Sol-gel processing of Sr0.5Sm0.5CoO3 film
Strontium-doped samarium cobaltite (Sm0.5Sr0.5CoO3, SSC) has attracted increasing attention as cathode material for intermediate-temperature solid oxide fuel cells (IT-SOFCs) due to its mixed-conduction characteristics and relatively high ionic conductivity. In this paper, sol-gel-derived SSC films...
Gespeichert in:
| Veröffentlicht in: | Journal of power sources 2006-06, Vol.157 (1), p.385-388 |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 388 |
|---|---|
| container_issue | 1 |
| container_start_page | 385 |
| container_title | Journal of power sources |
| container_volume | 157 |
| creator | ZHAOLIN TANG YONGSONG XIE HAWTHORNE, Howard GHOSH, Dave |
| description | Strontium-doped samarium cobaltite (Sm0.5Sr0.5CoO3, SSC) has attracted increasing attention as cathode material for intermediate-temperature solid oxide fuel cells (IT-SOFCs) due to its mixed-conduction characteristics and relatively high ionic conductivity. In this paper, sol-gel-derived SSC films were deposited on yttria stabilized zirconia (YSZ) substrates from an alkoxide solution of strontium isopropoxide, samarium isopropoxide and cobalt isopropoxide. The alkoxide solution was chelated with 2-ethylacetoacetate (CH3COCH2COOC2H5), and the effect of polyethylene glycol (PEG) addition on the crystallization behavior and microstructure evolution of SSC films was investigated. XRD, TGA and SEM measurements indicated that single-perovskite phase SSC films were formed when the films were heated at 700 deg C, and PEG could significantly refine the crystalline size of the SSC film from around 100-50nm. |
| doi_str_mv | 10.1016/j.jpowsour.2005.07.041 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_29601230</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>29601230</sourcerecordid><originalsourceid>FETCH-LOGICAL-c316t-a6742d38910f25e8870d01648f1cf779f793f0639edc1ee42c51bac1436ff1b33</originalsourceid><addsrcrecordid>eNpFkEtLAzEUhYMoWKt_QWaj4GLGe_OepRRfUOiiug5pmpQZZpqadBD_vVNacXPu5px7Dh8htwgVAsrHtmp38TvHIVUUQFSgKuB4RiaoFSupEuKcTIApXSol2CW5yrkFAEQFE_KwjF258V2xS9H5nJvtpoihWCaoxLIfZRYXrAhN11-Ti2C77G9Od0o-X54_Zm_lfPH6Pnual46h3JdWKk7XTNcIgQqvtYL1uJLrgC4oVQdVswCS1X7t0HtOncCVdciZDAFXjE3J_fHvuOhr8Hlv-iY733V26-OQDa0lIGUwGuXR6FLMOflgdqnpbfoxCOZAxrTmj4w5kDGgzEhmDN6dGmx2tgvJbl2T_9NK15wzZL_3W2QV</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>29601230</pqid></control><display><type>article</type><title>Sol-gel processing of Sr0.5Sm0.5CoO3 film</title><source>Elsevier ScienceDirect Journals</source><creator>ZHAOLIN TANG ; YONGSONG XIE ; HAWTHORNE, Howard ; GHOSH, Dave</creator><creatorcontrib>ZHAOLIN TANG ; YONGSONG XIE ; HAWTHORNE, Howard ; GHOSH, Dave</creatorcontrib><description>Strontium-doped samarium cobaltite (Sm0.5Sr0.5CoO3, SSC) has attracted increasing attention as cathode material for intermediate-temperature solid oxide fuel cells (IT-SOFCs) due to its mixed-conduction characteristics and relatively high ionic conductivity. In this paper, sol-gel-derived SSC films were deposited on yttria stabilized zirconia (YSZ) substrates from an alkoxide solution of strontium isopropoxide, samarium isopropoxide and cobalt isopropoxide. The alkoxide solution was chelated with 2-ethylacetoacetate (CH3COCH2COOC2H5), and the effect of polyethylene glycol (PEG) addition on the crystallization behavior and microstructure evolution of SSC films was investigated. XRD, TGA and SEM measurements indicated that single-perovskite phase SSC films were formed when the films were heated at 700 deg C, and PEG could significantly refine the crystalline size of the SSC film from around 100-50nm.</description><identifier>ISSN: 0378-7753</identifier><identifier>EISSN: 1873-2755</identifier><identifier>DOI: 10.1016/j.jpowsour.2005.07.041</identifier><identifier>CODEN: JPSODZ</identifier><language>eng</language><publisher>Lausanne: Elsevier Sequoia</publisher><subject>Applied sciences ; Energy ; Energy. Thermal use of fuels ; Equipments for energy generation and conversion: thermal, electrical, mechanical energy, etc ; Exact sciences and technology ; Fuel cells</subject><ispartof>Journal of power sources, 2006-06, Vol.157 (1), p.385-388</ispartof><rights>2006 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-a6742d38910f25e8870d01648f1cf779f793f0639edc1ee42c51bac1436ff1b33</citedby><cites>FETCH-LOGICAL-c316t-a6742d38910f25e8870d01648f1cf779f793f0639edc1ee42c51bac1436ff1b33</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=17894431$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>ZHAOLIN TANG</creatorcontrib><creatorcontrib>YONGSONG XIE</creatorcontrib><creatorcontrib>HAWTHORNE, Howard</creatorcontrib><creatorcontrib>GHOSH, Dave</creatorcontrib><title>Sol-gel processing of Sr0.5Sm0.5CoO3 film</title><title>Journal of power sources</title><description>Strontium-doped samarium cobaltite (Sm0.5Sr0.5CoO3, SSC) has attracted increasing attention as cathode material for intermediate-temperature solid oxide fuel cells (IT-SOFCs) due to its mixed-conduction characteristics and relatively high ionic conductivity. In this paper, sol-gel-derived SSC films were deposited on yttria stabilized zirconia (YSZ) substrates from an alkoxide solution of strontium isopropoxide, samarium isopropoxide and cobalt isopropoxide. The alkoxide solution was chelated with 2-ethylacetoacetate (CH3COCH2COOC2H5), and the effect of polyethylene glycol (PEG) addition on the crystallization behavior and microstructure evolution of SSC films was investigated. XRD, TGA and SEM measurements indicated that single-perovskite phase SSC films were formed when the films were heated at 700 deg C, and PEG could significantly refine the crystalline size of the SSC film from around 100-50nm.</description><subject>Applied sciences</subject><subject>Energy</subject><subject>Energy. Thermal use of fuels</subject><subject>Equipments for energy generation and conversion: thermal, electrical, mechanical energy, etc</subject><subject>Exact sciences and technology</subject><subject>Fuel cells</subject><issn>0378-7753</issn><issn>1873-2755</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2006</creationdate><recordtype>article</recordtype><recordid>eNpFkEtLAzEUhYMoWKt_QWaj4GLGe_OepRRfUOiiug5pmpQZZpqadBD_vVNacXPu5px7Dh8htwgVAsrHtmp38TvHIVUUQFSgKuB4RiaoFSupEuKcTIApXSol2CW5yrkFAEQFE_KwjF258V2xS9H5nJvtpoihWCaoxLIfZRYXrAhN11-Ti2C77G9Od0o-X54_Zm_lfPH6Pnual46h3JdWKk7XTNcIgQqvtYL1uJLrgC4oVQdVswCS1X7t0HtOncCVdciZDAFXjE3J_fHvuOhr8Hlv-iY733V26-OQDa0lIGUwGuXR6FLMOflgdqnpbfoxCOZAxrTmj4w5kDGgzEhmDN6dGmx2tgvJbl2T_9NK15wzZL_3W2QV</recordid><startdate>20060619</startdate><enddate>20060619</enddate><creator>ZHAOLIN TANG</creator><creator>YONGSONG XIE</creator><creator>HAWTHORNE, Howard</creator><creator>GHOSH, Dave</creator><general>Elsevier Sequoia</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7TB</scope><scope>8FD</scope><scope>FR3</scope><scope>KR7</scope><scope>L7M</scope></search><sort><creationdate>20060619</creationdate><title>Sol-gel processing of Sr0.5Sm0.5CoO3 film</title><author>ZHAOLIN TANG ; YONGSONG XIE ; HAWTHORNE, Howard ; GHOSH, Dave</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-a6742d38910f25e8870d01648f1cf779f793f0639edc1ee42c51bac1436ff1b33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2006</creationdate><topic>Applied sciences</topic><topic>Energy</topic><topic>Energy. Thermal use of fuels</topic><topic>Equipments for energy generation and conversion: thermal, electrical, mechanical energy, etc</topic><topic>Exact sciences and technology</topic><topic>Fuel cells</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>ZHAOLIN TANG</creatorcontrib><creatorcontrib>YONGSONG XIE</creatorcontrib><creatorcontrib>HAWTHORNE, Howard</creatorcontrib><creatorcontrib>GHOSH, Dave</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Civil Engineering Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of power sources</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>ZHAOLIN TANG</au><au>YONGSONG XIE</au><au>HAWTHORNE, Howard</au><au>GHOSH, Dave</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Sol-gel processing of Sr0.5Sm0.5CoO3 film</atitle><jtitle>Journal of power sources</jtitle><date>2006-06-19</date><risdate>2006</risdate><volume>157</volume><issue>1</issue><spage>385</spage><epage>388</epage><pages>385-388</pages><issn>0378-7753</issn><eissn>1873-2755</eissn><coden>JPSODZ</coden><abstract>Strontium-doped samarium cobaltite (Sm0.5Sr0.5CoO3, SSC) has attracted increasing attention as cathode material for intermediate-temperature solid oxide fuel cells (IT-SOFCs) due to its mixed-conduction characteristics and relatively high ionic conductivity. In this paper, sol-gel-derived SSC films were deposited on yttria stabilized zirconia (YSZ) substrates from an alkoxide solution of strontium isopropoxide, samarium isopropoxide and cobalt isopropoxide. The alkoxide solution was chelated with 2-ethylacetoacetate (CH3COCH2COOC2H5), and the effect of polyethylene glycol (PEG) addition on the crystallization behavior and microstructure evolution of SSC films was investigated. XRD, TGA and SEM measurements indicated that single-perovskite phase SSC films were formed when the films were heated at 700 deg C, and PEG could significantly refine the crystalline size of the SSC film from around 100-50nm.</abstract><cop>Lausanne</cop><pub>Elsevier Sequoia</pub><doi>10.1016/j.jpowsour.2005.07.041</doi><tpages>4</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0378-7753 |
| ispartof | Journal of power sources, 2006-06, Vol.157 (1), p.385-388 |
| issn | 0378-7753 1873-2755 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_29601230 |
| source | Elsevier ScienceDirect Journals |
| subjects | Applied sciences Energy Energy. Thermal use of fuels Equipments for energy generation and conversion: thermal, electrical, mechanical energy, etc Exact sciences and technology Fuel cells |
| title | Sol-gel processing of Sr0.5Sm0.5CoO3 film |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-28T16%3A08%3A33IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Sol-gel%20processing%20of%20Sr0.5Sm0.5CoO3%20film&rft.jtitle=Journal%20of%20power%20sources&rft.au=ZHAOLIN%20TANG&rft.date=2006-06-19&rft.volume=157&rft.issue=1&rft.spage=385&rft.epage=388&rft.pages=385-388&rft.issn=0378-7753&rft.eissn=1873-2755&rft.coden=JPSODZ&rft_id=info:doi/10.1016/j.jpowsour.2005.07.041&rft_dat=%3Cproquest_cross%3E29601230%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=29601230&rft_id=info:pmid/&rfr_iscdi=true |