Comparison of CNF and XC-72 carbon supported palladium electrocatalysts for magnesium air fuel cell
Palladium catalysts supported on carbon nanofibers (CNFs) and XC-72 carbon were developed by chemically reducing palladium chloride with ethylene glycol. The morphologies and crystal structure of the Pd/CNF catalyst and Pd/XC-72 catalyst were investigated by TEM and XRD, respectively. The electrocat...
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| Veröffentlicht in: | Carbon (New York) 2007-02, Vol.45 (2), p.397-401 |
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| creator | Yang, Weiqian Yang, Shaohua Guo, Junsong Sun, Gongquan Xin, Qin |
| description | Palladium catalysts supported on carbon nanofibers (CNFs) and XC-72 carbon were developed by chemically reducing palladium chloride with ethylene glycol. The morphologies and crystal structure of the Pd/CNF catalyst and Pd/XC-72 catalyst were investigated by TEM and XRD, respectively. The electrocatalytical activity of the catalysts was examined via cyclic voltammetry testing techniques. The performance of the air electrodes was examined by linear polarization methods. Magnesium air fuel cells with Pd/CNF catalyst and Pd/XC-72 catalyst were fabricated and characterized. The results showed that the Pd/CNF catalyst had higher catalytic activity for the oxygen reduction reaction and achieved better performance of the magnesium air fuel cell compared with the Pd/XC-72 catalyst. |
| doi_str_mv | 10.1016/j.carbon.2006.09.003 |
| format | Article |
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The morphologies and crystal structure of the Pd/CNF catalyst and Pd/XC-72 catalyst were investigated by TEM and XRD, respectively. The electrocatalytical activity of the catalysts was examined via cyclic voltammetry testing techniques. The performance of the air electrodes was examined by linear polarization methods. Magnesium air fuel cells with Pd/CNF catalyst and Pd/XC-72 catalyst were fabricated and characterized. The results showed that the Pd/CNF catalyst had higher catalytic activity for the oxygen reduction reaction and achieved better performance of the magnesium air fuel cell compared with the Pd/XC-72 catalyst.</description><identifier>ISSN: 0008-6223</identifier><identifier>EISSN: 1873-3891</identifier><identifier>DOI: 10.1016/j.carbon.2006.09.003</identifier><identifier>CODEN: CRBNAH</identifier><language>eng</language><publisher>Oxford: Elsevier Ltd</publisher><subject>Applied sciences ; Chemistry ; Cross-disciplinary physics: materials science; rheology ; Electrochemistry ; Energy ; Energy. 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Thermal use of fuels</subject><subject>Equipments for energy generation and conversion: thermal, electrical, mechanical energy, etc</subject><subject>Exact sciences and technology</subject><subject>Fuel cells</subject><subject>Fullerenes and related materials; diamonds, graphite</subject><subject>General and physical chemistry</subject><subject>Kinetics and mechanism of reactions</subject><subject>Materials science</subject><subject>Physics</subject><subject>Specific materials</subject><issn>0008-6223</issn><issn>1873-3891</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2007</creationdate><recordtype>article</recordtype><recordid>eNp9kMGL1TAQxoMo-Fz9Dzzkord2M0lfm1wEKa4uLHpR8Bam6UTySJuatML-9_bRBW-ehmG--Wa-H2NvQdQgoL291A7zkOZaCtHWwtRCqGfsBLpTldIGnrOTEEJXrZTqJXtVymVvGw3Nibk-TQvmUNLMk-f91zuO88h_9lUn-eHKy7YsKa808gVjxDFsE6dIbs3J4YrxsayF-5T5hL9mKtcxhsz9RpE7ivE1e-ExFnrzVG_Yj7tP3_sv1cO3z_f9x4fKNUKv1eAkQTMAdd1IqEFriTR2gzQITgwexhbO3RmcJwWm1dL4Vp2VMgAgGkB1w94fvktOvzcqq51CuT6AM6WtWGnOwkjZ7cLmELqcSsnk7ZLDhPnRgrBXovZij-z2StQKY3ei-9q7J38sDqPPOLtQ_u3qpjM78l334dDRHvZPoGyLCzQ7GkPeqdkxhf8f-gt0443N</recordid><startdate>20070201</startdate><enddate>20070201</enddate><creator>Yang, Weiqian</creator><creator>Yang, Shaohua</creator><creator>Guo, Junsong</creator><creator>Sun, Gongquan</creator><creator>Xin, Qin</creator><general>Elsevier Ltd</general><general>Elsevier Science</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20070201</creationdate><title>Comparison of CNF and XC-72 carbon supported palladium electrocatalysts for magnesium air fuel cell</title><author>Yang, Weiqian ; Yang, Shaohua ; Guo, Junsong ; Sun, Gongquan ; Xin, Qin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c408t-bc2e14b1e77dea81882aed7b29a1c0bf1d615751cfe3196829f635339111041a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2007</creationdate><topic>Applied sciences</topic><topic>Chemistry</topic><topic>Cross-disciplinary physics: materials science; rheology</topic><topic>Electrochemistry</topic><topic>Energy</topic><topic>Energy. Thermal use of fuels</topic><topic>Equipments for energy generation and conversion: thermal, electrical, mechanical energy, etc</topic><topic>Exact sciences and technology</topic><topic>Fuel cells</topic><topic>Fullerenes and related materials; diamonds, graphite</topic><topic>General and physical chemistry</topic><topic>Kinetics and mechanism of reactions</topic><topic>Materials science</topic><topic>Physics</topic><topic>Specific materials</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yang, Weiqian</creatorcontrib><creatorcontrib>Yang, Shaohua</creatorcontrib><creatorcontrib>Guo, Junsong</creatorcontrib><creatorcontrib>Sun, Gongquan</creatorcontrib><creatorcontrib>Xin, Qin</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Carbon (New York)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yang, Weiqian</au><au>Yang, Shaohua</au><au>Guo, Junsong</au><au>Sun, Gongquan</au><au>Xin, Qin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Comparison of CNF and XC-72 carbon supported palladium electrocatalysts for magnesium air fuel cell</atitle><jtitle>Carbon (New York)</jtitle><date>2007-02-01</date><risdate>2007</risdate><volume>45</volume><issue>2</issue><spage>397</spage><epage>401</epage><pages>397-401</pages><issn>0008-6223</issn><eissn>1873-3891</eissn><coden>CRBNAH</coden><abstract>Palladium catalysts supported on carbon nanofibers (CNFs) and XC-72 carbon were developed by chemically reducing palladium chloride with ethylene glycol. The morphologies and crystal structure of the Pd/CNF catalyst and Pd/XC-72 catalyst were investigated by TEM and XRD, respectively. The electrocatalytical activity of the catalysts was examined via cyclic voltammetry testing techniques. The performance of the air electrodes was examined by linear polarization methods. Magnesium air fuel cells with Pd/CNF catalyst and Pd/XC-72 catalyst were fabricated and characterized. The results showed that the Pd/CNF catalyst had higher catalytic activity for the oxygen reduction reaction and achieved better performance of the magnesium air fuel cell compared with the Pd/XC-72 catalyst.</abstract><cop>Oxford</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.carbon.2006.09.003</doi><tpages>5</tpages></addata></record> |
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| source | Elsevier ScienceDirect Journals Complete |
| subjects | Applied sciences Chemistry Cross-disciplinary physics: materials science rheology Electrochemistry Energy Energy. Thermal use of fuels Equipments for energy generation and conversion: thermal, electrical, mechanical energy, etc Exact sciences and technology Fuel cells Fullerenes and related materials diamonds, graphite General and physical chemistry Kinetics and mechanism of reactions Materials science Physics Specific materials |
| title | Comparison of CNF and XC-72 carbon supported palladium electrocatalysts for magnesium air fuel cell |
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