Synthesis of Hierarchical Titanium Carbide from Titania-Coated Cellulose Paper
Cellulose paper and an aqueous‐based, inexpensive TiO2 precursor, Tyzor‐LA, have been used to prepare TiC via carbothermal reduction in an Ar flow. The hierarchical cellulose structures were completely maintained upon the agglomeration of 10–50 nm TiC nanoparticles. The lattice parameter of TiC incr...
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| Veröffentlicht in: | Advanced Materials 2004-07, Vol.16 (14), p.1212-1215 |
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| container_title | Advanced Materials |
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| creator | Shin, Y. Li, X. S. Wang, C. Coleman, J. R. Exarhos, G. J. |
| description | Cellulose paper and an aqueous‐based, inexpensive TiO2 precursor, Tyzor‐LA, have been used to prepare TiC via carbothermal reduction in an Ar flow. The hierarchical cellulose structures were completely maintained upon the agglomeration of 10–50 nm TiC nanoparticles. The lattice parameter of TiC increased with increasing reaction temperature, while the oxygen content in the sample decreased and showed minimal oxygen impurity at 1500 °C (0.24 wt.‐%). |
| doi_str_mv | 10.1002/adma.200306661 |
| format | Article |
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S. ; Wang, C. ; Coleman, J. R. ; Exarhos, G. J.</creator><creatorcontrib>Shin, Y. ; Li, X. S. ; Wang, C. ; Coleman, J. R. ; Exarhos, G. J. ; Pacific Northwest National Lab., Richland, WA (US), Environmental Molecular Sciences Laboratory (US)</creatorcontrib><description>Cellulose paper and an aqueous‐based, inexpensive TiO2 precursor, Tyzor‐LA, have been used to prepare TiC via carbothermal reduction in an Ar flow. The hierarchical cellulose structures were completely maintained upon the agglomeration of 10–50 nm TiC nanoparticles. The lattice parameter of TiC increased with increasing reaction temperature, while the oxygen content in the sample decreased and showed minimal oxygen impurity at 1500 °C (0.24 wt.‐%).</description><identifier>ISSN: 0935-9648</identifier><identifier>EISSN: 1521-4095</identifier><identifier>DOI: 10.1002/adma.200306661</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>AGGLOMERATION ; Biomimetics ; carbide ; CARBOTHERMAL SYNTHESIS ; CELLULOSE ; Ceramics ; Ceramics, carbide ; ENVIRONMENTAL MOLECULAR SCIENCES LABORATORY ; INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ; LATTICE PARAMETERS ; MINERALIZATION ; POWDERS ; PRECURSOR ; Structure replication ; SYNTHESIS ; Titania ; Titanium carbide ; TITANIUM CARBIDES ; TITANIUM OXIDES ; WOOD</subject><ispartof>Advanced Materials, 2004-07, Vol.16 (14), p.1212-1215</ispartof><rights>Copyright © 2004 WILEY‐VCH Verlag GmbH & Co. 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J.</creatorcontrib><creatorcontrib>Pacific Northwest National Lab., Richland, WA (US), Environmental Molecular Sciences Laboratory (US)</creatorcontrib><title>Synthesis of Hierarchical Titanium Carbide from Titania-Coated Cellulose Paper</title><title>Advanced Materials</title><addtitle>Adv. Mater</addtitle><description>Cellulose paper and an aqueous‐based, inexpensive TiO2 precursor, Tyzor‐LA, have been used to prepare TiC via carbothermal reduction in an Ar flow. The hierarchical cellulose structures were completely maintained upon the agglomeration of 10–50 nm TiC nanoparticles. The lattice parameter of TiC increased with increasing reaction temperature, while the oxygen content in the sample decreased and showed minimal oxygen impurity at 1500 °C (0.24 wt.‐%).</description><subject>AGGLOMERATION</subject><subject>Biomimetics</subject><subject>carbide</subject><subject>CARBOTHERMAL SYNTHESIS</subject><subject>CELLULOSE</subject><subject>Ceramics</subject><subject>Ceramics, carbide</subject><subject>ENVIRONMENTAL MOLECULAR SCIENCES LABORATORY</subject><subject>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</subject><subject>LATTICE PARAMETERS</subject><subject>MINERALIZATION</subject><subject>POWDERS</subject><subject>PRECURSOR</subject><subject>Structure replication</subject><subject>SYNTHESIS</subject><subject>Titania</subject><subject>Titanium carbide</subject><subject>TITANIUM CARBIDES</subject><subject>TITANIUM OXIDES</subject><subject>WOOD</subject><issn>0935-9648</issn><issn>1521-4095</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2004</creationdate><recordtype>article</recordtype><recordid>eNqFkE1r3DAQhkVIIZu015wNgdy8GVlf1nHjNNm0aVpoSo9C1o5Ytba1lby0--_r4BB661wGhucZZl5CziksKUB1ZTe9XVYADKSU9IgsqKhoyUGLY7IAzUSpJa9PyGnOPwBAS5AL8vj1MIxbzCEX0RfrgMkmtw3OdsVTGO0Q9n3R2NSGDRY-xf5lassm2hE3RYNdt-9ixuKL3WF6S95422V899LPyLfb90_Nunz4fHffrB5KxwXQkirtueSKO6aQVQyc0FI4hbW0rdDeK2tx03rOoVKqdYK1FWUCPHJtq9azM3Ix7415DCa7MKLbujgM6EZDxfTdVBN1OVO7FH_tMY-mD9lNF9sB4z6bSnNRS0oncDmDLsWcE3qzS6G36WAomOdwzXO45jXcSdCz8Dt0ePgPbVY3n1b_uuXshjzin1fXpp9GKqaE-f54Z65vP67rev3BXLO_m5mMNA</recordid><startdate>20040719</startdate><enddate>20040719</enddate><creator>Shin, Y.</creator><creator>Li, X. 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S.</creatorcontrib><creatorcontrib>Wang, C.</creatorcontrib><creatorcontrib>Coleman, J. R.</creatorcontrib><creatorcontrib>Exarhos, G. J.</creatorcontrib><creatorcontrib>Pacific Northwest National Lab., Richland, WA (US), Environmental Molecular Sciences Laboratory (US)</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><collection>Corrosion Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>OSTI.GOV</collection><jtitle>Advanced Materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Shin, Y.</au><au>Li, X. S.</au><au>Wang, C.</au><au>Coleman, J. R.</au><au>Exarhos, G. J.</au><aucorp>Pacific Northwest National Lab., Richland, WA (US), Environmental Molecular Sciences Laboratory (US)</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of Hierarchical Titanium Carbide from Titania-Coated Cellulose Paper</atitle><jtitle>Advanced Materials</jtitle><addtitle>Adv. Mater</addtitle><date>2004-07-19</date><risdate>2004</risdate><volume>16</volume><issue>14</issue><spage>1212</spage><epage>1215</epage><pages>1212-1215</pages><issn>0935-9648</issn><eissn>1521-4095</eissn><abstract>Cellulose paper and an aqueous‐based, inexpensive TiO2 precursor, Tyzor‐LA, have been used to prepare TiC via carbothermal reduction in an Ar flow. The hierarchical cellulose structures were completely maintained upon the agglomeration of 10–50 nm TiC nanoparticles. The lattice parameter of TiC increased with increasing reaction temperature, while the oxygen content in the sample decreased and showed minimal oxygen impurity at 1500 °C (0.24 wt.‐%).</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><doi>10.1002/adma.200306661</doi><tpages>4</tpages></addata></record> |
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| ispartof | Advanced Materials, 2004-07, Vol.16 (14), p.1212-1215 |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | AGGLOMERATION Biomimetics carbide CARBOTHERMAL SYNTHESIS CELLULOSE Ceramics Ceramics, carbide ENVIRONMENTAL MOLECULAR SCIENCES LABORATORY INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY LATTICE PARAMETERS MINERALIZATION POWDERS PRECURSOR Structure replication SYNTHESIS Titania Titanium carbide TITANIUM CARBIDES TITANIUM OXIDES WOOD |
| title | Synthesis of Hierarchical Titanium Carbide from Titania-Coated Cellulose Paper |
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