Thermal analysis (TG-DTA) and drift spectroscopy applied to investigate the evolution of humic acids in forest soil at different vegetation stages

Humic acids (HAs) extracted from soils developed under two Norwegian spruce (Picea abies, (L.) Karst) subalpine forests of northern Italy were characterized using chemical, thermal (TG-DTA) and spectroscopic (DRIFT) analyses. The samples were taken from five sites which differed in orientation (nort...

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Veröffentlicht in:Journal of Thermal Analysis and Calorimetry 2006-02, Vol.83 (2), p.393-399
Hauptverfasser: MONTECCHIO, D, FRANCIOSO, Ornella, CARLETTI, P, PIZZEGHELLO, D, CHERSICH, S, PREVITALI, F, NARDI, S
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container_end_page 399
container_issue 2
container_start_page 393
container_title Journal of Thermal Analysis and Calorimetry
container_volume 83
creator MONTECCHIO, D
FRANCIOSO, Ornella
CARLETTI, P
PIZZEGHELLO, D
CHERSICH, S
PREVITALI, F
NARDI, S
description Humic acids (HAs) extracted from soils developed under two Norwegian spruce (Picea abies, (L.) Karst) subalpine forests of northern Italy were characterized using chemical, thermal (TG-DTA) and spectroscopic (DRIFT) analyses. The samples were taken from five sites which differed in orientation (northern and southern exposure) and vegetal cover at different old age: grassland, regeneration, immature and mature stands. In general, the thermal patterns of HAs were similar (three exothermic reactions appeared around at 300, 400 and 500 deg C) in both sites in grasslands and regeneration while a considerable modification appeared in HA from stands of different age at northern and southern exposure site. DRIFT spectroscopy confirmed the differences observed through TG-DTA analysis. In particular the main structural changes were ascribed to modification of carbonyl group and of CH stretching in aliphatic components in each HAs from different sites.
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subjects Agronomy. Soil science and plant productions
Biological and medical sciences
Chemical, physicochemical, biochemical and biological properties
Fundamental and applied biological sciences. Psychology
Organic matter
Physics, chemistry, biochemistry and biology of agricultural and forest soils
Soil science
title Thermal analysis (TG-DTA) and drift spectroscopy applied to investigate the evolution of humic acids in forest soil at different vegetation stages
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