The effects of nitrogen and boron doping on the optical emission and diameters of single-walled carbon nanotubes

Using TEM, absorption and photoluminescence-excitation spectroscopy we have shown that nitrogen and nitrogen/boron doping of single-walled carbon nanotubes produce significant changes in both the optical properties and the diameter distribution of nanotubes produced by the arc-discharge method. Smal...

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Veröffentlicht in:Carbon (New York) 2006-11, Vol.44 (13), p.2752-2757
Hauptverfasser: Li, Lain-Jong, Glerup, M., Khlobystov, A.N., Wiltshire, J.G., Sauvajol, J.-L., Taylor, R.A., Nicholas, R.J.
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container_end_page 2757
container_issue 13
container_start_page 2752
container_title Carbon (New York)
container_volume 44
creator Li, Lain-Jong
Glerup, M.
Khlobystov, A.N.
Wiltshire, J.G.
Sauvajol, J.-L.
Taylor, R.A.
Nicholas, R.J.
description Using TEM, absorption and photoluminescence-excitation spectroscopy we have shown that nitrogen and nitrogen/boron doping of single-walled carbon nanotubes produce significant changes in both the optical properties and the diameter distribution of nanotubes produced by the arc-discharge method. Smaller diameter tubes are preferentially formed in the presence of boron. In addition the presence of nitrogen is found to significantly affect the emission properties of the nanotube ensemble, causing a shift in the dominant emission to lower energies, possibly due to changes in the bundling structure of the nanotubes in solution, but only very small changes are observed in the emission energies for individual nanotubes.
doi_str_mv 10.1016/j.carbon.2006.03.037
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subjects Carbon nanotubes
Cross-disciplinary physics: materials science
rheology
Doped carbon
Exact sciences and technology
Fullerenes and related materials
diamonds, graphite
Luminescence
Materials science
Physics
Specific materials
Transmission electron microscopy
title The effects of nitrogen and boron doping on the optical emission and diameters of single-walled carbon nanotubes
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