBnT6EPxowovmTK_69F7_16dXfZo1OuvLk5_PFUs_on2bO_vKwNczYGJ24oKZwMc3TrYNr8QadHfiMH_xs8ewFq6CrQ9Zrrazv_iYf2a9v28</recordid><startdate>20060301</startdate><enddate>20060301</enddate><creator>Roberts, Paul H.</creator><creator>Thomas, Kevin V.</creator><general>Elsevier B.V</general><general>Elsevier Science</general><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QH</scope><scope>7ST</scope><scope>7TG</scope><scope>7TV</scope><scope>7U6</scope><scope>7UA</scope><scope>C1K</scope><scope>KL.</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope><scope>KR7</scope><scope>7TB</scope></search><sort><creationdate>20060301</creationdate><title>The occurrence of selected pharmaceuticals in wastewater effluent and surface waters of the lower Tyne catchment</title><author>Roberts, Paul H. ; Thomas, Kevin V.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c607t-807bb5729495dd1d1f2e825ce358c8aab46f117fe1c3caad6c17c6b1e61d1fe23</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2006</creationdate><topic>Applied sciences</topic><topic>Earth sciences</topic><topic>Earth, ocean, space</topic><topic>Engineering and environment geology. Geothermics</topic><topic>Exact sciences and technology</topic><topic>Natural water pollution</topic><topic>OSPAR</topic><topic>Other wastewaters</topic><topic>Pharmaceutical Preparations - analysis</topic><topic>Pharmaceuticals</topic><topic>Pollution</topic><topic>Pollution, environment geology</topic><topic>Raw effluent</topic><topic>Rivers - chemistry</topic><topic>Seawaters, estuaries</topic><topic>United Kingdom</topic><topic>Wastewater treatment works</topic><topic>Wastewaters</topic><topic>Water Pollutants, Chemical - analysis</topic><topic>Water Purification - methods</topic><topic>Water Supply - standards</topic><topic>Water treatment and pollution</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Roberts, Paul H.</creatorcontrib><creatorcontrib>Thomas, Kevin V.</creatorcontrib><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Aqualine</collection><collection>Environment Abstracts</collection><collection>Meteorological & Geoastrophysical Abstracts</collection><collection>Pollution Abstracts</collection><collection>Sustainability Science Abstracts</collection><collection>Water Resources Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Meteorological & Geoastrophysical Abstracts - Academic</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Civil Engineering Abstracts</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><jtitle>The Science of the total environment</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Roberts, Paul H.</au><au>Thomas, Kevin V.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The occurrence of selected pharmaceuticals in wastewater effluent and surface waters of the lower Tyne catchment</atitle><jtitle>The Science of the total environment</jtitle><addtitle>Sci Total Environ</addtitle><date>2006-03-01</date><risdate>2006</risdate><volume>356</volume><issue>1</issue><spage>143</spage><epage>153</epage><pages>143-153</pages><issn>0048-9697</issn><eissn>1879-1026</eissn><coden>STENDL</coden><abstract>This paper presents the results of a survey of the wastewater effluent and surface waters of the lower river Tyne, UK. Samples were analysed by reversed-phase high-performance liquid chromatography–electrospray tandem mass spectrometry following solid phase extraction, for the presence of 13 pharmaceuticals selected from the priority lists of the UK Environment Agency and the Oslo and Paris Commission (OSPAR). The pharmaceutical compounds measured were acetyl-sulfamethoxazole, clofibric acid, clotrimazole, dextropropoxyphene, diclofenac, erythromycin, ibuprofen, mefenamic acid, paracetamol, propranolol, sulfamethoxazole, tamoxifen and trimethoprim.
Of the wastewater treatment works (WTW) samples (
n
=
9) analysed, all compounds except sulfamethoxazole and acetyl-sulfamethoxazole were detected at concentrations ranging from 11 to 69,570 ng l
−
1
(in raw effluent). In the surface water samples (
n
=
18), clotrimazole, dextropropoxyphene, erythromycin, ibuprofen, propranolol, tamoxifen and trimethoprim were detected at concentrations ranging from 4 to 2370 ng l
−
1
. Results of this study show that various pharmaceutical compounds are effectively reduced during their passage through a tertiary wastewater treatment works, whilst others are sufficiently persistent to occur in estuarine systems.</abstract><cop>Shannon</cop><pub>Elsevier B.V</pub><pmid>15936058</pmid><doi>10.1016/j.scitotenv.2005.04.031</doi><tpages>11</tpages><oa>free_for_read</oa></addata></record> |
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subjects | Applied sciences Earth sciences Earth, ocean, space Engineering and environment geology. Geothermics Exact sciences and technology Natural water pollution OSPAR Other wastewaters Pharmaceutical Preparations - analysis Pharmaceuticals Pollution Pollution, environment geology Raw effluent Rivers - chemistry Seawaters, estuaries United Kingdom Wastewater treatment works Wastewaters Water Pollutants, Chemical - analysis Water Purification - methods Water Supply - standards Water treatment and pollution |
title | The occurrence of selected pharmaceuticals in wastewater effluent and surface waters of the lower Tyne catchment |
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