Inorganic–organic hybrid structures: Synthesis, structure and magnetic properties of a new iron oxalatoarsenate, [NH 3(CH 2)CH(NH 3)CH 3] 3[Fe 6(AsO 4) 2(HAsO 4) 6(C 2O 4) 3]
A hydrothermal reaction of a mixture of iron oxalate, arsenic acid, 1,2-diaminopropane and water at 150 °C gave rise to a new three-dimensional iron oxalatoarsenate, [NH 3(CH 2)CH(NH 3)CH 3] 3[Fe 6(AsO 4) 2(HAsO 4) 6(C 2O 4) 3], I. Crystal data: hexagonal, space group = P-3c1, a = 13.9899 ( 12 ) , c...
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| Veröffentlicht in: | Solid state sciences 2006-06, Vol.8 (6), p.692-697 |
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| creator | Rao, Vandavasi Koteswara Kam, Kinson C. Cheetham, Anthony K. Natarajan, Srinivasan |
| description | A hydrothermal reaction of a mixture of iron oxalate, arsenic acid, 1,2-diaminopropane and water at 150 °C gave rise to a new three-dimensional iron oxalatoarsenate, [NH
3(CH
2)CH(NH
3)CH
3]
3[Fe
6(AsO
4)
2(HAsO
4)
6(C
2O
4)
3],
I. Crystal data: hexagonal, space group
=
P-3c1,
a
=
13.9899
(
12
)
,
c
=
14.936
(
3
)
Å
,
V
=
2531.6
(
5
)
Å
3
. The structure consists of layers of vertex-sharing FeO
6 octahedral and AsO
4 tetrahedral units that form 12-membered apertures. The layers are connected together by the oxalate units, forming a uniform one-dimensional channel that is occupied by protonated amine molecules. Variable temperature powder XRD studies indicates that
I loses crystallinity at ∼300 °C forming an amorphous phase that gives way to crystalline FeAsO
4 at ∼650 °C. Magnetic studies reveal that
I is antiferromagnetic with
T
N
=
31
K
. |
| doi_str_mv | 10.1016/j.solidstatesciences.2006.02.031 |
| format | Article |
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3(CH
2)CH(NH
3)CH
3]
3[Fe
6(AsO
4)
2(HAsO
4)
6(C
2O
4)
3],
I. Crystal data: hexagonal, space group
=
P-3c1,
a
=
13.9899
(
12
)
,
c
=
14.936
(
3
)
Å
,
V
=
2531.6
(
5
)
Å
3
. The structure consists of layers of vertex-sharing FeO
6 octahedral and AsO
4 tetrahedral units that form 12-membered apertures. The layers are connected together by the oxalate units, forming a uniform one-dimensional channel that is occupied by protonated amine molecules. Variable temperature powder XRD studies indicates that
I loses crystallinity at ∼300 °C forming an amorphous phase that gives way to crystalline FeAsO
4 at ∼650 °C. Magnetic studies reveal that
I is antiferromagnetic with
T
N
=
31
K
.</description><identifier>ISSN: 1293-2558</identifier><identifier>EISSN: 1873-3085</identifier><identifier>DOI: 10.1016/j.solidstatesciences.2006.02.031</identifier><language>eng</language><publisher>Paris: Elsevier Masson SAS</publisher><subject>Condensed matter: structure, mechanical and thermal properties ; Cross-disciplinary physics: materials science; rheology ; Exact sciences and technology ; Growth from solutions ; Hydrothermal synthesis ; Inorganic compounds ; Inorganic–organic hybrid ; Iron ; Materials science ; Methods of crystal growth; physics of crystal growth ; Miscellaneous ; Physics ; Structure of solids and liquids; crystallography ; Structure of specific crystalline solids ; X-ray diffraction</subject><ispartof>Solid state sciences, 2006-06, Vol.8 (6), p.692-697</ispartof><rights>2006 Elsevier SAS</rights><rights>2006 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c318t-584c67821feab70c1dd02aec288202b9b2205f9f8090443bfadb2149558bf1ac3</citedby><cites>FETCH-LOGICAL-c318t-584c67821feab70c1dd02aec288202b9b2205f9f8090443bfadb2149558bf1ac3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.solidstatesciences.2006.02.031$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,778,782,3539,27913,27914,45984</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=17798735$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Rao, Vandavasi Koteswara</creatorcontrib><creatorcontrib>Kam, Kinson C.</creatorcontrib><creatorcontrib>Cheetham, Anthony K.</creatorcontrib><creatorcontrib>Natarajan, Srinivasan</creatorcontrib><title>Inorganic–organic hybrid structures: Synthesis, structure and magnetic properties of a new iron oxalatoarsenate, [NH 3(CH 2)CH(NH 3)CH 3] 3[Fe 6(AsO 4) 2(HAsO 4) 6(C 2O 4) 3]</title><title>Solid state sciences</title><description>A hydrothermal reaction of a mixture of iron oxalate, arsenic acid, 1,2-diaminopropane and water at 150 °C gave rise to a new three-dimensional iron oxalatoarsenate, [NH
3(CH
2)CH(NH
3)CH
3]
3[Fe
6(AsO
4)
2(HAsO
4)
6(C
2O
4)
3],
I. Crystal data: hexagonal, space group
=
P-3c1,
a
=
13.9899
(
12
)
,
c
=
14.936
(
3
)
Å
,
V
=
2531.6
(
5
)
Å
3
. The structure consists of layers of vertex-sharing FeO
6 octahedral and AsO
4 tetrahedral units that form 12-membered apertures. The layers are connected together by the oxalate units, forming a uniform one-dimensional channel that is occupied by protonated amine molecules. Variable temperature powder XRD studies indicates that
I loses crystallinity at ∼300 °C forming an amorphous phase that gives way to crystalline FeAsO
4 at ∼650 °C. Magnetic studies reveal that
I is antiferromagnetic with
T
N
=
31
K
.</description><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>Cross-disciplinary physics: materials science; rheology</subject><subject>Exact sciences and technology</subject><subject>Growth from solutions</subject><subject>Hydrothermal synthesis</subject><subject>Inorganic compounds</subject><subject>Inorganic–organic hybrid</subject><subject>Iron</subject><subject>Materials science</subject><subject>Methods of crystal growth; physics of crystal growth</subject><subject>Miscellaneous</subject><subject>Physics</subject><subject>Structure of solids and liquids; crystallography</subject><subject>Structure of specific crystalline solids</subject><subject>X-ray diffraction</subject><issn>1293-2558</issn><issn>1873-3085</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2006</creationdate><recordtype>article</recordtype><recordid>eNqNkc1u1DAUhSMEEqXwDt6AUqkJ_skvK6qIkqKKLoBVVVmOc9N6lLGnvh5gdrwDL8Iz8SR4mEhdsGFh3WPr87m-PkmSMpozyqrXqxzdbEYMKgBqA1YD5pzSKqc8p4I9So5YU4tM0KZ8HDVvRcbLsnmaPENc0QhWdXGU_Lqwzt8qa_TvHz8XRe52gzcjweC3Omw94BvyaWfDHaDB04djouxI1urWQoiXNt5twAcDSNxEFLHwjRjvLHHf1ayCUx7BxseekuuPPRFp1xN-0vXpfhMrETdEXJ8DqdIzvCLFCeFpv6gq7Qj_q8TN8-TJpGaEF0s9Tr6cv_vc9dnl1fuL7uwy04I1ISubQld1w9kEaqipZuNIuQLNm4ZTPrQD57Sc2qmhLS0KMUxqHDgr2vhDw8SUFsfJq4NvnOt-Cxjk2qCGeVYW3BYlb4uqiCuCbw-g9g7RwyQ33qyV30lG5T4quZL_RiX3UUnKZYwqWrxceinUap68strgg09dtzHKMnIfDhzEwb8a8HKxG40HHeTozP83_QOYerPN</recordid><startdate>200606</startdate><enddate>200606</enddate><creator>Rao, Vandavasi Koteswara</creator><creator>Kam, Kinson C.</creator><creator>Cheetham, Anthony K.</creator><creator>Natarajan, Srinivasan</creator><general>Elsevier Masson SAS</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>200606</creationdate><title>Inorganic–organic hybrid structures: Synthesis, structure and magnetic properties of a new iron oxalatoarsenate, [NH 3(CH 2)CH(NH 3)CH 3] 3[Fe 6(AsO 4) 2(HAsO 4) 6(C 2O 4) 3]</title><author>Rao, Vandavasi Koteswara ; Kam, Kinson C. ; Cheetham, Anthony K. ; Natarajan, Srinivasan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c318t-584c67821feab70c1dd02aec288202b9b2205f9f8090443bfadb2149558bf1ac3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2006</creationdate><topic>Condensed matter: structure, mechanical and thermal properties</topic><topic>Cross-disciplinary physics: materials science; rheology</topic><topic>Exact sciences and technology</topic><topic>Growth from solutions</topic><topic>Hydrothermal synthesis</topic><topic>Inorganic compounds</topic><topic>Inorganic–organic hybrid</topic><topic>Iron</topic><topic>Materials science</topic><topic>Methods of crystal growth; physics of crystal growth</topic><topic>Miscellaneous</topic><topic>Physics</topic><topic>Structure of solids and liquids; crystallography</topic><topic>Structure of specific crystalline solids</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Rao, Vandavasi Koteswara</creatorcontrib><creatorcontrib>Kam, Kinson C.</creatorcontrib><creatorcontrib>Cheetham, Anthony K.</creatorcontrib><creatorcontrib>Natarajan, Srinivasan</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Solid state sciences</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Rao, Vandavasi Koteswara</au><au>Kam, Kinson C.</au><au>Cheetham, Anthony K.</au><au>Natarajan, Srinivasan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Inorganic–organic hybrid structures: Synthesis, structure and magnetic properties of a new iron oxalatoarsenate, [NH 3(CH 2)CH(NH 3)CH 3] 3[Fe 6(AsO 4) 2(HAsO 4) 6(C 2O 4) 3]</atitle><jtitle>Solid state sciences</jtitle><date>2006-06</date><risdate>2006</risdate><volume>8</volume><issue>6</issue><spage>692</spage><epage>697</epage><pages>692-697</pages><issn>1293-2558</issn><eissn>1873-3085</eissn><abstract>A hydrothermal reaction of a mixture of iron oxalate, arsenic acid, 1,2-diaminopropane and water at 150 °C gave rise to a new three-dimensional iron oxalatoarsenate, [NH
3(CH
2)CH(NH
3)CH
3]
3[Fe
6(AsO
4)
2(HAsO
4)
6(C
2O
4)
3],
I. Crystal data: hexagonal, space group
=
P-3c1,
a
=
13.9899
(
12
)
,
c
=
14.936
(
3
)
Å
,
V
=
2531.6
(
5
)
Å
3
. The structure consists of layers of vertex-sharing FeO
6 octahedral and AsO
4 tetrahedral units that form 12-membered apertures. The layers are connected together by the oxalate units, forming a uniform one-dimensional channel that is occupied by protonated amine molecules. Variable temperature powder XRD studies indicates that
I loses crystallinity at ∼300 °C forming an amorphous phase that gives way to crystalline FeAsO
4 at ∼650 °C. Magnetic studies reveal that
I is antiferromagnetic with
T
N
=
31
K
.</abstract><cop>Paris</cop><pub>Elsevier Masson SAS</pub><doi>10.1016/j.solidstatesciences.2006.02.031</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1293-2558 |
| ispartof | Solid state sciences, 2006-06, Vol.8 (6), p.692-697 |
| issn | 1293-2558 1873-3085 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_29464946 |
| source | ScienceDirect Journals (5 years ago - present) |
| subjects | Condensed matter: structure, mechanical and thermal properties Cross-disciplinary physics: materials science rheology Exact sciences and technology Growth from solutions Hydrothermal synthesis Inorganic compounds Inorganic–organic hybrid Iron Materials science Methods of crystal growth physics of crystal growth Miscellaneous Physics Structure of solids and liquids crystallography Structure of specific crystalline solids X-ray diffraction |
| title | Inorganic–organic hybrid structures: Synthesis, structure and magnetic properties of a new iron oxalatoarsenate, [NH 3(CH 2)CH(NH 3)CH 3] 3[Fe 6(AsO 4) 2(HAsO 4) 6(C 2O 4) 3] |
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