Comparative structural investigation of aluminium fluoride solvates
To get some insight by conclusions of analogy into the drying process of alcoholic aluminium fluoride sol–gels [AlF 3/(ROH) x ], the structures of α- and β-AlF 3⋅3H 2O as well as of the nonahydrate AlF 3⋅9H 2O are reinvestigated and discussed based on X-ray single crystal structural data. In additio...
Gespeichert in:
| Veröffentlicht in: | Solid state sciences 2006-12, Vol.8 (12), p.1443-1452 |
|---|---|
| Hauptverfasser: | , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 1452 |
|---|---|
| container_issue | 12 |
| container_start_page | 1443 |
| container_title | Solid state sciences |
| container_volume | 8 |
| creator | Kemnitz, E. Groß, U. Rüdiger, St Scholz, G. Heidemann, D. Troyanov, S.I. Morosov, I.V. Lemée-Cailleau, M.-H. |
| description | To get some insight by conclusions of analogy into the drying process of alcoholic aluminium fluoride sol–gels [AlF
3/(ROH)
x
], the structures of
α- and
β-AlF
3⋅3H
2O as well as of the nonahydrate AlF
3⋅9H
2O are reinvestigated and discussed based on X-ray single crystal structural data. In addition, neutron diffraction experiments of the latter allowed the refinement of proton positions. In accordance with crystal structures, low-temperature solid state
27Al-,
1H- and
19F-MAS NMR spectra convincingly confirm the structural similarity between
α-AlF
3⋅3H
2O and AlF
3⋅9H
2O, while the
β-phase material is structurally different forming chain structures. Thermal analysis of AlF
3/(ROH)
x
gave evidence for discrete AlF
3:ROH ratios of only 1:0.45 and 1:0.1, and solution NMR showed some similarities between aqueous and alcoholic systems. |
| doi_str_mv | 10.1016/j.solidstatesciences.2006.07.008 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_29597896</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S1293255806002202</els_id><sourcerecordid>29597896</sourcerecordid><originalsourceid>FETCH-LOGICAL-c373t-7327995cd56f66c8d6e2dd304eda26f37b9e964a8ff5aa71160b3d96ea7818fe3</originalsourceid><addsrcrecordid>eNqNkE1LxDAQhosouH78h57ES2vSbPNxUxY_WfCi55BNJpIlbdYkLfjvzbJ78-JpBubhnZmnqm4xajHC9G7bpuCdSVllSNrBqCG1HUK0RaxFiJ9UC8wZaQji_WnpO0Garu_5eXWR0hYVkLLlolqtwrBTUWU3Q51ynHSeovK1G2dI2X2VQRjrYGvlp8GNbhpq66cQnSl48PN--1V1ZpVPcH2sl9Xn0-PH6qVZvz-_rh7WjSaM5IaRjgnRa9NTS6nmhkJnDEFLMKqjlrCNAEGXilvbK8UwpmhDjKCgGMfcArmsbg65uxi-p3KeHFzS4L0aIUxJdqIXjAtawPsDqGNIKYKVu-gGFX8kRnJvT27lX3tyb08iJou9EvF2iIDy0OwgyiNmXASdpQnu_2G_dX-HiA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>29597896</pqid></control><display><type>article</type><title>Comparative structural investigation of aluminium fluoride solvates</title><source>Elsevier ScienceDirect Journals</source><creator>Kemnitz, E. ; Groß, U. ; Rüdiger, St ; Scholz, G. ; Heidemann, D. ; Troyanov, S.I. ; Morosov, I.V. ; Lemée-Cailleau, M.-H.</creator><creatorcontrib>Kemnitz, E. ; Groß, U. ; Rüdiger, St ; Scholz, G. ; Heidemann, D. ; Troyanov, S.I. ; Morosov, I.V. ; Lemée-Cailleau, M.-H.</creatorcontrib><description>To get some insight by conclusions of analogy into the drying process of alcoholic aluminium fluoride sol–gels [AlF
3/(ROH)
x
], the structures of
α- and
β-AlF
3⋅3H
2O as well as of the nonahydrate AlF
3⋅9H
2O are reinvestigated and discussed based on X-ray single crystal structural data. In addition, neutron diffraction experiments of the latter allowed the refinement of proton positions. In accordance with crystal structures, low-temperature solid state
27Al-,
1H- and
19F-MAS NMR spectra convincingly confirm the structural similarity between
α-AlF
3⋅3H
2O and AlF
3⋅9H
2O, while the
β-phase material is structurally different forming chain structures. Thermal analysis of AlF
3/(ROH)
x
gave evidence for discrete AlF
3:ROH ratios of only 1:0.45 and 1:0.1, and solution NMR showed some similarities between aqueous and alcoholic systems.</description><identifier>ISSN: 1293-2558</identifier><identifier>EISSN: 1873-3085</identifier><identifier>DOI: 10.1016/j.solidstatesciences.2006.07.008</identifier><language>eng</language><publisher>Elsevier Masson SAS</publisher><subject>27Al-, 1H-, 19F-MAS NMR ; Aluminium fluoride hydrates/methanolates ; Low temperature NMR ; Single crystal structure</subject><ispartof>Solid state sciences, 2006-12, Vol.8 (12), p.1443-1452</ispartof><rights>2006 Elsevier SAS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c373t-7327995cd56f66c8d6e2dd304eda26f37b9e964a8ff5aa71160b3d96ea7818fe3</citedby><cites>FETCH-LOGICAL-c373t-7327995cd56f66c8d6e2dd304eda26f37b9e964a8ff5aa71160b3d96ea7818fe3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S1293255806002202$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids></links><search><creatorcontrib>Kemnitz, E.</creatorcontrib><creatorcontrib>Groß, U.</creatorcontrib><creatorcontrib>Rüdiger, St</creatorcontrib><creatorcontrib>Scholz, G.</creatorcontrib><creatorcontrib>Heidemann, D.</creatorcontrib><creatorcontrib>Troyanov, S.I.</creatorcontrib><creatorcontrib>Morosov, I.V.</creatorcontrib><creatorcontrib>Lemée-Cailleau, M.-H.</creatorcontrib><title>Comparative structural investigation of aluminium fluoride solvates</title><title>Solid state sciences</title><description>To get some insight by conclusions of analogy into the drying process of alcoholic aluminium fluoride sol–gels [AlF
3/(ROH)
x
], the structures of
α- and
β-AlF
3⋅3H
2O as well as of the nonahydrate AlF
3⋅9H
2O are reinvestigated and discussed based on X-ray single crystal structural data. In addition, neutron diffraction experiments of the latter allowed the refinement of proton positions. In accordance with crystal structures, low-temperature solid state
27Al-,
1H- and
19F-MAS NMR spectra convincingly confirm the structural similarity between
α-AlF
3⋅3H
2O and AlF
3⋅9H
2O, while the
β-phase material is structurally different forming chain structures. Thermal analysis of AlF
3/(ROH)
x
gave evidence for discrete AlF
3:ROH ratios of only 1:0.45 and 1:0.1, and solution NMR showed some similarities between aqueous and alcoholic systems.</description><subject>27Al-, 1H-, 19F-MAS NMR</subject><subject>Aluminium fluoride hydrates/methanolates</subject><subject>Low temperature NMR</subject><subject>Single crystal structure</subject><issn>1293-2558</issn><issn>1873-3085</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2006</creationdate><recordtype>article</recordtype><recordid>eNqNkE1LxDAQhosouH78h57ES2vSbPNxUxY_WfCi55BNJpIlbdYkLfjvzbJ78-JpBubhnZmnqm4xajHC9G7bpuCdSVllSNrBqCG1HUK0RaxFiJ9UC8wZaQji_WnpO0Garu_5eXWR0hYVkLLlolqtwrBTUWU3Q51ynHSeovK1G2dI2X2VQRjrYGvlp8GNbhpq66cQnSl48PN--1V1ZpVPcH2sl9Xn0-PH6qVZvz-_rh7WjSaM5IaRjgnRa9NTS6nmhkJnDEFLMKqjlrCNAEGXilvbK8UwpmhDjKCgGMfcArmsbg65uxi-p3KeHFzS4L0aIUxJdqIXjAtawPsDqGNIKYKVu-gGFX8kRnJvT27lX3tyb08iJou9EvF2iIDy0OwgyiNmXASdpQnu_2G_dX-HiA</recordid><startdate>20061201</startdate><enddate>20061201</enddate><creator>Kemnitz, E.</creator><creator>Groß, U.</creator><creator>Rüdiger, St</creator><creator>Scholz, G.</creator><creator>Heidemann, D.</creator><creator>Troyanov, S.I.</creator><creator>Morosov, I.V.</creator><creator>Lemée-Cailleau, M.-H.</creator><general>Elsevier Masson SAS</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20061201</creationdate><title>Comparative structural investigation of aluminium fluoride solvates</title><author>Kemnitz, E. ; Groß, U. ; Rüdiger, St ; Scholz, G. ; Heidemann, D. ; Troyanov, S.I. ; Morosov, I.V. ; Lemée-Cailleau, M.-H.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c373t-7327995cd56f66c8d6e2dd304eda26f37b9e964a8ff5aa71160b3d96ea7818fe3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2006</creationdate><topic>27Al-, 1H-, 19F-MAS NMR</topic><topic>Aluminium fluoride hydrates/methanolates</topic><topic>Low temperature NMR</topic><topic>Single crystal structure</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kemnitz, E.</creatorcontrib><creatorcontrib>Groß, U.</creatorcontrib><creatorcontrib>Rüdiger, St</creatorcontrib><creatorcontrib>Scholz, G.</creatorcontrib><creatorcontrib>Heidemann, D.</creatorcontrib><creatorcontrib>Troyanov, S.I.</creatorcontrib><creatorcontrib>Morosov, I.V.</creatorcontrib><creatorcontrib>Lemée-Cailleau, M.-H.</creatorcontrib><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Solid state sciences</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kemnitz, E.</au><au>Groß, U.</au><au>Rüdiger, St</au><au>Scholz, G.</au><au>Heidemann, D.</au><au>Troyanov, S.I.</au><au>Morosov, I.V.</au><au>Lemée-Cailleau, M.-H.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Comparative structural investigation of aluminium fluoride solvates</atitle><jtitle>Solid state sciences</jtitle><date>2006-12-01</date><risdate>2006</risdate><volume>8</volume><issue>12</issue><spage>1443</spage><epage>1452</epage><pages>1443-1452</pages><issn>1293-2558</issn><eissn>1873-3085</eissn><abstract>To get some insight by conclusions of analogy into the drying process of alcoholic aluminium fluoride sol–gels [AlF
3/(ROH)
x
], the structures of
α- and
β-AlF
3⋅3H
2O as well as of the nonahydrate AlF
3⋅9H
2O are reinvestigated and discussed based on X-ray single crystal structural data. In addition, neutron diffraction experiments of the latter allowed the refinement of proton positions. In accordance with crystal structures, low-temperature solid state
27Al-,
1H- and
19F-MAS NMR spectra convincingly confirm the structural similarity between
α-AlF
3⋅3H
2O and AlF
3⋅9H
2O, while the
β-phase material is structurally different forming chain structures. Thermal analysis of AlF
3/(ROH)
x
gave evidence for discrete AlF
3:ROH ratios of only 1:0.45 and 1:0.1, and solution NMR showed some similarities between aqueous and alcoholic systems.</abstract><pub>Elsevier Masson SAS</pub><doi>10.1016/j.solidstatesciences.2006.07.008</doi><tpages>10</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1293-2558 |
| ispartof | Solid state sciences, 2006-12, Vol.8 (12), p.1443-1452 |
| issn | 1293-2558 1873-3085 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_29597896 |
| source | Elsevier ScienceDirect Journals |
| subjects | 27Al-, 1H-, 19F-MAS NMR Aluminium fluoride hydrates/methanolates Low temperature NMR Single crystal structure |
| title | Comparative structural investigation of aluminium fluoride solvates |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-05T04%3A54%3A39IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Comparative%20structural%20investigation%20of%20aluminium%20fluoride%20solvates&rft.jtitle=Solid%20state%20sciences&rft.au=Kemnitz,%20E.&rft.date=2006-12-01&rft.volume=8&rft.issue=12&rft.spage=1443&rft.epage=1452&rft.pages=1443-1452&rft.issn=1293-2558&rft.eissn=1873-3085&rft_id=info:doi/10.1016/j.solidstatesciences.2006.07.008&rft_dat=%3Cproquest_cross%3E29597896%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=29597896&rft_id=info:pmid/&rft_els_id=S1293255806002202&rfr_iscdi=true |