The effects of chain length dependent propagation and termination on the kinetics of free-radical polymerization at low chain lengths

The kinetics of the free-radical polymerization of methyl methacrylate at 60 °C in the presence of large amounts of n-dodecanethiol (DDM) were investigated as a test at short chain lengths of our recently proposed composite termination model [Smith GB, Russell GT, Heuts JPA. Macromol Theory Simul 20...

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Veröffentlicht in:	European polymer journal 2005-02, Vol.41 (2), p.225-230
Hauptverfasser:	Smith, Gregory B., Russell, Gregory T., Yin, Ming, Heuts, Johan P.A.
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences Chain transfer Chain-length dependent propagation Chain-length dependent termination Exact sciences and technology Free-radical polymerization Kinetics Organic polymers Physicochemistry of polymers Polymerization Preparation, kinetics, thermodynamics, mechanism and catalysts
Online-Zugang:	Volltext
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