Controlled radical polymerization of acrylates by γ -irradiation in the presence of 1,1-diphenylethene

Controlled radical polymerization of acrylates by γ -irradiation in the presence of 1,1-diphenylethene

Poly (butyl acrylate) and poly (methyl acrylate) were successfully prepared in the presence of 1,1-diphenylethene (DPE) by γ -irradiation-induced polymerization in both bulk and solution. The influences of polymerization time, amounts of DPE in system on conversion, molecular weight (MW) and its dis...

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Veröffentlicht in:Radiation physics and chemistry (Oxford, England : 1993) England : 1993), 2005-12, Vol.74 (5), p.331-337
Hauptverfasser: Wu, Zongtao, Zhang, Zhicheng
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Sprache:eng
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1,1-diphenylethene
[formula omitted]-irradiation
Acrylates
Controlled radical polymerization
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container_title Radiation physics and chemistry (Oxford, England : 1993)
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creator Wu, Zongtao
Zhang, Zhicheng
description Poly (butyl acrylate) and poly (methyl acrylate) were successfully prepared in the presence of 1,1-diphenylethene (DPE) by γ -irradiation-induced polymerization in both bulk and solution. The influences of polymerization time, amounts of DPE in system on conversion, molecular weight (MW) and its distribution ( M w/ M n) were studied. The results indicate that the polymerization initiated by γ -irradiation in the presence of DPE shows the character of living radical reaction.
doi_str_mv 10.1016/j.radphyschem.2004.09.023
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subjects 1,1-diphenylethene
[formula omitted]-irradiation
Acrylates
Controlled radical polymerization
title Controlled radical polymerization of acrylates by γ -irradiation in the presence of 1,1-diphenylethene
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