Structural analysis of undoped microcrystalline silicon thin films deposited by PECVD technique

Undoped microcrystalline silicon thin films have been deposited by radio frequency powered plasma enhanced chemical vapour deposition technique. The structural order of silicon network in the films has been studied by Raman spectroscopy. The role of bonded hydrogen in the films and their consequence...

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Veröffentlicht in:Journal of physics. D, Applied physics Applied physics, 2004-07, Vol.37 (13), p.1736-1741
Hauptverfasser: Mukhopadhyay, Sumita, Das, Chandan, Ray, Swati
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container_title Journal of physics. D, Applied physics
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creator Mukhopadhyay, Sumita
Das, Chandan
Ray, Swati
description Undoped microcrystalline silicon thin films have been deposited by radio frequency powered plasma enhanced chemical vapour deposition technique. The structural order of silicon network in the films has been studied by Raman spectroscopy. The role of bonded hydrogen in the films and their consequences in microstructural defects have been obtained from the results of Fourier transform infrared spectroscopy. The presence of microcrystals and growth morphology of the microcrystalline films have been investigated by transmission and scanning electron microscopy, respectively. Optimized deposition conditions are obtained where properties of the microcrystalline films are suitable as absorber layer of solar cells. A highly conducting undoped microcrystalline film with 87% crystalline fraction (fc) is obtained, which exhibits columnar structure.
doi_str_mv 10.1088/0022-3727/37/13/003
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subjects Condensed matter: structure, mechanical and thermal properties
Exact sciences and technology
Physics
Structure and morphology
thickness
Surfaces and interfaces
thin films and whiskers (structure and nonelectronic properties)
Thin film structure and morphology
title Structural analysis of undoped microcrystalline silicon thin films deposited by PECVD technique
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