Characterization of odorous compounds from bleached kraft pulp mill effluent
Odour compounds to extracts of bleached kraft pulp mill effluent (BKME) have been characterized by olfactory gas chromatography (OGC) and gas chromatography-mass spectrometry. A variety of sulfury odours was detected by OGC in addition to woody and pulp mill-like odours. Three sulfur compounds were...
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| Veröffentlicht in: | Water science and technology 1995, Vol.31 (11), p.35-40 |
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| creator | Brownlee, B.G. Kenefick, S.L. Maclnnis, G.A. Hrudey, S.E. |
| description | Odour compounds to extracts of bleached kraft pulp mill effluent (BKME) have been characterized by olfactory gas chromatography (OGC) and gas chromatography-mass spectrometry. A variety of sulfury odours was detected by OGC in addition to woody and pulp mill-like odours. Three sulfur compounds were identified by comparison of retention times and partial mass spectra with authentic standards: dimethyl disulfide, 3-methylthiophene and thioanisole (methyl phenyl sulfide). Typical concentrations in BKME were 1, 0.05, and 0.5 µg/l, respectively. Their odour intensity is relatively low and they were not detected by OGC. Dimethyl trtsulfide was tentatively identified by comparison of its partial mass spectrum with a literature (library) spectrum. Its concentration in BKME was estimated at 0.5-2 µg/l. It corresponded to a skunky odour in the OGC profiles. Efforts to identify another odour peak, eluting just after 3-methylihiophene, with a pronounced alkyl sulfide odour were unsuccessful. |
| doi_str_mv | 10.1016/0273-1223(95)00453-T |
| format | Article |
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A variety of sulfury odours was detected by OGC in addition to woody and pulp mill-like odours. Three sulfur compounds were identified by comparison of retention times and partial mass spectra with authentic standards: dimethyl disulfide, 3-methylthiophene and thioanisole (methyl phenyl sulfide). Typical concentrations in BKME were 1, 0.05, and 0.5 µg/l, respectively. Their odour intensity is relatively low and they were not detected by OGC. Dimethyl trtsulfide was tentatively identified by comparison of its partial mass spectrum with a literature (library) spectrum. Its concentration in BKME was estimated at 0.5-2 µg/l. It corresponded to a skunky odour in the OGC profiles. Efforts to identify another odour peak, eluting just after 3-methylihiophene, with a pronounced alkyl sulfide odour were unsuccessful.</description><identifier>ISSN: 0273-1223</identifier><identifier>EISSN: 1996-9732</identifier><identifier>DOI: 10.1016/0273-1223(95)00453-T</identifier><language>eng</language><publisher>London: Elsevier Ltd</publisher><subject>Aroma compounds ; Bleaching ; Chromatography ; Dimethyl disulfide ; Dimethyl trisulfide ; Effluents ; Freshwater ; Gas chromatography ; Identification ; Industrial wastewater ; Kraft pulp ; Libraries ; Mass spectra ; Mass spectrometry ; Mass spectroscopy ; methyl phenyl sulfide ; methyl sulfide ; Odor intensity ; Odors ; Odour ; Olfaction ; olfactory gas chromatography ; organic sulfur compounds ; Profiles ; Pulp ; Pulp & paper industry ; Pulp & paper mills ; pulp and paper mill effluents ; Pulp mill effluents ; Pulp wastes ; Q1 ; Rivers ; sniff-GC ; Sulfides ; sulfides (organic) ; Sulfur ; Sulfur compounds ; Sulphides ; Sulphur ; Thioanisole ; thiophene ; thiophenes</subject><ispartof>Water science and technology, 1995, Vol.31 (11), p.35-40</ispartof><rights>1995 International Association on Water Quality</rights><rights>Copyright IWA Publishing Jun 1995</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c457t-a2bb6b17fa22788066b85fe0054677b831afeeadc6543c1230a46196245cea913</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>309,310,314,776,780,785,786,4009,4035,4036,23910,23911,25119,27902,27903,27904</link.rule.ids></links><search><contributor>Hrudey, SE</contributor><contributor>McGuire, MJ</contributor><contributor>Whitfield</contributor><creatorcontrib>Brownlee, B.G.</creatorcontrib><creatorcontrib>Kenefick, S.L.</creatorcontrib><creatorcontrib>Maclnnis, G.A.</creatorcontrib><creatorcontrib>Hrudey, S.E.</creatorcontrib><title>Characterization of odorous compounds from bleached kraft pulp mill effluent</title><title>Water science and technology</title><description>Odour compounds to extracts of bleached kraft pulp mill effluent (BKME) have been characterized by olfactory gas chromatography (OGC) and gas chromatography-mass spectrometry. A variety of sulfury odours was detected by OGC in addition to woody and pulp mill-like odours. Three sulfur compounds were identified by comparison of retention times and partial mass spectra with authentic standards: dimethyl disulfide, 3-methylthiophene and thioanisole (methyl phenyl sulfide). Typical concentrations in BKME were 1, 0.05, and 0.5 µg/l, respectively. Their odour intensity is relatively low and they were not detected by OGC. Dimethyl trtsulfide was tentatively identified by comparison of its partial mass spectrum with a literature (library) spectrum. Its concentration in BKME was estimated at 0.5-2 µg/l. It corresponded to a skunky odour in the OGC profiles. Efforts to identify another odour peak, eluting just after 3-methylihiophene, with a pronounced alkyl sulfide odour were unsuccessful.</description><subject>Aroma compounds</subject><subject>Bleaching</subject><subject>Chromatography</subject><subject>Dimethyl disulfide</subject><subject>Dimethyl trisulfide</subject><subject>Effluents</subject><subject>Freshwater</subject><subject>Gas chromatography</subject><subject>Identification</subject><subject>Industrial wastewater</subject><subject>Kraft pulp</subject><subject>Libraries</subject><subject>Mass spectra</subject><subject>Mass spectrometry</subject><subject>Mass spectroscopy</subject><subject>methyl phenyl sulfide</subject><subject>methyl sulfide</subject><subject>Odor intensity</subject><subject>Odors</subject><subject>Odour</subject><subject>Olfaction</subject><subject>olfactory gas chromatography</subject><subject>organic sulfur compounds</subject><subject>Profiles</subject><subject>Pulp</subject><subject>Pulp & paper industry</subject><subject>Pulp & paper mills</subject><subject>pulp and paper mill effluents</subject><subject>Pulp mill effluents</subject><subject>Pulp wastes</subject><subject>Q1</subject><subject>Rivers</subject><subject>sniff-GC</subject><subject>Sulfides</subject><subject>sulfides (organic)</subject><subject>Sulfur</subject><subject>Sulfur compounds</subject><subject>Sulphides</subject><subject>Sulphur</subject><subject>Thioanisole</subject><subject>thiophene</subject><subject>thiophenes</subject><issn>0273-1223</issn><issn>1996-9732</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1995</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNqN0s-L1DAUB_AiCo6r_4FgQRA9dH353VwEGXRdGNjDzp5Dmr64WdumJq2gf70ZR_bgwdlTLp_3kpf3raqXBM4JEPkeqGINoZS91eIdABes2T-qNkRr2WjF6ONqc0-eVs9yvgMAxThsqt321ibrFkzhl11CnOro69jHFNdcuzjOcZ36XPsUx7ob0Lpb7OtvyfqlntdhrscwDDV6P6w4Lc-rJ94OGV_8Pc-qm8-f9tsvze7q4nL7cdc4LtTSWNp1siPKW0pV24KUXSs8AggulepaRqxHtL2TgjNHKAPLJdGScuHQasLOqjfHvnOK31fMixlDdjgMdsLybkO1BEE1fQAknDFxuiMRspWMPAiCZkKehpy1LQU4DZnkqpWqwNf_wLu4pql8tCG6jEHLjnVR_Khcijkn9GZOYbTppyFgDmkxhyiYQxSMFuZPWsy-lL06lnkbjf2aQjY31xQIAyLKTLIt4sNRYNnsj4DJZBdwctiHhG4xfQz_v-I38FjNKg</recordid><startdate>1995</startdate><enddate>1995</enddate><creator>Brownlee, 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of odorous compounds from bleached kraft pulp mill effluent</title><author>Brownlee, B.G. ; Kenefick, S.L. ; Maclnnis, G.A. ; Hrudey, S.E.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c457t-a2bb6b17fa22788066b85fe0054677b831afeeadc6543c1230a46196245cea913</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1995</creationdate><topic>Aroma compounds</topic><topic>Bleaching</topic><topic>Chromatography</topic><topic>Dimethyl disulfide</topic><topic>Dimethyl trisulfide</topic><topic>Effluents</topic><topic>Freshwater</topic><topic>Gas chromatography</topic><topic>Identification</topic><topic>Industrial wastewater</topic><topic>Kraft pulp</topic><topic>Libraries</topic><topic>Mass spectra</topic><topic>Mass spectrometry</topic><topic>Mass spectroscopy</topic><topic>methyl phenyl sulfide</topic><topic>methyl sulfide</topic><topic>Odor intensity</topic><topic>Odors</topic><topic>Odour</topic><topic>Olfaction</topic><topic>olfactory gas chromatography</topic><topic>organic sulfur compounds</topic><topic>Profiles</topic><topic>Pulp</topic><topic>Pulp & paper industry</topic><topic>Pulp & paper mills</topic><topic>pulp and paper mill effluents</topic><topic>Pulp mill effluents</topic><topic>Pulp wastes</topic><topic>Q1</topic><topic>Rivers</topic><topic>sniff-GC</topic><topic>Sulfides</topic><topic>sulfides (organic)</topic><topic>Sulfur</topic><topic>Sulfur compounds</topic><topic>Sulphides</topic><topic>Sulphur</topic><topic>Thioanisole</topic><topic>thiophene</topic><topic>thiophenes</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Brownlee, B.G.</creatorcontrib><creatorcontrib>Kenefick, S.L.</creatorcontrib><creatorcontrib>Maclnnis, G.A.</creatorcontrib><creatorcontrib>Hrudey, 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technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Brownlee, B.G.</au><au>Kenefick, S.L.</au><au>Maclnnis, G.A.</au><au>Hrudey, S.E.</au><au>Hrudey, SE</au><au>McGuire, MJ</au><au>Whitfield</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Characterization of odorous compounds from bleached kraft pulp mill effluent</atitle><jtitle>Water science and technology</jtitle><date>1995</date><risdate>1995</risdate><volume>31</volume><issue>11</issue><spage>35</spage><epage>40</epage><pages>35-40</pages><issn>0273-1223</issn><eissn>1996-9732</eissn><abstract>Odour compounds to extracts of bleached kraft pulp mill effluent (BKME) have been characterized by olfactory gas chromatography (OGC) and gas chromatography-mass spectrometry. A variety of sulfury odours was detected by OGC in addition to woody and pulp mill-like odours. Three sulfur compounds were identified by comparison of retention times and partial mass spectra with authentic standards: dimethyl disulfide, 3-methylthiophene and thioanisole (methyl phenyl sulfide). Typical concentrations in BKME were 1, 0.05, and 0.5 µg/l, respectively. Their odour intensity is relatively low and they were not detected by OGC. Dimethyl trtsulfide was tentatively identified by comparison of its partial mass spectrum with a literature (library) spectrum. Its concentration in BKME was estimated at 0.5-2 µg/l. It corresponded to a skunky odour in the OGC profiles. Efforts to identify another odour peak, eluting just after 3-methylihiophene, with a pronounced alkyl sulfide odour were unsuccessful.</abstract><cop>London</cop><pub>Elsevier Ltd</pub><doi>10.1016/0273-1223(95)00453-T</doi><tpages>6</tpages></addata></record> |
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| ispartof | Water science and technology, 1995, Vol.31 (11), p.35-40 |
| issn | 0273-1223 1996-9732 |
| language | eng |
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| source | Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals |
| subjects | Aroma compounds Bleaching Chromatography Dimethyl disulfide Dimethyl trisulfide Effluents Freshwater Gas chromatography Identification Industrial wastewater Kraft pulp Libraries Mass spectra Mass spectrometry Mass spectroscopy methyl phenyl sulfide methyl sulfide Odor intensity Odors Odour Olfaction olfactory gas chromatography organic sulfur compounds Profiles Pulp Pulp & paper industry Pulp & paper mills pulp and paper mill effluents Pulp mill effluents Pulp wastes Q1 Rivers sniff-GC Sulfides sulfides (organic) Sulfur Sulfur compounds Sulphides Sulphur Thioanisole thiophene thiophenes |
| title | Characterization of odorous compounds from bleached kraft pulp mill effluent |
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