Electrical impedance spectroscopy of epoxy systems: The case of 1,4-butanediol diglycidyl ether/ cis-1,2-cyclohexanedicarboxylic anhydride and triethylamine as initiator
A series of epoxy cured samples, with different molar composition of 1,4-butanediol diglycidyl ether (EP), cis-1,2-cyclohexanedicarboxylic anhydride (CH) and triethylamine (TEA) as initiator, was studied by Electrical Impedance Spectroscopy (EIS) in the frequency range 10 −2–10 5 Hz. The resistivity...
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| Veröffentlicht in: | European polymer journal 2006, Vol.42 (1), p.195-202 |
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| container_title | European polymer journal |
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| creator | Nucci, Ana M. Nicolau, Aline Martini, Emilse M.A. Samios, Dimitrios |
| description | A series of epoxy cured samples, with different molar composition of 1,4-butanediol diglycidyl ether (EP),
cis-1,2-cyclohexanedicarboxylic anhydride (CH) and triethylamine (TEA) as initiator, was studied by Electrical Impedance Spectroscopy (EIS) in the frequency range 10
−2–10
5
Hz. The resistivity of the system was evaluated by using the complex impedance analysis method. Resistivity values in the range between 10
7 and 10
13
Ω
cm were obtained and related to the composition (molar fraction
x
EP or
x
CH) of the epoxy system. The gel formation characteristics of the samples were obtained as theoretically described by Flory. |
| doi_str_mv | 10.1016/j.eurpolymj.2005.05.016 |
| format | Article |
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cis-1,2-cyclohexanedicarboxylic anhydride (CH) and triethylamine (TEA) as initiator, was studied by Electrical Impedance Spectroscopy (EIS) in the frequency range 10
−2–10
5
Hz. The resistivity of the system was evaluated by using the complex impedance analysis method. Resistivity values in the range between 10
7 and 10
13
Ω
cm were obtained and related to the composition (molar fraction
x
EP or
x
CH) of the epoxy system. The gel formation characteristics of the samples were obtained as theoretically described by Flory.</description><identifier>ISSN: 0014-3057</identifier><identifier>EISSN: 1873-1945</identifier><identifier>DOI: 10.1016/j.eurpolymj.2005.05.016</identifier><identifier>CODEN: EUPJAG</identifier><language>eng</language><publisher>Oxford: Elsevier Ltd</publisher><subject>Applied sciences ; Chemical properties ; Electrical impedance spectroscopy ; Epoxy systems ; Exact sciences and technology ; Molar fraction variation ; Polymer industry, paints, wood ; Properties and testing ; Technology of polymers</subject><ispartof>European polymer journal, 2006, Vol.42 (1), p.195-202</ispartof><rights>2005 Elsevier Ltd</rights><rights>2006 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c376t-abfdbed633fb4bbae7efc3e8f3eed5ed921b950ce8abc389b32809e7d61090a53</citedby><cites>FETCH-LOGICAL-c376t-abfdbed633fb4bbae7efc3e8f3eed5ed921b950ce8abc389b32809e7d61090a53</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0014305705002168$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,4010,27900,27901,27902,65306</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=17410907$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Nucci, Ana M.</creatorcontrib><creatorcontrib>Nicolau, Aline</creatorcontrib><creatorcontrib>Martini, Emilse M.A.</creatorcontrib><creatorcontrib>Samios, Dimitrios</creatorcontrib><title>Electrical impedance spectroscopy of epoxy systems: The case of 1,4-butanediol diglycidyl ether/ cis-1,2-cyclohexanedicarboxylic anhydride and triethylamine as initiator</title><title>European polymer journal</title><description>A series of epoxy cured samples, with different molar composition of 1,4-butanediol diglycidyl ether (EP),
cis-1,2-cyclohexanedicarboxylic anhydride (CH) and triethylamine (TEA) as initiator, was studied by Electrical Impedance Spectroscopy (EIS) in the frequency range 10
−2–10
5
Hz. The resistivity of the system was evaluated by using the complex impedance analysis method. Resistivity values in the range between 10
7 and 10
13
Ω
cm were obtained and related to the composition (molar fraction
x
EP or
x
CH) of the epoxy system. The gel formation characteristics of the samples were obtained as theoretically described by Flory.</description><subject>Applied sciences</subject><subject>Chemical properties</subject><subject>Electrical impedance spectroscopy</subject><subject>Epoxy systems</subject><subject>Exact sciences and technology</subject><subject>Molar fraction variation</subject><subject>Polymer industry, paints, wood</subject><subject>Properties and testing</subject><subject>Technology of polymers</subject><issn>0014-3057</issn><issn>1873-1945</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2006</creationdate><recordtype>article</recordtype><recordid>eNqFUU1v1DAQtRBILIXfgC9warZ2nMQJt6oqUKkSl3K2_DFhZ-XEwc6i-ifxL3HYCo6VRrI1fm_m-T1C3nO254x3V8c9nOISfJ6O-5qxdr8V716QHe-lqPjQtC_JjjHeVIK18jV5k9KRMSZFJ3bk960Hu0a02lOcFnB6tkDTsjVDsmHJNIwUlvCYacpphSl9og8HoFYn2J74ZVOZ06pncBg8dfjDZ4suewrrAeIVtZgqfllXNlsfDvD4F2l1NGWkR0v1fMguooNyc7RIKbzs9YRz6SSKM66o1xDfklej9gnePZ0X5Pvn24ebr9X9ty93N9f3lRWyWyttRmfAdUKMpjFGg4TRCuhHAeBacEPNzdAyC702VvSDEXXPBpCu42xguhUX5ON57hLDzxOkVU2YLHhfhIdTUvXQCtk2fQHKM9AWp1KEUS0RJx2z4kxt0aij-heN2qJRW_GuMD88rdCpGD_GYjqm_3TZbFpkwV2fcVD--wshqmQRSkAOYwlIuYDP7voD9AGvTQ</recordid><startdate>2006</startdate><enddate>2006</enddate><creator>Nucci, Ana M.</creator><creator>Nicolau, Aline</creator><creator>Martini, Emilse M.A.</creator><creator>Samios, Dimitrios</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>2006</creationdate><title>Electrical impedance spectroscopy of epoxy systems: The case of 1,4-butanediol diglycidyl ether/ cis-1,2-cyclohexanedicarboxylic anhydride and triethylamine as initiator</title><author>Nucci, Ana M. ; Nicolau, Aline ; Martini, Emilse M.A. ; Samios, Dimitrios</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c376t-abfdbed633fb4bbae7efc3e8f3eed5ed921b950ce8abc389b32809e7d61090a53</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2006</creationdate><topic>Applied sciences</topic><topic>Chemical properties</topic><topic>Electrical impedance spectroscopy</topic><topic>Epoxy systems</topic><topic>Exact sciences and technology</topic><topic>Molar fraction variation</topic><topic>Polymer industry, paints, wood</topic><topic>Properties and testing</topic><topic>Technology of polymers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Nucci, Ana M.</creatorcontrib><creatorcontrib>Nicolau, Aline</creatorcontrib><creatorcontrib>Martini, Emilse M.A.</creatorcontrib><creatorcontrib>Samios, Dimitrios</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>European polymer journal</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Nucci, Ana M.</au><au>Nicolau, Aline</au><au>Martini, Emilse M.A.</au><au>Samios, Dimitrios</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Electrical impedance spectroscopy of epoxy systems: The case of 1,4-butanediol diglycidyl ether/ cis-1,2-cyclohexanedicarboxylic anhydride and triethylamine as initiator</atitle><jtitle>European polymer journal</jtitle><date>2006</date><risdate>2006</risdate><volume>42</volume><issue>1</issue><spage>195</spage><epage>202</epage><pages>195-202</pages><issn>0014-3057</issn><eissn>1873-1945</eissn><coden>EUPJAG</coden><abstract>A series of epoxy cured samples, with different molar composition of 1,4-butanediol diglycidyl ether (EP),
cis-1,2-cyclohexanedicarboxylic anhydride (CH) and triethylamine (TEA) as initiator, was studied by Electrical Impedance Spectroscopy (EIS) in the frequency range 10
−2–10
5
Hz. The resistivity of the system was evaluated by using the complex impedance analysis method. Resistivity values in the range between 10
7 and 10
13
Ω
cm were obtained and related to the composition (molar fraction
x
EP or
x
CH) of the epoxy system. The gel formation characteristics of the samples were obtained as theoretically described by Flory.</abstract><cop>Oxford</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.eurpolymj.2005.05.016</doi><tpages>8</tpages></addata></record> |
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| ispartof | European polymer journal, 2006, Vol.42 (1), p.195-202 |
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| language | eng |
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| source | Elsevier ScienceDirect Journals |
| subjects | Applied sciences Chemical properties Electrical impedance spectroscopy Epoxy systems Exact sciences and technology Molar fraction variation Polymer industry, paints, wood Properties and testing Technology of polymers |
| title | Electrical impedance spectroscopy of epoxy systems: The case of 1,4-butanediol diglycidyl ether/ cis-1,2-cyclohexanedicarboxylic anhydride and triethylamine as initiator |
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