Fe2+-NTA synergized UV254 photolytic defluorination of perfluorooctane sulfonate (PFOS): Enhancing through intramolecular electron density perturbation via electron acquisition

•Fe2+-NTA synergized PFOS defluorination under UV254 irradiation at near-neutral pH.•PFOS-Fe2+-NTA becomes more vulnerable with lower transition energy than PFOS anion.•Photo induced electron transfer to PFOS occurred via Fe2+ bridged MLCT process.•Marked electron density perturbation was revealed i...

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Veröffentlicht in:Water research (Oxford) 2024-05, Vol.254, p.121421-121421, Article 121421
Hauptverfasser: Chen, Yihua, Zhu, Jiaxin, Ma, Hang, Gu, Yurong, Liu, Tongzhou
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Sprache:eng
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