Loss of permselectivity of anion exchange membranes in contact with zinc chloride complexes
In this paper we compare the properties of anion-exchange membranes in contact with aqueous solutions containing zinc chloride complexes and with uncomplexed metal chloride solutions. Electric resistance measurements were performed as a function of the composition of the external solutions, which ar...
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| Veröffentlicht in: | Desalination 1999, Vol.121 (1), p.13-22 |
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| container_title | Desalination |
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| creator | Aouad, F. Lindheimer, A. Chaouki, M. Gavach, C. |
| description | In this paper we compare the properties of anion-exchange membranes in contact with aqueous solutions containing zinc chloride complexes and with uncomplexed metal chloride solutions. Electric resistance measurements were performed as a function of the composition of the external solutions, which are mixtures of hydrochloric acid with sodium, zinc or nickel chloride. The transport numbers of proton and zinc through anion-exchange membranes were measured, and the obtained results showed the influence of the complexed species on the loss of permselectivity of the studied membranes. These results were analyzed on the basis of Raman spectra of the membranes equilibrated with the considered solutions. |
| doi_str_mv | 10.1016/S0011-9164(99)00003-X |
| format | Article |
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Electric resistance measurements were performed as a function of the composition of the external solutions, which are mixtures of hydrochloric acid with sodium, zinc or nickel chloride. The transport numbers of proton and zinc through anion-exchange membranes were measured, and the obtained results showed the influence of the complexed species on the loss of permselectivity of the studied membranes. 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These results were analyzed on the basis of Raman spectra of the membranes equilibrated with the considered solutions.</description><subject>Anion exchange membranes</subject><subject>Applied sciences</subject><subject>Complexes between Zn 2+ and Cl</subject><subject>Electric resistance</subject><subject>Exact sciences and technology</subject><subject>General purification processes</subject><subject>Loss of permselectivity</subject><subject>Pollution</subject><subject>Transfer numbers</subject><subject>Wastewaters</subject><subject>Water treatment and pollution</subject><issn>0011-9164</issn><issn>1873-4464</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1999</creationdate><recordtype>article</recordtype><recordid>eNqFkUtLAzEQgIMoWKs_QchBRA-rySab3ZxEii8oeFCh4CFk04mN7KMm29r6600f6LG5hMx8k8l8QeiUkitKqLh-IYTSRFLBL6S8JHGxZLSHerTIWcK54Puo94ccoqMQPuMxlYz10PuwDQG3Fk_B1wEqMJ2bu265CunGtQ2GhZno5gNwDXXpdQMBuwabtum06fC36yb4xzUGm0nVejeGmKqnFSwgHKMDq6sAJ9u9j97u714Hj8nw-eFpcDtMDGdZlxRCpJoUBSOUFanhoiBM2lSaGBS5LW1u0tJmrAROMs2YzfNS5JwVWpKUZZb10fnm3qlvv2YQOlW7YKCq4mPbWVCpzAkjROwEaZ4SzjiJYLYBjY96PFg19a7WfqkoUSvnau1crYQqKdXauRrFurNtAx2MrmzUZVz4L46jZUUWsZsNBtHK3IFXwThoDIydjx-gxq3b0egX576VdA</recordid><startdate>1999</startdate><enddate>1999</enddate><creator>Aouad, F.</creator><creator>Lindheimer, A.</creator><creator>Chaouki, M.</creator><creator>Gavach, C.</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7UA</scope><scope>C1K</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>1999</creationdate><title>Loss of permselectivity of anion exchange membranes in contact with zinc chloride complexes</title><author>Aouad, F. ; Lindheimer, A. ; Chaouki, M. ; Gavach, C.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c435t-8662a088301382c468039f29ca0867fbf7c2bf53be405a33f77b67438a90235f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1999</creationdate><topic>Anion exchange membranes</topic><topic>Applied sciences</topic><topic>Complexes between Zn 2+ and Cl</topic><topic>Electric resistance</topic><topic>Exact sciences and technology</topic><topic>General purification processes</topic><topic>Loss of permselectivity</topic><topic>Pollution</topic><topic>Transfer numbers</topic><topic>Wastewaters</topic><topic>Water treatment and pollution</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Aouad, F.</creatorcontrib><creatorcontrib>Lindheimer, A.</creatorcontrib><creatorcontrib>Chaouki, M.</creatorcontrib><creatorcontrib>Gavach, C.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Water Resources Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Desalination</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Aouad, F.</au><au>Lindheimer, A.</au><au>Chaouki, M.</au><au>Gavach, C.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Loss of permselectivity of anion exchange membranes in contact with zinc chloride complexes</atitle><jtitle>Desalination</jtitle><date>1999</date><risdate>1999</risdate><volume>121</volume><issue>1</issue><spage>13</spage><epage>22</epage><pages>13-22</pages><issn>0011-9164</issn><eissn>1873-4464</eissn><coden>DSLNAH</coden><abstract>In this paper we compare the properties of anion-exchange membranes in contact with aqueous solutions containing zinc chloride complexes and with uncomplexed metal chloride solutions. 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| source | Elsevier ScienceDirect Journals |
| subjects | Anion exchange membranes Applied sciences Complexes between Zn 2+ and Cl Electric resistance Exact sciences and technology General purification processes Loss of permselectivity Pollution Transfer numbers Wastewaters Water treatment and pollution |
| title | Loss of permselectivity of anion exchange membranes in contact with zinc chloride complexes |
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