Oxidative addition of different electrophiles with rhodium(I) carbonyl complexes of unsymmetrical phosphine-phosphine monoselenide ligands

Dimeric chlorobridge complex [Rh(CO)2Cl]2 reacts with two equivalents of a series of unsymmetrical phosphine–phosphine monoselenide ligands, Ph2P(CH2)nP(Se)Ph2 {n = 1(a), 2(b), 3(c), 4(d)}to form chelate complex [Rh(CO)Cl(P∩Se)] (1a) {P∩Se = η2‐(P,Se) coordinated} and non‐chelate complexes [Rh(CO)2C...

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