Synthesis and crystal structure of [CuCl(phen)2]3H3V10O28 · 7 H2O
The new compound, [CuCl(phen)2]3H3V10O28 · 7 H2O, was prepared by reaction of an aqueous KVO3 solution (pH 3) with an aqueous solution of CuSO4 · 5 H2O in which 1,10‐phenanthroline (phen) and KCl were added. The crystal structure of the compound was determined, and the proton position in H3V10O283–...
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| Veröffentlicht in: | Crystal research and technology (1979) 2005-07, Vol.40 (7), p.719-722 |
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| container_title | Crystal research and technology (1979) |
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| creator | Rakovský, E. Joniaková, D. Gyepes, R. Schwendt, P. Mička, Z. |
| description | The new compound, [CuCl(phen)2]3H3V10O28 · 7 H2O, was prepared by reaction of an aqueous KVO3 solution (pH 3) with an aqueous solution of CuSO4 · 5 H2O in which 1,10‐phenanthroline (phen) and KCl were added. The crystal structure of the compound was determined, and the proton position in H3V10O283– were calculated by the bond length/bond number method and also determined from difference electron density map. The protons are bound to colinearly arranged μ–OV2 and μ–OV3 groups which is the common protonation type in trihydrogen decavanadates. The structure crystallizes in P1 space group symmetry. (© 2005 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) |
| doi_str_mv | 10.1002/crat.200410415 |
| format | Article |
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The crystal structure of the compound was determined, and the proton position in H3V10O283– were calculated by the bond length/bond number method and also determined from difference electron density map. The protons are bound to colinearly arranged μ–OV2 and μ–OV3 groups which is the common protonation type in trihydrogen decavanadates. The structure crystallizes in P1 space group symmetry. (© 2005 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)</description><identifier>ISSN: 0232-1300</identifier><identifier>EISSN: 1521-4079</identifier><identifier>DOI: 10.1002/crat.200410415</identifier><language>eng</language><publisher>Berlin: WILEY-VCH Verlag</publisher><subject>bond-length/bond-number calculation ; heptahydrate ; structure analysis ; trihydrogendecavanadate ; X-ray diffraction</subject><ispartof>Crystal research and technology (1979), 2005-07, Vol.40 (7), p.719-722</ispartof><rights>Copyright © 2005 WILEY‐VCH Verlag GmbH & Co. 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| ispartof | Crystal research and technology (1979), 2005-07, Vol.40 (7), p.719-722 |
| issn | 0232-1300 1521-4079 |
| language | eng |
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| source | Wiley Journals |
| subjects | bond-length/bond-number calculation heptahydrate structure analysis trihydrogendecavanadate X-ray diffraction |
| title | Synthesis and crystal structure of [CuCl(phen)2]3H3V10O28 · 7 H2O |
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