Stabilization and isomerization of radical cations generated by fast electron irradiation of unsaturated organic molecules in a solid argon matrix
Matrix isolation EPR spectroscopy was used to study the fate of “hot” unsaturated radical cations produced by fast electron irradiation in solid argon. It was found that the radical cations of cis-2-butene, trans-2-butene and ethyl vinyl ether resulting from highly exothermic hole transfer (excess e...
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| Veröffentlicht in: | Radiation physics and chemistry (Oxford, England : 1993) England : 1993), 2006, Vol.75 (1), p.106-114 |
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| container_title | Radiation physics and chemistry (Oxford, England : 1993) |
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| creator | Feldman, V.I. Sukhov, F.F. Orlov, A.Yu Tyulpina, I.V. Ivanchenko, V.K. |
| description | Matrix isolation EPR spectroscopy was used to study the fate of “hot” unsaturated radical cations produced by fast electron irradiation in solid argon. It was found that the radical cations of
cis-2-butene,
trans-2-butene and ethyl vinyl ether resulting from highly exothermic hole transfer (excess energy>6
eV) underwent effective relaxation in an argon matrix. 1-Butene radical cation exhibits isomerization to
cis-2-butene radical cation. The role of molecular structure of organic radical cations in excess energy relaxation is discussed. |
| doi_str_mv | 10.1016/j.radphyschem.2005.03.012 |
| format | Article |
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cis-2-butene,
trans-2-butene and ethyl vinyl ether resulting from highly exothermic hole transfer (excess energy>6
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cis-2-butene,
trans-2-butene and ethyl vinyl ether resulting from highly exothermic hole transfer (excess energy>6
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cis-2-butene radical cation. The role of molecular structure of organic radical cations in excess energy relaxation is discussed.</description><subject>EPR</subject><subject>Excess energy</subject><subject>Matrix isolation</subject><subject>Radical cations</subject><subject>Unsaturated compounds</subject><issn>0969-806X</issn><issn>1879-0895</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2006</creationdate><recordtype>article</recordtype><recordid>eNqNkcFu2zAMhoVhBZZlfQf10ptdSrYc-1gE3VqgQA_tgN4EWqYTBbaVSnKx7DH6xFOWbdixJxLE9_8E-TN2ISAXIKqrXe6x228PwWxpzCWAyqHIQcgPbCHqVZNB3aiPbAFN1WQ1VM-f2OcQdgCwqlWxYG-PEVs72J8YrZs4Th23wY3k_05cz9MGa3Dg5vck8A1N5DFSx9sD7zFETgOZ6BNt_RH-p5yngHE-sc5vcLKGjy7B80CB27SPBzfYjqPfJMWI0dsfX9hZj0Og8z91yb5_vXla32b3D9_u1tf3mSmUjFmnyh6atlVSyroszcqUUhhZF6Upyl4K0UoDSpVYKaRetaqgFqDEHqsudapYssuT7967l5lC1KMNhoYBJ3Jz0LJRSqxkk8DmBBrvQvDU6723I_qDFqCPKeid_i8FfUxBQ6FTCkm7PmkpXfJqyetgLE2GOuvTz3Tn7DtcfgHVIptc</recordid><startdate>2006</startdate><enddate>2006</enddate><creator>Feldman, V.I.</creator><creator>Sukhov, F.F.</creator><creator>Orlov, A.Yu</creator><creator>Tyulpina, I.V.</creator><creator>Ivanchenko, V.K.</creator><general>Elsevier Ltd</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>2006</creationdate><title>Stabilization and isomerization of radical cations generated by fast electron irradiation of unsaturated organic molecules in a solid argon matrix</title><author>Feldman, V.I. ; Sukhov, F.F. ; Orlov, A.Yu ; Tyulpina, I.V. ; Ivanchenko, V.K.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c352t-d54f09bb5222844c7c421c2834c34f211b2c0554a65aef5b53eb004afa6deb053</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2006</creationdate><topic>EPR</topic><topic>Excess energy</topic><topic>Matrix isolation</topic><topic>Radical cations</topic><topic>Unsaturated compounds</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Feldman, V.I.</creatorcontrib><creatorcontrib>Sukhov, F.F.</creatorcontrib><creatorcontrib>Orlov, A.Yu</creatorcontrib><creatorcontrib>Tyulpina, I.V.</creatorcontrib><creatorcontrib>Ivanchenko, V.K.</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Radiation physics and chemistry (Oxford, England : 1993)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Feldman, V.I.</au><au>Sukhov, F.F.</au><au>Orlov, A.Yu</au><au>Tyulpina, I.V.</au><au>Ivanchenko, V.K.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Stabilization and isomerization of radical cations generated by fast electron irradiation of unsaturated organic molecules in a solid argon matrix</atitle><jtitle>Radiation physics and chemistry (Oxford, England : 1993)</jtitle><date>2006</date><risdate>2006</risdate><volume>75</volume><issue>1</issue><spage>106</spage><epage>114</epage><pages>106-114</pages><issn>0969-806X</issn><eissn>1879-0895</eissn><abstract>Matrix isolation EPR spectroscopy was used to study the fate of “hot” unsaturated radical cations produced by fast electron irradiation in solid argon. It was found that the radical cations of
cis-2-butene,
trans-2-butene and ethyl vinyl ether resulting from highly exothermic hole transfer (excess energy>6
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| ispartof | Radiation physics and chemistry (Oxford, England : 1993), 2006, Vol.75 (1), p.106-114 |
| issn | 0969-806X 1879-0895 |
| language | eng |
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| source | Elsevier ScienceDirect Journals Complete - AutoHoldings |
| subjects | EPR Excess energy Matrix isolation Radical cations Unsaturated compounds |
| title | Stabilization and isomerization of radical cations generated by fast electron irradiation of unsaturated organic molecules in a solid argon matrix |
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