SiC-4H Epitaxial Layer Growth Using Trichlorosilane (TCS) as Silicon Precursor

4H-SiC epitaxial layers have been grown using trichlorosilane (TCS) as the silicon precursor source together with ethylene as the carbon precursor source. A higher C/Si ratio is necessary compared with the silane/ethylene system. This ratio has to be reduced especially at higher Si/H2 ratio because...

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Veröffentlicht in:Materials science forum 2006-10, Vol.527-529, p.179-182
Hauptverfasser: Crippa, Danilo, Pistone, Giuseppe, Portuese, F., La Via, Francesco, Abbondanza, Giuseppe, Foti, Gaetano, Valente, Gian Luca, Reitano, Ricardo, Barbera, Milo, Mauceri, Marco, Abagnale, Giovanni, Leone, Stefano
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container_title Materials science forum
container_volume 527-529
creator Crippa, Danilo
Pistone, Giuseppe
Portuese, F.
La Via, Francesco
Abbondanza, Giuseppe
Foti, Gaetano
Valente, Gian Luca
Reitano, Ricardo
Barbera, Milo
Mauceri, Marco
Abagnale, Giovanni
Leone, Stefano
description 4H-SiC epitaxial layers have been grown using trichlorosilane (TCS) as the silicon precursor source together with ethylene as the carbon precursor source. A higher C/Si ratio is necessary compared with the silane/ethylene system. This ratio has to be reduced especially at higher Si/H2 ratio because the step-bunching effect occurs. From the comparison with the process that uses silane as the silicon precursor, a 15% higher growth rate has been found using TCS (trichlorosilane) at the same Si/H2 ratio. Furthermore, in the TCS process, the presence of chlorine, that reduces the possibility of silicon droplet formation, allows to use a high Si/H2 ratio and then to reach high growth rates (16 *m/h). The obtained results on the growth rates, the surface roughness and the crystal quality are very promising.
doi_str_mv 10.4028/www.scientific.net/MSF.527-529.179
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