Ozone Generation by a TaO[sub x] and Pt Composite Insulator-Coated Ti Electrode

The characteristics of a new-type of ozone-generating electrode with a catalyst layer fabricated by thermal decomposition were investigated. The catalyst layer consisted of insulating tantalum oxide and metallic platinum. Ozone generation was observed when the concentration of Ta of the catalyst lay...

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Veröffentlicht in:Electrochemical and solid-state letters 2005, Vol.8 (6), p.J13-J16
Hauptverfasser: Kaneda, Kazuhiro, Ikematsu, Mineo, Koizumi, Yurika, Minoshima, Haruki, Rakuma, Tsuyoshi, Takaoka, Daizo, Yasuda, Masashi
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container_end_page J16
container_issue 6
container_start_page J13
container_title Electrochemical and solid-state letters
container_volume 8
creator Kaneda, Kazuhiro
Ikematsu, Mineo
Koizumi, Yurika
Minoshima, Haruki
Rakuma, Tsuyoshi
Takaoka, Daizo
Yasuda, Masashi
description The characteristics of a new-type of ozone-generating electrode with a catalyst layer fabricated by thermal decomposition were investigated. The catalyst layer consisted of insulating tantalum oxide and metallic platinum. Ozone generation was observed when the concentration of Ta of the catalyst layer was 70% and above and the maximum current efficiency of ozone generation was 6%. Scanning electron microscopy revealed cracks, which were capable of ozone generation, reaching the Pt buffered layer of the electrode. It is concluded that the cracks were the paths of the electrolyte and that electronic transfer was accomplished on the surface of the buffered layer.
doi_str_mv 10.1149/1.1904467
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title Ozone Generation by a TaO[sub x] and Pt Composite Insulator-Coated Ti Electrode
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