Biodegradability assessment of ozonated raw and biotreated pharmaceutical wastewater

The activated sludge specific oxygen uptake rate (SOUR) and BOD(5)/COD ratios of biologically pretreated pharmaceutical wastewater were analyzed and compared to assess relative changes in biotreatability during ozonation at a rate of 7.4 g/(L x h) for 4 h. An appreciable COD removal (41%) was achiev...

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Veröffentlicht in:Archives of environmental contamination and toxicology 2002-11, Vol.43 (4), p.425-431
Hauptverfasser: Arslan-Alaton, I, Akmehmet Balcioglu, I
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Akmehmet Balcioglu, I
description The activated sludge specific oxygen uptake rate (SOUR) and BOD(5)/COD ratios of biologically pretreated pharmaceutical wastewater were analyzed and compared to assess relative changes in biotreatability during ozonation at a rate of 7.4 g/(L x h) for 4 h. An appreciable COD removal (41%) was achieved by the initial biological treatment process, whereas ozonation was more effective in reducing the UV-sensitive aromatic compounds present in the pretreated effluent. Sequential treatment using activated sludge + ozonation processes resulted in an average COD removal efficiency of 48%, and a proceeding biotreatment stage increased the overall COD removal to 53%. An optimum ozone dose in the range of 1,854-3,708 mg/L corresponding to a specific ozone input rate of 0.23-0.46 mg O(3)/mg COD(o) existed where SOUR (3.7 x 10(-3) mg O(2)/[mg MLSS x min] for ozonation at pH 8) and BOD(5)/COD (0.57) as well as the proceeding biological COD removal yield Y(COD) (average 8 mg COD/mg MLSS) exerted maximum values.
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subjects Activated Sludge
Aromatic compounds
Biochemical oxygen demand
biodegradability
Biodegradation
Biodegradation, Environmental
Biological treatment
chemical oxygen demand
Drug Industry
Hydrogen-Ion Concentration
Industrial Waste
Medical wastes
Microorganisms
Oxidants, Photochemical - chemistry
oxygen
Oxygen - metabolism
Oxygen uptake
Ozonation
Ozone
Ozone - chemistry
Pharmaceutical industry wastes
Waste Disposal, Fluid - methods
wastewater
Wastewater treatment
Water pollution
Water treatment
title Biodegradability assessment of ozonated raw and biotreated pharmaceutical wastewater
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