Metal-free β,γ-C(sp)-H difunctionalization of propanols: DMP-initiated asymmetric spirocyclopropanation

A DMP-initiated metal-free effective β,γ-asymmetric spirocyclopropanation of propanols strategy using oxidative iminium activation is described. This process has been realized by a synergistic amine-catalyzed one-pot cascade oxidation-Michael addition cyclopropanation for "one-pot" access...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2024-03, Vol.6 (26), p.3579-3582
Hauptverfasser:	Li, Zheyao, Zhang, Huiwen, Zhao, Lin, Ma, Yueyue, Wu, Qiufang, Ren, Haosong, Lin, Zhongren, Zheng, Jun, Yu, Xinhong
Format:	Artikel
Sprache:	eng
Schlagworte:	Asymmetry Bromination Enantiomers Oxidation
Online-Zugang:	Volltext
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