The behaviour of graphite, carbon black, and Li4Ti5O12 in LiBOB-based electrolytes
The film formation behaviour of lithium bis(oxalato)borate (LiBOB), a new electrolyte salt for lithium batteries, on graphite, carbon black and lithium titanate is reported. LiBOB is actively involved in the formation of the solid electrolyte interphase (SEI) at the anode. Part of this formation is...
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| Veröffentlicht in: | Journal of applied electrochemistry 2006-11, Vol.36 (11), p.1199-1206 |
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| container_end_page | 1206 |
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| container_issue | 11 |
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| container_title | Journal of applied electrochemistry |
| container_volume | 36 |
| creator | WACHTLER, Mario WOHLFAHRT-MEHRENS, Margret STRÖBELE, Sandra PANITZ, Jan-Christoph WIETELMANN, Ulrich |
| description | The film formation behaviour of lithium bis(oxalato)borate (LiBOB), a new electrolyte salt for lithium batteries, on graphite, carbon black and lithium titanate is reported. LiBOB is actively involved in the formation of the solid electrolyte interphase (SEI) at the anode. Part of this formation is an irreversible reductive reaction which takes place at potentials of around 1.75 V vs Li/Li and contributes to the irreversible capacity of anode materials in the first cycle. Carbon black interacts strongly with LiBOB-based electrolytes, which results in strong film formation and loss of electronic conductivity within the composite electrode. In LiBOB-based electrolytes the electrode kinetics increase in the order: carbon black |
| doi_str_mv | 10.1007/s10800-006-9175-2 |
| format | Article |
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LiBOB is actively involved in the formation of the solid electrolyte interphase (SEI) at the anode. Part of this formation is an irreversible reductive reaction which takes place at potentials of around 1.75 V vs Li/Li and contributes to the irreversible capacity of anode materials in the first cycle. Carbon black interacts strongly with LiBOB-based electrolytes, which results in strong film formation and loss of electronic conductivity within the composite electrode. In LiBOB-based electrolytes the electrode kinetics increase in the order: carbon black</description><identifier>ISSN: 0021-891X</identifier><identifier>EISSN: 1572-8838</identifier><identifier>DOI: 10.1007/s10800-006-9175-2</identifier><identifier>CODEN: JAELBJ</identifier><language>eng</language><publisher>Heidelberg: Springer</publisher><subject>Applied sciences ; Direct energy conversion and energy accumulation ; Electrical engineering. 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LiBOB is actively involved in the formation of the solid electrolyte interphase (SEI) at the anode. Part of this formation is an irreversible reductive reaction which takes place at potentials of around 1.75 V vs Li/Li and contributes to the irreversible capacity of anode materials in the first cycle. Carbon black interacts strongly with LiBOB-based electrolytes, which results in strong film formation and loss of electronic conductivity within the composite electrode. In LiBOB-based electrolytes the electrode kinetics increase in the order: carbon black</description><subject>Applied sciences</subject><subject>Direct energy conversion and energy accumulation</subject><subject>Electrical engineering. 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| source | Springer Nature - Complete Springer Journals |
| subjects | Applied sciences Direct energy conversion and energy accumulation Electrical engineering. Electrical power engineering Electrical power engineering Electrochemical conversion: primary and secondary batteries, fuel cells Exact sciences and technology |
| title | The behaviour of graphite, carbon black, and Li4Ti5O12 in LiBOB-based electrolytes |
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