4-Carboxyphenyl as efficient donor group in nano Zn-Porphyrin for dye sensitized solar cells

Dye-sensitized solar cells, represent the alternate technology in solar research due to their cost effective, easy fabrication processes, higher efficiencies, and design flexibility. In this research, dual donor group modified zinc porphyrin dyes, have been synthesized for DSSCs. The complexes of zi...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Environmental research 2024-06, Vol.251 (Pt 2), p.118704, Article 118704
Hauptverfasser: Dayanithi, Janet, Pichaikaran, Sudhakar, Selvam, Sandhiya, Kotteswaran, Shanmugam, Kumaresan, Natesan, Pugazhendhi, Arivalagan, Rajesh Kumar, Manavalan, AL Garalleh, Hakim, Ali Alshehri, Mohammed, Murugadoss, Govindhasamy
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page
container_issue Pt 2
container_start_page 118704
container_title Environmental research
container_volume 251
creator Dayanithi, Janet
Pichaikaran, Sudhakar
Selvam, Sandhiya
Kotteswaran, Shanmugam
Kumaresan, Natesan
Pugazhendhi, Arivalagan
Rajesh Kumar, Manavalan
AL Garalleh, Hakim
Ali Alshehri, Mohammed
Murugadoss, Govindhasamy
description Dye-sensitized solar cells, represent the alternate technology in solar research due to their cost effective, easy fabrication processes, higher efficiencies, and design flexibility. In this research, dual donor group modified zinc porphyrin dyes, have been synthesized for DSSCs. The complexes of zinc porphyrin functioned as acceptor or attaching groups within each mesophenyl ring and carboxylic acid. These complexes exhibited diverse alkyl substituents and sizable electron-donating substituents, contributing to their varied chemical structures and potential applications. The dual Donor-π bridge -Acceptor group sensitizers, Zn[5,15-diphenylcarbazole-10,20-(4-carboxyphenyl) Porphyrin] (KSR-1) and Zn [5,15-thiadiazole-10,20-(4-carboxyphenyl) Porphyrin] (KSR-2) have been synthesized and adopted for DSSCs implementation. The molar absorption coefficients (ε) of KSR-2 and KSR-1 Soret bands were 0.56 x 105 mol/L/cm and 0.47 x 105 mol/L/cm, respectively. The Q bands of the KSR-1 and KSR-2 dyes were 1.10 x 105 mol/L/cm and 1.0 x 105 mol/L/cm, respectively and the molar absorption coefficient of the KSR-1 dye was greater when compared to the KSR-2 dye. The molar absorption coefficient of 0.71 x 105 mol/L/cm was visible in the KSR -1 Q-band. DFT calculations and the electrochemical characteristics of the KSR-1 and KSR-2 dyes have been studied and discussed. The exploration involved in investigating the photophysical properties and photovoltaic performance which were affected by varying the length and number of the donor entities. The wall-plug efficiency of the KSR-1 based solar panel was Voc = 0.68 V, Jsc = 8.94 mA/m2, FF = 56 and Efficiency (μ) = 3.44%. The wall-plug efficiency of the KSR-2 based solar panel was Voc = 0.63 V, Jsc = 5.42 mA/m2, FF = 53 and Efficiency (μ) = 1.83%. •A novel Donor-π-Acceptor based Zn-Porphyrins have been designed and synthesized.•Diphenyl carbazole used as a donor instead of thiadiazol in the Porphyrin core.•Molar extinction coefficient of KSR-1 was increased due to Diphenyl carbazole.•Energy band alignment in Diphenyl carbazole based Zn-Porphyrin is suitable for DSSC.•KSR-1 cell efficiency was achieved almost equal to commercially available dye.
doi_str_mv 10.1016/j.envres.2024.118704
format Article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_2967059704</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S001393512400608X</els_id><sourcerecordid>2967059704</sourcerecordid><originalsourceid>FETCH-LOGICAL-c311t-92dddef849c7b201292bd301f7dec3d57f9589c2df60b5e06a18bd60cac586323</originalsourceid><addsrcrecordid>eNp9kE1P3DAQhq0KVBbaf1BVPnLJ4o84iS9I1aotSEhwgEtVyXLscfEqa6d2FjX8-noV4MhpNDPvzDvzIPSFkjUltLnYriE8JchrRli9prRrSf0BrSiRTUWk4EdoRQjlleSCnqDTnLclpYKTj-iEd7XknWAr9LuuNjr18d88PkKYB6wzBue88RAmbGOICf9JcT9iH3DQIeJfobqLaXycU6m40rYz4Awh-8k_g8U5DjphA8OQP6Fjp4cMn1_iGXr48f1-c1Xd3P683ny7qQyndKoks9aCKzeZtmeEMsl6ywl1rQXDrWidFJ00zLqG9AJIo2nX24YYbUTXcMbP0Pmyd0zx7x7ypHY-Hy7QAeI-KyablghZABVpvUhNijkncGpMfqfTrChRB65qqxau6sBVLVzL2NcXh32_A_s29AqyCC4XAZQ_nzwklQ8IDVifwEzKRv--w38fdowA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2967059704</pqid></control><display><type>article</type><title>4-Carboxyphenyl as efficient donor group in nano Zn-Porphyrin for dye sensitized solar cells</title><source>ScienceDirect Freedom Collection (Elsevier)</source><creator>Dayanithi, Janet ; Pichaikaran, Sudhakar ; Selvam, Sandhiya ; Kotteswaran, Shanmugam ; Kumaresan, Natesan ; Pugazhendhi, Arivalagan ; Rajesh Kumar, Manavalan ; AL Garalleh, Hakim ; Ali Alshehri, Mohammed ; Murugadoss, Govindhasamy</creator><creatorcontrib>Dayanithi, Janet ; Pichaikaran, Sudhakar ; Selvam, Sandhiya ; Kotteswaran, Shanmugam ; Kumaresan, Natesan ; Pugazhendhi, Arivalagan ; Rajesh Kumar, Manavalan ; AL Garalleh, Hakim ; Ali Alshehri, Mohammed ; Murugadoss, Govindhasamy</creatorcontrib><description>Dye-sensitized solar cells, represent the alternate technology in solar research due to their cost effective, easy fabrication processes, higher efficiencies, and design flexibility. In this research, dual donor group modified zinc porphyrin dyes, have been synthesized for DSSCs. The complexes of zinc porphyrin functioned as acceptor or attaching groups within each mesophenyl ring and carboxylic acid. These complexes exhibited diverse alkyl substituents and sizable electron-donating substituents, contributing to their varied chemical structures and potential applications. The dual Donor-π bridge -Acceptor group sensitizers, Zn[5,15-diphenylcarbazole-10,20-(4-carboxyphenyl) Porphyrin] (KSR-1) and Zn [5,15-thiadiazole-10,20-(4-carboxyphenyl) Porphyrin] (KSR-2) have been synthesized and adopted for DSSCs implementation. The molar absorption coefficients (ε) of KSR-2 and KSR-1 Soret bands were 0.56 x 105 mol/L/cm and 0.47 x 105 mol/L/cm, respectively. The Q bands of the KSR-1 and KSR-2 dyes were 1.10 x 105 mol/L/cm and 1.0 x 105 mol/L/cm, respectively and the molar absorption coefficient of the KSR-1 dye was greater when compared to the KSR-2 dye. The molar absorption coefficient of 0.71 x 105 mol/L/cm was visible in the KSR -1 Q-band. DFT calculations and the electrochemical characteristics of the KSR-1 and KSR-2 dyes have been studied and discussed. The exploration involved in investigating the photophysical properties and photovoltaic performance which were affected by varying the length and number of the donor entities. The wall-plug efficiency of the KSR-1 based solar panel was Voc = 0.68 V, Jsc = 8.94 mA/m2, FF = 56 and Efficiency (μ) = 3.44%. The wall-plug efficiency of the KSR-2 based solar panel was Voc = 0.63 V, Jsc = 5.42 mA/m2, FF = 53 and Efficiency (μ) = 1.83%. •A novel Donor-π-Acceptor based Zn-Porphyrins have been designed and synthesized.•Diphenyl carbazole used as a donor instead of thiadiazol in the Porphyrin core.•Molar extinction coefficient of KSR-1 was increased due to Diphenyl carbazole.•Energy band alignment in Diphenyl carbazole based Zn-Porphyrin is suitable for DSSC.•KSR-1 cell efficiency was achieved almost equal to commercially available dye.</description><identifier>ISSN: 0013-9351</identifier><identifier>ISSN: 1096-0953</identifier><identifier>EISSN: 1096-0953</identifier><identifier>DOI: 10.1016/j.envres.2024.118704</identifier><identifier>PMID: 38493852</identifier><language>eng</language><publisher>Netherlands: Elsevier Inc</publisher><subject>Donor groups ; Economic ; High efficiency ; Solar cells ; Zn-porphyrins</subject><ispartof>Environmental research, 2024-06, Vol.251 (Pt 2), p.118704, Article 118704</ispartof><rights>2024 Elsevier Inc.</rights><rights>Copyright © 2024 Elsevier Inc. All rights reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c311t-92dddef849c7b201292bd301f7dec3d57f9589c2df60b5e06a18bd60cac586323</cites><orcidid>0000-0002-0972-2726</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.envres.2024.118704$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/38493852$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Dayanithi, Janet</creatorcontrib><creatorcontrib>Pichaikaran, Sudhakar</creatorcontrib><creatorcontrib>Selvam, Sandhiya</creatorcontrib><creatorcontrib>Kotteswaran, Shanmugam</creatorcontrib><creatorcontrib>Kumaresan, Natesan</creatorcontrib><creatorcontrib>Pugazhendhi, Arivalagan</creatorcontrib><creatorcontrib>Rajesh Kumar, Manavalan</creatorcontrib><creatorcontrib>AL Garalleh, Hakim</creatorcontrib><creatorcontrib>Ali Alshehri, Mohammed</creatorcontrib><creatorcontrib>Murugadoss, Govindhasamy</creatorcontrib><title>4-Carboxyphenyl as efficient donor group in nano Zn-Porphyrin for dye sensitized solar cells</title><title>Environmental research</title><addtitle>Environ Res</addtitle><description>Dye-sensitized solar cells, represent the alternate technology in solar research due to their cost effective, easy fabrication processes, higher efficiencies, and design flexibility. In this research, dual donor group modified zinc porphyrin dyes, have been synthesized for DSSCs. The complexes of zinc porphyrin functioned as acceptor or attaching groups within each mesophenyl ring and carboxylic acid. These complexes exhibited diverse alkyl substituents and sizable electron-donating substituents, contributing to their varied chemical structures and potential applications. The dual Donor-π bridge -Acceptor group sensitizers, Zn[5,15-diphenylcarbazole-10,20-(4-carboxyphenyl) Porphyrin] (KSR-1) and Zn [5,15-thiadiazole-10,20-(4-carboxyphenyl) Porphyrin] (KSR-2) have been synthesized and adopted for DSSCs implementation. The molar absorption coefficients (ε) of KSR-2 and KSR-1 Soret bands were 0.56 x 105 mol/L/cm and 0.47 x 105 mol/L/cm, respectively. The Q bands of the KSR-1 and KSR-2 dyes were 1.10 x 105 mol/L/cm and 1.0 x 105 mol/L/cm, respectively and the molar absorption coefficient of the KSR-1 dye was greater when compared to the KSR-2 dye. The molar absorption coefficient of 0.71 x 105 mol/L/cm was visible in the KSR -1 Q-band. DFT calculations and the electrochemical characteristics of the KSR-1 and KSR-2 dyes have been studied and discussed. The exploration involved in investigating the photophysical properties and photovoltaic performance which were affected by varying the length and number of the donor entities. The wall-plug efficiency of the KSR-1 based solar panel was Voc = 0.68 V, Jsc = 8.94 mA/m2, FF = 56 and Efficiency (μ) = 3.44%. The wall-plug efficiency of the KSR-2 based solar panel was Voc = 0.63 V, Jsc = 5.42 mA/m2, FF = 53 and Efficiency (μ) = 1.83%. •A novel Donor-π-Acceptor based Zn-Porphyrins have been designed and synthesized.•Diphenyl carbazole used as a donor instead of thiadiazol in the Porphyrin core.•Molar extinction coefficient of KSR-1 was increased due to Diphenyl carbazole.•Energy band alignment in Diphenyl carbazole based Zn-Porphyrin is suitable for DSSC.•KSR-1 cell efficiency was achieved almost equal to commercially available dye.</description><subject>Donor groups</subject><subject>Economic</subject><subject>High efficiency</subject><subject>Solar cells</subject><subject>Zn-porphyrins</subject><issn>0013-9351</issn><issn>1096-0953</issn><issn>1096-0953</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNp9kE1P3DAQhq0KVBbaf1BVPnLJ4o84iS9I1aotSEhwgEtVyXLscfEqa6d2FjX8-noV4MhpNDPvzDvzIPSFkjUltLnYriE8JchrRli9prRrSf0BrSiRTUWk4EdoRQjlleSCnqDTnLclpYKTj-iEd7XknWAr9LuuNjr18d88PkKYB6wzBue88RAmbGOICf9JcT9iH3DQIeJfobqLaXycU6m40rYz4Awh-8k_g8U5DjphA8OQP6Fjp4cMn1_iGXr48f1-c1Xd3P683ny7qQyndKoks9aCKzeZtmeEMsl6ywl1rQXDrWidFJ00zLqG9AJIo2nX24YYbUTXcMbP0Pmyd0zx7x7ypHY-Hy7QAeI-KyablghZABVpvUhNijkncGpMfqfTrChRB65qqxau6sBVLVzL2NcXh32_A_s29AqyCC4XAZQ_nzwklQ8IDVifwEzKRv--w38fdowA</recordid><startdate>20240615</startdate><enddate>20240615</enddate><creator>Dayanithi, Janet</creator><creator>Pichaikaran, Sudhakar</creator><creator>Selvam, Sandhiya</creator><creator>Kotteswaran, Shanmugam</creator><creator>Kumaresan, Natesan</creator><creator>Pugazhendhi, Arivalagan</creator><creator>Rajesh Kumar, Manavalan</creator><creator>AL Garalleh, Hakim</creator><creator>Ali Alshehri, Mohammed</creator><creator>Murugadoss, Govindhasamy</creator><general>Elsevier Inc</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-0972-2726</orcidid></search><sort><creationdate>20240615</creationdate><title>4-Carboxyphenyl as efficient donor group in nano Zn-Porphyrin for dye sensitized solar cells</title><author>Dayanithi, Janet ; Pichaikaran, Sudhakar ; Selvam, Sandhiya ; Kotteswaran, Shanmugam ; Kumaresan, Natesan ; Pugazhendhi, Arivalagan ; Rajesh Kumar, Manavalan ; AL Garalleh, Hakim ; Ali Alshehri, Mohammed ; Murugadoss, Govindhasamy</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c311t-92dddef849c7b201292bd301f7dec3d57f9589c2df60b5e06a18bd60cac586323</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Donor groups</topic><topic>Economic</topic><topic>High efficiency</topic><topic>Solar cells</topic><topic>Zn-porphyrins</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Dayanithi, Janet</creatorcontrib><creatorcontrib>Pichaikaran, Sudhakar</creatorcontrib><creatorcontrib>Selvam, Sandhiya</creatorcontrib><creatorcontrib>Kotteswaran, Shanmugam</creatorcontrib><creatorcontrib>Kumaresan, Natesan</creatorcontrib><creatorcontrib>Pugazhendhi, Arivalagan</creatorcontrib><creatorcontrib>Rajesh Kumar, Manavalan</creatorcontrib><creatorcontrib>AL Garalleh, Hakim</creatorcontrib><creatorcontrib>Ali Alshehri, Mohammed</creatorcontrib><creatorcontrib>Murugadoss, Govindhasamy</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Environmental research</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Dayanithi, Janet</au><au>Pichaikaran, Sudhakar</au><au>Selvam, Sandhiya</au><au>Kotteswaran, Shanmugam</au><au>Kumaresan, Natesan</au><au>Pugazhendhi, Arivalagan</au><au>Rajesh Kumar, Manavalan</au><au>AL Garalleh, Hakim</au><au>Ali Alshehri, Mohammed</au><au>Murugadoss, Govindhasamy</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>4-Carboxyphenyl as efficient donor group in nano Zn-Porphyrin for dye sensitized solar cells</atitle><jtitle>Environmental research</jtitle><addtitle>Environ Res</addtitle><date>2024-06-15</date><risdate>2024</risdate><volume>251</volume><issue>Pt 2</issue><spage>118704</spage><pages>118704-</pages><artnum>118704</artnum><issn>0013-9351</issn><issn>1096-0953</issn><eissn>1096-0953</eissn><abstract>Dye-sensitized solar cells, represent the alternate technology in solar research due to their cost effective, easy fabrication processes, higher efficiencies, and design flexibility. In this research, dual donor group modified zinc porphyrin dyes, have been synthesized for DSSCs. The complexes of zinc porphyrin functioned as acceptor or attaching groups within each mesophenyl ring and carboxylic acid. These complexes exhibited diverse alkyl substituents and sizable electron-donating substituents, contributing to their varied chemical structures and potential applications. The dual Donor-π bridge -Acceptor group sensitizers, Zn[5,15-diphenylcarbazole-10,20-(4-carboxyphenyl) Porphyrin] (KSR-1) and Zn [5,15-thiadiazole-10,20-(4-carboxyphenyl) Porphyrin] (KSR-2) have been synthesized and adopted for DSSCs implementation. The molar absorption coefficients (ε) of KSR-2 and KSR-1 Soret bands were 0.56 x 105 mol/L/cm and 0.47 x 105 mol/L/cm, respectively. The Q bands of the KSR-1 and KSR-2 dyes were 1.10 x 105 mol/L/cm and 1.0 x 105 mol/L/cm, respectively and the molar absorption coefficient of the KSR-1 dye was greater when compared to the KSR-2 dye. The molar absorption coefficient of 0.71 x 105 mol/L/cm was visible in the KSR -1 Q-band. DFT calculations and the electrochemical characteristics of the KSR-1 and KSR-2 dyes have been studied and discussed. The exploration involved in investigating the photophysical properties and photovoltaic performance which were affected by varying the length and number of the donor entities. The wall-plug efficiency of the KSR-1 based solar panel was Voc = 0.68 V, Jsc = 8.94 mA/m2, FF = 56 and Efficiency (μ) = 3.44%. The wall-plug efficiency of the KSR-2 based solar panel was Voc = 0.63 V, Jsc = 5.42 mA/m2, FF = 53 and Efficiency (μ) = 1.83%. •A novel Donor-π-Acceptor based Zn-Porphyrins have been designed and synthesized.•Diphenyl carbazole used as a donor instead of thiadiazol in the Porphyrin core.•Molar extinction coefficient of KSR-1 was increased due to Diphenyl carbazole.•Energy band alignment in Diphenyl carbazole based Zn-Porphyrin is suitable for DSSC.•KSR-1 cell efficiency was achieved almost equal to commercially available dye.</abstract><cop>Netherlands</cop><pub>Elsevier Inc</pub><pmid>38493852</pmid><doi>10.1016/j.envres.2024.118704</doi><orcidid>https://orcid.org/0000-0002-0972-2726</orcidid></addata></record>
fulltext fulltext
identifier ISSN: 0013-9351
ispartof Environmental research, 2024-06, Vol.251 (Pt 2), p.118704, Article 118704
issn 0013-9351
1096-0953
1096-0953
language eng
recordid cdi_proquest_miscellaneous_2967059704
source ScienceDirect Freedom Collection (Elsevier)
subjects Donor groups
Economic
High efficiency
Solar cells
Zn-porphyrins
title 4-Carboxyphenyl as efficient donor group in nano Zn-Porphyrin for dye sensitized solar cells
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-25T06%3A12%3A09IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=4-Carboxyphenyl%20as%20efficient%20donor%20group%20in%20nano%20Zn-Porphyrin%20for%20dye%20sensitized%20solar%20cells&rft.jtitle=Environmental%20research&rft.au=Dayanithi,%20Janet&rft.date=2024-06-15&rft.volume=251&rft.issue=Pt%202&rft.spage=118704&rft.pages=118704-&rft.artnum=118704&rft.issn=0013-9351&rft.eissn=1096-0953&rft_id=info:doi/10.1016/j.envres.2024.118704&rft_dat=%3Cproquest_cross%3E2967059704%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2967059704&rft_id=info:pmid/38493852&rft_els_id=S001393512400608X&rfr_iscdi=true