Growth of highly oriented graphite films at room temperature by pulsed laser deposition using carbon–sulfur targets

Carbon–sulfur films were grown by pulsed laser deposition at room temperature using different graphite–sulfur mixtures as targets. The structure of the films was characterized by X-ray diffraction and transmission electron microscopy. The composition and the chemical bonds were analyzed by Rutherfor...

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Veröffentlicht in:Carbon (New York) 2006-11, Vol.44 (14), p.3064-3072
Hauptverfasser: Semmelhack, H.C., Höhne, R., Esquinazi, P., Wagner, G., Rahm, A., Hallmeier, K.H., Spemann, D., Schindler, K.
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container_end_page 3072
container_issue 14
container_start_page 3064
container_title Carbon (New York)
container_volume 44
creator Semmelhack, H.C.
Höhne, R.
Esquinazi, P.
Wagner, G.
Rahm, A.
Hallmeier, K.H.
Spemann, D.
Schindler, K.
description Carbon–sulfur films were grown by pulsed laser deposition at room temperature using different graphite–sulfur mixtures as targets. The structure of the films was characterized by X-ray diffraction and transmission electron microscopy. The composition and the chemical bonds were analyzed by Rutherford-backscattering spectroscopy, X-ray photoelectron spectroscopy and energy dispersive X-ray analysis. The films were composed of amorphous carbon with sp 2-, sp 3- and S–C–C–S bonds and textured graphite on the top of the film. The thin graphite layer on top of the carbon–sulfur films is highly oriented, comparable to highly oriented pyrolytic graphite, and free of sulfur in the graphite lattice. The lateral size of the oriented graphite grains in the films was up to 8 μm. Magnetic measurements reveal that the films prepared under the conditions of our study show neither magnetic ordering nor superconductivity in the studied temperature range T > 2 K.
doi_str_mv 10.1016/j.carbon.2006.05.004
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subjects Cross-disciplinary physics: materials science
rheology
Crystallite size
Exact sciences and technology
Fullerenes and related materials
diamonds, graphite
Graphitization
Highly oriented graphite
Magnetic properties
Materials science
Physics
Specific materials
X-ray diffraction
title Growth of highly oriented graphite films at room temperature by pulsed laser deposition using carbon–sulfur targets
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