Recent Advances in Redox-Based Z‑Scheme Overall Water Splitting under Visible Light Irradiation

Photocatalytic overall water splitting (OWS) using suspended particulate photocatalysts to produce green hydrogen has inspired continuous interest due to its low cost for easy large-scale application. The two-step photoexcitation system (Z-scheme) mimicking natural photosynthesis was proposed to efficiently use visible light for realization of efficient conversion of solar irradiation. In this Perspective, we will introduce recent advances in redox-based Z-scheme OWS systems, including iodine-based, iron-based, metal complex-based, and other special ion redox couples. The advantages and challenges of each couple and the factors affecting the Z-scheme OWS efficiency are discussed in detail. Finally, the challenges and feasible solutions for the achievement of highly efficient Z-scheme OWS are then outlined. This Perspective provides guidance on how to construct a Z-scheme OWS system and enhance photocatalytic performance.