Electrosynthesis of nitroso compounds from (1S, 2S)-2-amino-l-(4-nitrophenyl)-propane-1,3-diol derivatives

Electrosynthesis of nitroso compounds from (1S, 2S)-2-amino-l-(4-nitrophenyl)-propane-1,3-diol derivatives

Nitroso compounds were electrogenerated from (1S, 2S)-2-amino-1-(4-nitrophenyl)-propane-1,3-diol derivatives (derivatives of p-nitrophenylserinol) in a 'redox' flow cell equipped with two consecutive porous electrodes of opposite polarities. In spite. of the relative instability in methano...

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Veröffentlicht in:Journal of applied electrochemistry 2005-09, Vol.35 (9), p.851-855
Hauptverfasser: Cristea, C. V., Moinet, C., Jitaru, M., Popescu, I. C.
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container_title Journal of applied electrochemistry
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creator Cristea, C. V.
Moinet, C.
Jitaru, M.
Popescu, I. C.
description Nitroso compounds were electrogenerated from (1S, 2S)-2-amino-1-(4-nitrophenyl)-propane-1,3-diol derivatives (derivatives of p-nitrophenylserinol) in a 'redox' flow cell equipped with two consecutive porous electrodes of opposite polarities. In spite. of the relative instability in methanol-acetate buffer of the hydroxylamine intermediates produced at the first porous electrode (cathode), the nitroso derivatives were prepared in good yields at the second one (anode). A coupling reaction between some nitroso derivatives and p-toluenesulphinic acid led to N-sulphonylphenylhydroxylamines.
doi_str_mv 10.1007/s10800-005-1320-9
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title Electrosynthesis of nitroso compounds from (1S, 2S)-2-amino-l-(4-nitrophenyl)-propane-1,3-diol derivatives
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