Collective Synthesis of Highly Oxygenated (Furano)germacranolides Derived from Elephantopus mollis and Elephantopus tomentosus

Germacranolides, secondary metabolites produced by plants, have garnered academic and industrial interest due to their diverse and complex topology as well as a wide array of pharmacological activities. Molephantin, a highly oxygenated germacranolide isolated from medicinal plants, Elephantopus moll...

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Veröffentlicht in:	Angewandte Chemie International Edition 2024-05, Vol.63 (19), p.e202402050-n/a
Hauptverfasser:	Patouret, Rémi, Cham, Ning, Chiba, Shunsuke
Format:	Artikel
Sprache:	eng
Schlagworte:	Aldehydes Allyl compounds Anticancer properties Asteraceae - chemistry Barbier allylation Chemical reactions Congeners Elephantopus mollis Elephantopus tomentosus Furans - chemical synthesis Furans - chemistry germacranolides Herbal medicine Inflammation Irradiation Isomerization Medicinal plants Metabolites Molecular Structure Nozaki–Hiyama–Kishi macrocyclization Optical activity Oxygen - chemistry Oxygenation photoinduced cycloisomerization Secondary metabolites Sesquiterpenes, Germacrane - chemical synthesis Sesquiterpenes, Germacrane - chemistry Stereoisomerism Stereoselectivity Synthesis Topology total synthesis Ultraviolet radiation
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