Surface modification of poly(propylene carbonate) by oxygen ion implantation
Poly(propylene carbonate) (PPC) was implanted by oxygen ion with energy of 40 keV. The influence of experimental parameters was investigated by varying ion fluence from 1 × 10 12 to 1 × 10 15 ions/cm 2. XPS, SEM, surface roughness, wettability, hardness, and modulus were employed to investigate stru...
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| Veröffentlicht in: | Applied surface science 2007-04, Vol.253 (12), p.5436-5441 |
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| creator | Zhang, Jizhong Kang, Jiachen Hu, Ping Meng, Qingli |
| description | Poly(propylene carbonate) (PPC) was implanted by oxygen ion with energy of 40
keV. The influence of experimental parameters was investigated by varying ion fluence from 1
×
10
12 to 1
×
10
15
ions/cm
2. XPS, SEM, surface roughness, wettability, hardness, and modulus were employed to investigate structure and properties of the as-implanted PPC samples. Eight chemical groups, i.e., carbon, C
H, C
O
C, C
O, O
C
O, C
O,
▪, and
▪ groups were observed on surfaces of the as-implanted samples. The species and relative intensities of the chemical groups changed with increasing ion fluence. SEM images displayed that irradiation damage was related strongly with ion fluence. Both surface-recovering and shrunken behavior were observed on surface of the PPC sample implanted with fluence of 1
×
10
15
ions/cm
2. As increasing ion fluence, the surface roughness of the as-implanted PPC samples increased firstly, reached the maximum value of 159
nm, and finally decreased down the minimum value. The water droplet contact angle of the as-implanted PPC samples changed gradually with fluence, and reached the minimum value of 70° with fluence of 1
×
10
15
ions/cm
2. The hardness and modulus of the as-implanted PPC samples increased with increasing ion fluence, and reached their corresponding maximum values with fluence of 1
×
10
15
ions/cm
2. The experimental results revealed that oxygen ion fluence closely affected surface chemical group, morphology, surface roughness, wettability, and mechanical properties of the as-implanted PPC samples. |
| doi_str_mv | 10.1016/j.apsusc.2006.12.023 |
| format | Article |
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keV. The influence of experimental parameters was investigated by varying ion fluence from 1
×
10
12 to 1
×
10
15
ions/cm
2. XPS, SEM, surface roughness, wettability, hardness, and modulus were employed to investigate structure and properties of the as-implanted PPC samples. Eight chemical groups, i.e., carbon, C
H, C
O
C, C
O, O
C
O, C
O,
▪, and
▪ groups were observed on surfaces of the as-implanted samples. The species and relative intensities of the chemical groups changed with increasing ion fluence. SEM images displayed that irradiation damage was related strongly with ion fluence. Both surface-recovering and shrunken behavior were observed on surface of the PPC sample implanted with fluence of 1
×
10
15
ions/cm
2. As increasing ion fluence, the surface roughness of the as-implanted PPC samples increased firstly, reached the maximum value of 159
nm, and finally decreased down the minimum value. The water droplet contact angle of the as-implanted PPC samples changed gradually with fluence, and reached the minimum value of 70° with fluence of 1
×
10
15
ions/cm
2. The hardness and modulus of the as-implanted PPC samples increased with increasing ion fluence, and reached their corresponding maximum values with fluence of 1
×
10
15
ions/cm
2. The experimental results revealed that oxygen ion fluence closely affected surface chemical group, morphology, surface roughness, wettability, and mechanical properties of the as-implanted PPC samples.</description><identifier>ISSN: 0169-4332</identifier><identifier>EISSN: 1873-5584</identifier><identifier>DOI: 10.1016/j.apsusc.2006.12.023</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Condensed matter: structure, mechanical and thermal properties ; Defects and impurities in crystals; microstructure ; Doping and impurity implantation in other materials ; Exact sciences and technology ; Mechanical and acoustical properties; adhesion ; Oxygen ion implantation ; Physics ; Poly(propylene carbonate) ; Polymers, elastomers, and plastics ; Solid surfaces and solid-solid interfaces ; Structure of solids and liquids; crystallography ; Surface modification ; Surfaces and interfaces; thin films and whiskers (structure and nonelectronic properties)</subject><ispartof>Applied surface science, 2007-04, Vol.253 (12), p.5436-5441</ispartof><rights>2006 Elsevier B.V.</rights><rights>2007 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c464t-9d35532e15e509d883bee07a8af72b32d175e0148f26d319d110aba3505911ec3</citedby><cites>FETCH-LOGICAL-c464t-9d35532e15e509d883bee07a8af72b32d175e0148f26d319d110aba3505911ec3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.apsusc.2006.12.023$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,777,781,3538,27906,27907,45977</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=18633301$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Zhang, Jizhong</creatorcontrib><creatorcontrib>Kang, Jiachen</creatorcontrib><creatorcontrib>Hu, Ping</creatorcontrib><creatorcontrib>Meng, Qingli</creatorcontrib><title>Surface modification of poly(propylene carbonate) by oxygen ion implantation</title><title>Applied surface science</title><description>Poly(propylene carbonate) (PPC) was implanted by oxygen ion with energy of 40
keV. The influence of experimental parameters was investigated by varying ion fluence from 1
×
10
12 to 1
×
10
15
ions/cm
2. XPS, SEM, surface roughness, wettability, hardness, and modulus were employed to investigate structure and properties of the as-implanted PPC samples. Eight chemical groups, i.e., carbon, C
H, C
O
C, C
O, O
C
O, C
O,
▪, and
▪ groups were observed on surfaces of the as-implanted samples. The species and relative intensities of the chemical groups changed with increasing ion fluence. SEM images displayed that irradiation damage was related strongly with ion fluence. Both surface-recovering and shrunken behavior were observed on surface of the PPC sample implanted with fluence of 1
×
10
15
ions/cm
2. As increasing ion fluence, the surface roughness of the as-implanted PPC samples increased firstly, reached the maximum value of 159
nm, and finally decreased down the minimum value. The water droplet contact angle of the as-implanted PPC samples changed gradually with fluence, and reached the minimum value of 70° with fluence of 1
×
10
15
ions/cm
2. The hardness and modulus of the as-implanted PPC samples increased with increasing ion fluence, and reached their corresponding maximum values with fluence of 1
×
10
15
ions/cm
2. The experimental results revealed that oxygen ion fluence closely affected surface chemical group, morphology, surface roughness, wettability, and mechanical properties of the as-implanted PPC samples.</description><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>Defects and impurities in crystals; microstructure</subject><subject>Doping and impurity implantation in other materials</subject><subject>Exact sciences and technology</subject><subject>Mechanical and acoustical properties; adhesion</subject><subject>Oxygen ion implantation</subject><subject>Physics</subject><subject>Poly(propylene carbonate)</subject><subject>Polymers, elastomers, and plastics</subject><subject>Solid surfaces and solid-solid interfaces</subject><subject>Structure of solids and liquids; crystallography</subject><subject>Surface modification</subject><subject>Surfaces and interfaces; thin films and whiskers (structure and nonelectronic properties)</subject><issn>0169-4332</issn><issn>1873-5584</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2007</creationdate><recordtype>article</recordtype><recordid>eNqFkE1LxDAQhoMouK7-Aw-9KHpozSRNPy6CLH7Bggf1HNJ0Klnapiat2H9vd7vgTU9zmOd9Z3gIOQcaAYXkZhOpzg9eR4zSJAIWUcYPyAKylIdCZPEhWUxYHsacs2Ny4v2GUmDTdkHWr4OrlMagsaWpjFa9sW1gq6Cz9XjVOduNNbYYaOUK26oer4NiDOz3-IFtsEVN09Wq7Xe5U3JUqdrj2X4uyfvD_dvqKVy_PD6v7tahjpO4D_OSC8EZgkBB8zLLeIFIU5WpKmUFZyWkAinEWcWSkkNeAlBVKC6oyAFQ8yW5nHun_z4H9L1sjNdYT4-gHbxkeQJpnNN_QcjjNKE7MJ5B7az3DivZOdMoN0qgcutYbuTsWG4dS2BycjzFLvb9ymtVV0612vjfbJZwzilM3O3M4WTly6CTXhtsNZbGoe5lac3fh34An2eT2w</recordid><startdate>20070415</startdate><enddate>20070415</enddate><creator>Zhang, Jizhong</creator><creator>Kang, Jiachen</creator><creator>Hu, Ping</creator><creator>Meng, Qingli</creator><general>Elsevier B.V</general><general>Elsevier Science</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QO</scope><scope>8FD</scope><scope>FR3</scope><scope>P64</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20070415</creationdate><title>Surface modification of poly(propylene carbonate) by oxygen ion implantation</title><author>Zhang, Jizhong ; Kang, Jiachen ; Hu, Ping ; Meng, Qingli</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c464t-9d35532e15e509d883bee07a8af72b32d175e0148f26d319d110aba3505911ec3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2007</creationdate><topic>Condensed matter: structure, mechanical and thermal properties</topic><topic>Defects and impurities in crystals; microstructure</topic><topic>Doping and impurity implantation in other materials</topic><topic>Exact sciences and technology</topic><topic>Mechanical and acoustical properties; adhesion</topic><topic>Oxygen ion implantation</topic><topic>Physics</topic><topic>Poly(propylene carbonate)</topic><topic>Polymers, elastomers, and plastics</topic><topic>Solid surfaces and solid-solid interfaces</topic><topic>Structure of solids and liquids; crystallography</topic><topic>Surface modification</topic><topic>Surfaces and interfaces; thin films and whiskers (structure and nonelectronic properties)</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhang, Jizhong</creatorcontrib><creatorcontrib>Kang, Jiachen</creatorcontrib><creatorcontrib>Hu, Ping</creatorcontrib><creatorcontrib>Meng, Qingli</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Biotechnology Research Abstracts</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Applied surface science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhang, Jizhong</au><au>Kang, Jiachen</au><au>Hu, Ping</au><au>Meng, Qingli</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Surface modification of poly(propylene carbonate) by oxygen ion implantation</atitle><jtitle>Applied surface science</jtitle><date>2007-04-15</date><risdate>2007</risdate><volume>253</volume><issue>12</issue><spage>5436</spage><epage>5441</epage><pages>5436-5441</pages><issn>0169-4332</issn><eissn>1873-5584</eissn><abstract>Poly(propylene carbonate) (PPC) was implanted by oxygen ion with energy of 40
keV. The influence of experimental parameters was investigated by varying ion fluence from 1
×
10
12 to 1
×
10
15
ions/cm
2. XPS, SEM, surface roughness, wettability, hardness, and modulus were employed to investigate structure and properties of the as-implanted PPC samples. Eight chemical groups, i.e., carbon, C
H, C
O
C, C
O, O
C
O, C
O,
▪, and
▪ groups were observed on surfaces of the as-implanted samples. The species and relative intensities of the chemical groups changed with increasing ion fluence. SEM images displayed that irradiation damage was related strongly with ion fluence. Both surface-recovering and shrunken behavior were observed on surface of the PPC sample implanted with fluence of 1
×
10
15
ions/cm
2. As increasing ion fluence, the surface roughness of the as-implanted PPC samples increased firstly, reached the maximum value of 159
nm, and finally decreased down the minimum value. The water droplet contact angle of the as-implanted PPC samples changed gradually with fluence, and reached the minimum value of 70° with fluence of 1
×
10
15
ions/cm
2. The hardness and modulus of the as-implanted PPC samples increased with increasing ion fluence, and reached their corresponding maximum values with fluence of 1
×
10
15
ions/cm
2. The experimental results revealed that oxygen ion fluence closely affected surface chemical group, morphology, surface roughness, wettability, and mechanical properties of the as-implanted PPC samples.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.apsusc.2006.12.023</doi><tpages>6</tpages></addata></record> |
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| subjects | Condensed matter: structure, mechanical and thermal properties Defects and impurities in crystals microstructure Doping and impurity implantation in other materials Exact sciences and technology Mechanical and acoustical properties adhesion Oxygen ion implantation Physics Poly(propylene carbonate) Polymers, elastomers, and plastics Solid surfaces and solid-solid interfaces Structure of solids and liquids crystallography Surface modification Surfaces and interfaces thin films and whiskers (structure and nonelectronic properties) |
| title | Surface modification of poly(propylene carbonate) by oxygen ion implantation |
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